公开(公告)号：JPH1029965A

公开(公告)日：1998-02-03

申请号：JP6381697

申请日：1997-03-03

申请人： CIBA GEIGY AG

发明人： DESOBRY VINCENT ,  DIETLIKER KURT ,  HUESLER RINALDO ,  RUTSCH WERNER ,  REMBOLD MANFRED ,  SITEK FRANCISZEK

IPC分类号： C07D209/12 ,  C07C67/00 ,  C07C209/86 ,  C07C213/00 ,  C07C219/02 ,  C07C219/04 ,  C07C225/02 ,  C07C225/16 ,  C07C225/22 ,  C07C229/06 ,  C07C229/14 ,  C07C229/16 ,  C07C229/34 ,  C07C229/52 ,  C07C233/36 ,  C07C253/00 ,  C07C255/56 ,  C07C313/00 ,  C07C317/24 ,  C07C317/32 ,  C07C317/36 ,  C07C323/22 ,  C07C323/23 ,  C07C323/25 ,  C07C323/31 ,  C07C323/32 ,  C07C323/65 ,  C07D209/86 ,  C07D219/02 ,  C07D219/04 ,  C07D223/22 ,  C07D263/32 ,  C07D263/56 ,  C07D265/30 ,  C07D265/36 ,  C07D265/38 ,  C07D279/18 ,  C07D283/00 ,  C07D295/02 ,  C07D295/10 ,  C07D295/104 ,  C07D295/112 ,  C07D295/12 ,  C07D307/91 ,  C07F7/18 ,  C08F2/46 ,  C08F2/50 ,  C09D4/00 ,  C09D5/32 ,  C09D7/12 ,  C09D11/10 ,  G03F7/00 ,  G03F7/031

摘要： PROBLEM TO BE SOLVED: To obtain a new compound useful as a photo-polymerization initiator for ethylene unsaturated compound and a photo-reaction initiator for the photo- setting of a pigment system as a printing ink or a white lacquer. SOLUTION: This compound is expressed by the formula I [Ar is an aromatic group of the formula II (R to R are each H, a halogen, a 1-12C alkyl, etc.); Y is a 1-6C alkylene, xylylene, cyclohexylene, etc.; R is (CH2 R )p -C (R )=(CR )-R , etc.; R and R are each a 1-12C alkyl, OH, a 1-4C alkoxy, etc.; R to R are each H, an alkyl, etc.; (p) is 0 or 1], e.g. 2-(dimethylamino)-2- ethyl-1-(4-morpholinophenyl)-4-penten-1-one. The compound of the formula I can be produced by using a bis-aryl ketone of the formula Ar -CO-CH2 -Y-CH2 - CO-Ar as a starting substance, brominating the ketone and reacting with a compound of the formula, NHR R and then with a compound of the formula, R Hal.

公开(公告)号：JPH1029977A

公开(公告)日：1998-02-03

申请号：JP6381597

申请日：1997-03-03

申请人： CIBA GEIGY AG

发明人： DESOBRY VINCENT ,  DIETLIKER KURT ,  HUESLER RINALDO ,  RUTSCH WERNER ,  REMBOLD MANFRED ,  SITEK FRANCISZEK

IPC分类号： C07D209/12 ,  C07C67/00 ,  C07C209/86 ,  C07C213/00 ,  C07C219/02 ,  C07C219/04 ,  C07C225/02 ,  C07C225/16 ,  C07C225/22 ,  C07C229/06 ,  C07C229/14 ,  C07C229/16 ,  C07C229/34 ,  C07C229/52 ,  C07C233/36 ,  C07C253/00 ,  C07C255/56 ,  C07C313/00 ,  C07C317/24 ,  C07C317/32 ,  C07C317/36 ,  C07C323/22 ,  C07C323/23 ,  C07C323/25 ,  C07C323/31 ,  C07C323/32 ,  C07C323/65 ,  C07D209/86 ,  C07D219/02 ,  C07D219/04 ,  C07D223/22 ,  C07D263/32 ,  C07D263/56 ,  C07D265/30 ,  C07D265/36 ,  C07D265/38 ,  C07D279/18 ,  C07D283/00 ,  C07D295/02 ,  C07D295/10 ,  C07D295/104 ,  C07D295/112 ,  C07D295/12 ,  C07D307/91 ,  C07F7/18 ,  C08F2/46 ,  C08F2/50 ,  C09D4/00 ,  C09D5/32 ,  C09D7/12 ,  C09D11/10 ,  G03F7/00 ,  G03F7/031

摘要： PROBLEM TO BE SOLVED: To obtain a mew α-aminoacetophenone derivative bearing allyl or aralkyl group on the α-site, having especially high activity as a photoinitiator, and effectively usable in esp. printing inks. SOLUTION: This new derivative is a compound (acid-added salt thereof) of formula I Ar is an aromatic group of formula II or formula III [U is O, S, etc.; V is O, S, CH2 , etc.; W is a straight-chain or branched 1-7C alkaline; R is a group of formula IV (R is H, a 1-8C alkyl or phenyl; R to R are each H or a 1-4C alkyl; (p) is 0 or 1), etc.; R is one of R s or a 1-12C alkyl; R is a 1-12C alkyl, etc.; R is a 1-12C alkyl, hydroxyl, etc.]}e.g. 2-(dimehjylamino)-2-ethyl-1-(4-morpholinophenyl)-4-penten-1-one. The compound of formula I is synthesizes, for example, using ketone as the starting material according to known reaction processes including C-allylation or C-benzylation.

公开(公告)号：JPH1087643A

公开(公告)日：1998-04-07

申请号：JP12794597

申请日：1997-05-01

申请人： CIBA GEIGY AG

发明人： HUESLER RINALDO ,  SCHWABE RUDOLF ,  LUISOLI RETO

IPC分类号： C07D295/10 ,  C07D211/14 ,  C07D241/04 ,  C07D265/28 ,  C07D265/30 ,  C07D295/112 ,  C07D295/12 ,  C07D295/135 ,  C08F2/50 ,  G03F7/028 ,  G03F7/031

摘要： PROBLEM TO BE SOLVED: To obtain a new compound substituted with a cyclic amine at a para position and useful as an intermediate for synthesizing a photoinitiator for photopolymerization of an ethylenically unsaturated compound. SOLUTION: This new compound is a compound of formula I (R and R together become O, S, or a 3-20C alkylene, which may be discontinued by N(R4 ); R3 is a 2-20C alkyl; R4 is H, a 1-3C alkyl, a 3-5C alkenyl, phenyl, etc.; etc.), e.g. 1-(4-morpholinophenyl)butan-1-one. A compound of formula I is obtained by subjecting a p-halophenyl alkyl ketone of formula II (X is a halogen) to aminolysis using a cyclic amine of formula III in water at a temperature of at least 130 deg.C. The compound of formula III is used in an amount of 2.5-12mol equivalent and further water is used in an amount of 1-100mol equivalent, each based on the compound of formula II. Examples of a compound of formula II include 1-(4-bromophenyl)butan-1-one, and examples of a cyclic amine of formula III include morpholine.