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公开(公告)号：JPH0393818A
公开(公告)日：1991-04-18
申请号：JP23028789
申请日：1989-09-07
申请人： SHOWA HIGHPOLYMER
发明人： SHINOHARA NORIO , OTANI KAZUO , HANIYUDA TOSHIAKI
IPC分类号： C08F299/00 , C08F212/34 , C08F222/40 , C08F283/04 , C08F290/00 , C08K5/32 , C08L79/08
摘要： PURPOSE:To provide the subject composition composed of a maleimide- containing compound, a specific compound, an ammonium salt of N- nitrosophenyl hydroxylamine, etc., having excellent workability, low-temperature curability, heat-resistance and mechanical properties and useful as a laminate- forming compound, etc. CONSTITUTION:The objective composition is composed of (A) a compound having >=2 maleimide groups in the molecule (e.g. N,N'-phenylenebismaleimide), (B) a compound having >=2 vinylbenzyl ether groups bonded to aromatic residue in the molecule [e.g. the compound of formula (X is hydroquinone group, diphenyl group, etc.)] and (C) ammonium salt or Al salt of nitrosophenyl hydroxylamine.
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公开(公告)号：JPH0392343A
公开(公告)日：1991-04-17
申请号：JP22868589
申请日：1989-09-04
申请人： SHOWA HIGHPOLYMER
发明人： SHINOHARA NORIO , OTANI KAZUO , HANIYUDA TOSHIAKI , MORI KOJIRO
摘要： PURPOSE:To improve heat resistance and electric characteristics by impregnating various fiber materials with a resin soln. consisting of a specified compd., laminating a prepreg with a copper foil and molding them under heating and pressure. CONSTITUTION:A uniform matrix resin wherein 100 pts.wt. at least one polyhydric phenol divinyl benzyl ether with a substituent and compd. having one or more vinyl benzyl ether bound with a naphthalene nucleus and 1-150 pts.wt. compd. having one or more maleimide groups in a molecule are main components and which has low viscosity, excellent moldability is used. Then, various fiber material are impregnated with this matrix resin and a prepreg made into a B-stage with an tackiness is laminated with a copper foil and molded under heating and pressure. A polymerizable monomer is used in a range of 5-50 pts.wt. based on 100 pts.wt. vinyl benzyl ether compd. from the view points of viscosity control, improvement of curing characteristics and economy. In addition, a polymerizable oligomer is used in a range of 5-200 pts.wt. based on 100 pts.wt. vinyl benzyl ether compd. from the view points of viscosity control, improvement of curing characteristics and economy.
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3.发明专利
公开(公告)号：JPH02134340A
公开(公告)日：1990-05-23
申请号：JP28705088
申请日：1988-11-14
申请人： SHOWA HIGHPOLYMER
发明人： HANIYUDA TOSHIAKI , MORI KOJIRO , OTANI KAZUO , SHINOHARA NORIO , SHIBATA JOJI
IPC分类号： C07C41/01 , C07C43/23 , C08F290/00 , C08F299/00 , C08F299/02 , C08G59/14
摘要： NEW MATERIAL:Phenol vinylbenzyl ether compounds represented by the formula (X is divalent phenol residue formed by removal of hydroxyl group from divalent phenol) having a vinylbenzyl ether group and a phenolic hydroxyl group in the molecule and prepared by substituting one or more phenolic hydroxyl groups of a polyvalent phenol with a vinylbenzyl ether group. USE:Useful as the raw material of a curing resin containing vinylbenzyl ether group-containing oligomers as the main components excellent in curing characteristics, capable of providing an excellent cured material and useful as an adhesive, coating material, a laminated material, a molding material, etc. The vinylbenzyl ether group-containing oligomers are produced by a reaction of the subject compound with an epoxy compound. PREPARATION:A polyvalent phenol is reacted with a halomethylstyrene in the presence of an alkali using the latter in an amount of
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公开(公告)号：JPS6465110A
公开(公告)日：1989-03-10
申请号：JP22033987
申请日：1987-09-04
申请人： SHOWA HIGHPOLYMER
发明人： HANIYUDA TOSHIAKI , SHIBATA JOJI , OTANI KAZUO
IPC分类号： C08F12/34 , C08F22/36 , C08F212/00 , C08F212/34 , C08F222/00 , C08F222/40 , C08F290/00 , C08F299/00
摘要： PURPOSE:To obtain the title compsn. which has a low curing temp. and a small curing time and is excellent in heat-resistance, heat stability and mechanical properties, by blending a specified maleimide compd. and vinylbenzyl ether compd. CONSTITUTION:A chloromethylstyrene monomer is reacted with a polyhydric phenol compd. (e.g., bisphenol A) to remove hydrogen chloride in the presence of an inorg. alkali in a dimethyl sulfoxide solvent to give a compd. having at least two vinylbenzyl ether units bonded to an arom. residue in the molecule of the formula as shown [where X is an arom. residue (a residue of polyhydric phenol compd. from which hydroxy groups having been removed)], (b). A compd. having at least two maleimide groups in the molecule (a) (e.g., N,N'- phenylenebismaleimide) and component (b) are blended so that the ratio of their unsatd. group equivalents is 100/30-1/100.
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公开(公告)号：JPS63165280A
公开(公告)日：1988-07-08
申请号：JP30918486
申请日：1986-12-27
申请人： SHOWA HIGHPOLYMER
摘要： PURPOSE:To facilitate and complete execution of binding stabilization, by a method wherein, in sheathing for an electric wiring and the like, a bundle of a plurality of filaments is sheathed with a sheetform prepreg of fibre-reinforced plastic impregnated with photo curable resin, and is cured through irradiation with light. CONSTITUTION:Resin series, where a light initiator is mixed in one kind or a mixture of radial curable resin, e.g., unstaturated polyester resin, acryl resin, vinyl ester resin, is impregnated in a fibrous material, e.g., glass fiber, organic fibre to produce a sheetform material. Through regulation of viscosity, proper pliability and adhesion are provided, a sheetform or a tapeform prepreg, having a specified length, is manufactured. A tape of the prepreg is wound around a bundle of the filaments having a specified length or the bundle is wrapped with the tape, and after the sheathing is formed in a given shape, it is irradiated with natural light or artificial light to cure the prepreg. This method facilitates binding, reinforcing, protection, and stabilization of various pliable filament substance.
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公开(公告)号：JPS61101518A
公开(公告)日：1986-05-20
申请号：JP22115584
申请日：1984-10-23
发明人： TANAKA SHIGEO , SHIBATA JOJI , HANIYUDA TOSHIAKI
IPC分类号： C08F299/00 , C08F290/00 , C08F299/02 , C08G59/00 , C08G59/16 , C08G59/17 , C08G59/40 , C09D163/10
摘要： PURPOSE: To obtain a vinyl ester resin excellent in corrosion inhibition and air dryability, by incorporating an allyl ether group in a specified product compound.
CONSTITUTION: A product compound is obtained by reacting the epoxy groups of an epoxy resin with an unsaturated monobasic acid [e.g., (meth)acrylic acid] part of which may be replaced with a half-ester carboxylic acid obtained by reacting a polyallyl ether monoalcohol (e.g., glycerin diallyl ether) with a dibasic acid anhydride (e.g., maleic anhydride) at 80W150°C in the presence of a polymerization inhibitor and an esterification catalyst and, if desired, effecting an addition reaction between the OH group in the reaction product and a dibasic acid anhydride to form a half-ester carboxylic acid. This product compound is reacted with allyl glycidyl ether or glycidyl (meth)acrylate to incorporate at least one allyl ether group per epoxymethacryl molecule in the product compound.
COPYRIGHT: (C)1986,JPO&Japio摘要翻译： 目的：通过在规定的产品化合物中加入烯丙基醚基来获得耐腐蚀性和空气干燥性优异的乙烯基酯树脂。 构成：通过使环氧树脂的环氧基与不饱和一元酸[例如（甲基）丙烯酸）反应获得产物化合物，其中一部分可以被通过使聚烯丙基醚一元醇 （例如，甘油二烯丙基醚）与二元酸酐（例如马来酸酐）在80-150℃下在聚合抑制剂和酯化催化剂存在下反应，并且如果需要，进行OH基团之间的加成反应 反应产物和二元酸酐形成半酯羧酸。 该产物化合物与烯丙基缩水甘油醚或（甲基）丙烯酸缩水甘油酯反应，以在产物化合物中引入至少一个烯丙基醚基团。
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公开(公告)号：JP2002265749A
公开(公告)日：2002-09-18
申请号：JP2001061606
申请日：2001-03-06
申请人： SHOWA HIGHPOLYMER
发明人： ISHITANI KOICHI , KO TOMO , UCHIDA JIRO , HARADA AKIO , HANIYUDA TOSHIAKI
IPC分类号： C08L57/00 , C08F210/00 , C08F212/06 , C08F214/04 , C08F218/04 , C08F220/10 , C08F246/00 , C08K5/07
摘要： PROBLEM TO BE SOLVED: To obtain a one-pack type ordinary temperature-crosslinking type emulsion composition having a one-liquid type ordinary temperature-crosslinking property as a polymer emulsion and fulfilling an antithetical requirement such that a film obtained is excellent both in water resistance and solvent resistance and rich in storage stability. SOLUTION: This one-pack type ordinary temperature-crosslinking type emulsion composition is a copolymer emulsion containing a urea group obtained by emulsion polymerization of an ethylenic unsaturated monomer having a urea group obtained by reaction of an ethylenic unsaturated monomer having an isocyanate group with an amine and added with a multifunctional aldehyde compound as a crosslinking agent with other unsaturated monomers.
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公开(公告)号：JPH05140049A
公开(公告)日：1993-06-08
申请号：JP32715691
申请日：1991-11-15
申请人： SHOWA HIGHPOLYMER
发明人： YOSHIDA HARUO , OTANI KAZUO , SHINOHARA NORIO , HANIYUDA TOSHIAKI
IPC分类号： B01J23/02 , C07B61/00 , C07C209/10 , C07C209/60 , C07C211/45 , C07C211/50 , C07C213/08 , C07C215/76 , C08F12/00 , C08F12/28
摘要： PURPOSE:To efficiently obtain the subject compound useful as a crosslinkable resin material in high yield by reacting a vinylbenzyl halide with an aromatic amine under a specific condition. CONSTITUTION:A vinylbenzyl halide is reacted with an aromatic amine in the presence of an alkali metal hydroxide (e.g. NaOH) in an aromatic hydrocarbon (e.g. toluene) and water as a solvent by adding an onium salt (e.g. benzyltriethylammonium chloride) and an alkali metal iodide (e.g. sodium iodide) to the reaction system at 25-100 deg.C to give the objective substance. The amount of the vinylbenzyl halide used is 0.5-1.3 equivalent based on 1 equivalent active hydrogen of the aromatic amine, the amount of the onium salt used is 1-20mol% based on the vinylbenzyl halide, the amount of the alkali metal iodide is 0.01-3mol% and the amount of the alkali metal hydroxide is 1-5mols. The subject composition has excellently curing properties at a relatively low temperature condition, provides a cured material having excellent heat resistance, electrical characteristics and mechanical characteristics and is suitable especially for molding material and laminate.
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公开(公告)号：JPH04164909A
公开(公告)日：1992-06-10
申请号：JP28849790
申请日：1990-10-29
申请人： SHOWA HIGHPOLYMER
发明人： SHINOHARA NORIO , OTANI KAZUO , HANIYUDA TOSHIAKI
IPC分类号： C08F12/34 , C08F12/00 , C08F22/36 , C08F212/34 , C08F222/40 , C08F290/00 , C08F290/06 , C08F299/00 , C09D4/00 , C09J4/00
摘要： PURPOSE:To obtain a curable resin composition which can be cured at low temperatures and has a short curing time and excellent heat stability and mechanical properties, especially hot strength, by mixing a maleimide compound with a divinylbenzyl ether. CONSTITUTION:A curable resin composition is obtained by mixing a compound having a maleimide group in the molecule (e.g. a bismaleimide such as N,N'- phenylenebismaleimide or a compound derived by modifying a bismaleimide with an amino compound such as diaminodiphenylmethane and still having two maleimide groups in the molecule) with divinylbenzyl ether. This composition excels in workability because it is amorphous and lowly viscous, and it can be extensively used as a bonding, casting, coating, impregnation or lamination molding compound, a coating material, an insulation material or a composite structural material because it is excellent in low-temperature curability, heat resistance and mechanical strengths.
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公开(公告)号：JPH03290414A
公开(公告)日：1991-12-20
申请号：JP9234690
申请日：1990-04-09
申请人： SHOWA HIGHPOLYMER
发明人： SHINOHARA NORIO , OTANI KAZUO , HANIYUDA TOSHIAKI
IPC分类号： C08F212/34 , C08F12/00 , C08F20/52 , C08F22/36 , C08F222/40
摘要： PURPOSE:To provide the subject composition having excellent cold-curability, heat-resistance and mechanical properties and composed of a compound containing a maleimide group and an N-substituted aromatic amine containing plural N-vinylbenzyl groups. CONSTITUTION:The objective composition is composed of (A) a compound containing maleimide group in the molecule (e.g. N,N'-phenylenebismaleimide) and (B) an N-substituted aromatic amine containing >=2 N-vinylbenzyl groups in the molecule [e.g. the compound of formula (X is residue produced by removing y H atoms from amino group of an aromatic amine; y is 2-6)].
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