利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

34 条记录 (耗时 0.019 秒)

    Compositions comprising 3,3,3-trifluoropropyne
    1.
    发明授权
    Compositions comprising 3,3,3-trifluoropropyne 有权
    包含3,3,3-三氟丙炔的组合物

    公开(公告)号：US08147709B2

    公开(公告)日：2012-04-03

    申请号：US12437014

    申请日：2009-05-07

    申请人： Barry Asher Mahler ,  Mario Joseph Nappa ,  Jeffrey P. Knapp

    发明人： Barry Asher Mahler ,  Mario Joseph Nappa ,  Jeffrey P. Knapp

    IPC分类号： C09K5/04

    CPC分类号： C09K5/00 ,  B01J27/125 ,  B01J37/26 ,  C07C17/25 ,  C07C17/354 ,  C07C21/18 ,  C07C21/22 ,  C08J9/146 ,  C08J9/149 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/12 ,  C09K2205/126 ,  C07C19/08

    摘要： Disclosed are compositions comprising HFC-245eb and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, and HFC-254fb. Compositions comprising HFC-245eb are useful in processes to make HFO-1234yf. Also disclosed are compositions comprising HFO-1234yf and at least one additional compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFC-254fb, HFO-1243zf, HFCHFC-245eb, HFC-245fa, HFC-245cb, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-134, HFC-134a, HFO-1132a and FC-1216. Compositions comprising HFO-1234yf are useful as heat transfer compositions for use in refrigeration, air-conditioning and heat pump systems.

    摘要翻译： 公开了包含HFC-245eb和至少一种选自HFO-1234ze，HFC-245fa，HFC-236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc ，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-143a，HFC-134，HFC-134a，FC-1216，HFO-1234yf，HFC-254eb，HFO-1243zf和HFC- 254fb。 包含HFC-245eb的组合物可用于制备HFO-1234yf的方法。 还公开了包含HFO-1234yf和至少一种选自HFO-1234ze，HFC-254eb，HFC-254fb，HFO-1243zf，HFCHFC-245eb，HFC-245fa，HFC-245cb，HFC- 236cb，HFC-236ea，HFC-236fa，HFC-227ea，HFC-227ca，HFO-1225yc，HFO-1225zc，HFO-1225ye，甲烷，乙烷，丙烷，HFC-23，HFC-134，HFC-134a， 1132a和FC-1216。 包含HFO-1234yf的组合物可用作用于制冷，空调和热泵系统的热转印组合物。

    Purification process for hexafluoroethane products
    4.
    发明授权
    Purification process for hexafluoroethane products 失效
    六氟乙烷产品净化过程

    公开(公告)号：US06221830B1

    公开(公告)日：2001-04-24

    申请号：US08842843

    申请日：1997-04-17

    申请人： Ralph Newton Miller ,  Mark Richard Deschere ,  Barry Asher Mahler ,  Olagappan Muthu

    发明人： Ralph Newton Miller ,  Mark Richard Deschere ,  Barry Asher Mahler ,  Olagappan Muthu

    IPC分类号： B01D334

    CPC分类号： C07C19/08 ,  C01B7/0712 ,  C01B7/196 ,  C07C17/38 ,  C07C17/386 ,  Y02P20/582

    摘要： The disclosure relates to removing impurities from hexafluoroethane (CF3CF3), also known as Perfluorocarbon 116 (PFC-116) or Fluorocarbon 116 (FC-116), by using azeotropic distillation such that an overhead product consisting essentially of HCl-hexafluoroethane is formed, optionally combined with a phase separation step to break the HCl-hexafluoroethane azeotropic or azeotrope-like composition thereby permitting recovery of substantially pure hexafluoroethane. Unreacted hydrogen fluoride (HF) may be removed from hexafluoroethane during the above azeotropic distillation with HCl or alternatively by an azeotropic distillation wherein an HF-hexafluoroethane azeotropic or azeotrope-like composition exits overhead and substantially pure HF exits in the bottoms stream.

    摘要翻译： 本公开涉及通过共沸蒸馏从六氟乙烷（CF 3 CF 3）（也称为全氟化碳116（PFC-116）或氟碳116（FC-116））除去杂质，从而形成基本上由HCl-六氟乙烷组成的塔顶馏出物 结合相分离步骤以破坏HCl-六氟乙烷共沸或类共沸组合物从而允许回收基本上纯的六氟乙烷。 在HCl的上述共沸蒸馏过程中，可以从六氟乙烷中除去未反应的氟化氢（HF），或者通过共沸蒸馏除去六氟乙烷，其中HF-六氟乙烷共沸或类共沸组合物离开塔顶馏出物，基本上纯的HF在塔底物流中离开。

    REACTOR FOR LIQUID PHASE FLUORINATION REACTIONS
    6.
    发明申请
    REACTOR FOR LIQUID PHASE FLUORINATION REACTIONS 有权
    液相荧光反应器的反应器

    公开(公告)号：US20150225316A1

    公开(公告)日：2015-08-13

    申请号：US14618500

    申请日：2015-02-10

    申请人： Daniel C. MERKEL ,  Barry Asher MAHLER ,  Hsueh Sung TUNG ,  Mario Joseph NAPPA

    发明人： Daniel C. MERKEL ,  Barry Asher MAHLER ,  Hsueh Sung TUNG ,  Mario Joseph NAPPA

    IPC分类号： C07C17/087 ,  C07C17/25

    CPC分类号： C07C17/087 ,  B01J19/18 ,  B01J19/1868 ,  C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C19/10

    摘要： The present invention relates to a hydrofluorinating process which comprises reacting a fluoroolefin with hydrogen fluoride in the liquid phase in the presence of a hydrofluorination catalyst in the reaction zone of a reactor, said reactor comprised of a reactor body having a length to diameter ratio of about 2:1 or greater; a stirred reaction zone containing said hydrofluorination catalyst, which may be prepared in situ, at least one inlet for supplying said hydrogen fluoride and fluoroolefin to the reaction zone and at least one outlet for recovering said fluoroalkane, said stirrer disposed in the reaction zone and comprising a plurality of blades fixedly attached to shaft drivable by a motor, said blades extending from about the bottom of the reaction zone to about the top of the reaction zone and said shaft extending on a longitudinal axis from the bottom of the reactor to the top of the reactor, said stirrer being rotated at a speed sufficient to promote a swirling of the liquid to effect the occurrence of hydrofluorination reaction and minimize overfluorination. The present invention also relates to said hydrofluorination reactor.

    摘要翻译： 本发明涉及一种氢氟化方法，其包括在反应器的反应区中在氟化氢催化剂存在下，在液相中使氟烯烃与氟化氢反应，所述反应器包括长径比为约 2：1或更大; 包含可以原位制备的所述氢氟化催化剂的搅拌反应区，至少一个用于将所述氟化氢和氟代烯烃供应到反应区的入口和用于回收所述氟烷烃的至少一个出口，所述搅拌器设置在反应区中并且包含 多个叶片固定地附接到由马达驱动的轴上，所述叶片从反应区域的底部延伸到反应区域的顶部，并且所述轴线在纵向轴线上从反应器底部延伸到顶部 反应器，所述搅拌器以足以促进液体旋转的速度旋转以实现氢氟化反应的发生并使过度氟化最小化。 本发明还涉及所述氢氟化反应器。

    NON-IGNITABLE GASEOUS COMPOSITION COMPRISING DIFLUOROMETHANE AND TETRAFLUOROETHYLENE
    7.
    发明申请
    NON-IGNITABLE GASEOUS COMPOSITION COMPRISING DIFLUOROMETHANE AND TETRAFLUOROETHYLENE 有权
    包含二氟甲磺酸和四氟乙烯的非点燃气体组合物

    公开(公告)号：US20100012900A1

    公开(公告)日：2010-01-21

    申请号：US12439565

    申请日：2007-09-04

    申请人： Barry Asher Mahler

    发明人： Barry Asher Mahler

    IPC分类号： C09K3/00

    CPC分类号： C07C19/08 ,  C07C17/42 ,  C07C21/185

    摘要： The present disclosure relates to non-ignitable gaseous compositions comprising difluoromethane and tetrafluoroethylene. When the pressure is at least 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 111.6−0.124X. When the pressure is less than 150 psig, the molar percentage of tetrafluoroethylene in the non-ignitable gaseous composition is no more than 102−0.06X. X is the pressure in the unit of psig.The present disclosure also provides processes for making such non-ignitable gaseous compositions.Also disclosed are azeotropic compositions of TFE and HFC-32.

    摘要翻译： 本发明涉及包含二氟甲烷和四氟乙烯的不可燃气体组合物。 当压力至少为150psig时​​，不燃点气体组合物中四氟乙烯的摩尔百分数不超过11​​1.6-0.124X。 当压力小于150psig时​​，不燃性气体组合物中四氟乙烯的摩尔百分比不大于102-0.06X。 X是以psig为单位的压力。 本公开还提供了制备这种不可燃气体组合物的方法。 还公开了TFE和HFC-32的共沸组合物。

    Separating 1,1,1,3,3-pentafluoropropane from hydrogen fluoride
    8.
    发明授权
    Separating 1,1,1,3,3-pentafluoropropane from hydrogen fluoride 有权
    从氟化氢分离1,1,1,3,3-五氟丙烷

    公开(公告)号：US06303838B1

    公开(公告)日：2001-10-16

    申请号：US09509859

    申请日：2000-03-31

    申请人： Sara W. Boehmer ,  Barry Asher Mahler ,  Ralph Newton Miller

    发明人： Sara W. Boehmer ,  Barry Asher Mahler ,  Ralph Newton Miller

    IPC分类号： C07C1738

    CPC分类号： C07C17/38 ,  C07C19/08

    摘要： Disclosed are processes for separating 1,1,1,3,3-pentafluoropropane (HFC-245fa) from hydrogen fluoride (HF) by distillation, wherein hydrocarbons, chloroflurocarbons, hydrochlorofluorocarbons and fluorocarbons are used as entraining agents. The processes comprise: contacting a first mixture comprising HFC-245fa and HF with an entraining agent selected from the group consisting of hydrocarbons, chlorofluorocarbons, hydrochlorofluorocarbons and fluorocarbons to form a second mixture, distilling the second mixture and thereby separating the HFC-245fa from HF and entraining agent, and recovering HFC-245fa substantially-free of HF.

    摘要翻译： 公开了通过蒸馏从氟化氢（HF）分离1,1,1,3,3-五氟丙烷（HFC-245fa）的方法，其中使用烃，氯氟烃，氢氯氟烃和碳氟化合物作为夹带剂。 该方法包括：使包含HFC-245fa和HF的第一混合物与选自碳氢化合物，氯氟烃，氢氯氟烃和碳氟化合物的夹带剂接触以形成第二混合物，蒸馏第二混合物，从而将HFC-245fa与HF分离 和夹带剂，并回收基本上不含HF的HFC-245fa。