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    Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups
    5.
    发明授权
    Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups 失效
    具有末端共轭不饱和脂环官能团的共轭二烯的聚合物

    公开(公告)号：US4284741A

    公开(公告)日：1981-08-18

    申请号：US186786

    申请日：1980-09-12

    申请人： Carl A. Uraneck ,  John E. Burleigh

    发明人： Carl A. Uraneck ,  John E. Burleigh

    IPC分类号： C08C19/44 ,  C08F36/04 ,  C08F4/48 ,  C08C19/32 ,  C08C19/40

    CPC分类号： C08C19/44 ,  C08F36/04

    摘要： Alicyclic organomonolithium compounds having delocalized conjugated unsaturation are effective initiators in the preparation of polymers of conjugated dienes. Polymers of conjugated dienes, prepared with or without the alicyclic organomonolithium compounds, are terminated with alicyclic compounds having conjugated unsaturation. Either or both approaches can be used to provide polymers containing alicyclic conjugated unsaturated functional groups. Alternatively, polymers prepared from the alicyclic organomonolithium compounds can be coupled to produce linear or branched polymers. Polymers prepared from multichelic lithium compounds also can be terminated with alicyclic conjugated unsaturated compounds.

    摘要翻译： 具有离域共轭不饱和键的脂环族有机单体锂化合物是制备共轭二烯的聚合物的有效引发剂。 用或不含脂环族有机锂化合物制备的共轭二烯的聚合物用具有共轭不饱和键的脂环族化合物封端。 可以使用这两种方法来提供含有脂环族共轭不饱和官能团的聚合物。 或者，由脂环族有机锂化合物制备的聚合物可以偶联以产生直链或支链聚合物。 由多种锂化合物制备的聚合物也可以用脂环族共轭不饱和化合物封端。

    Cleavable branching agents in emulsion polymerization systems
    8.
    发明授权
    Cleavable branching agents in emulsion polymerization systems 失效
    乳化聚合体系中可裂解的支化剂

    公开(公告)号：US4041227A

    公开(公告)日：1977-08-09

    申请号：US635002

    申请日：1975-11-25

    申请人： Carl A. Uraneck ,  Paul W. Solomon

    发明人： Carl A. Uraneck ,  Paul W. Solomon

    IPC分类号： C08F2/16 ,  C08F4/34 ,  C08F36/04 ,  C08F236/04 ,  C08F2/22 ,  C08F2/38

    CPC分类号： C08F236/04 ,  C08F36/04

    摘要： Bis(1,3-dienyl)dialkyltin, lead, and germanium compounds employed in the aqueous emulsion polymerization of conjugated dienes, optionally with vinyl comonomers, provide polymers with sufficiently high Mooney viscosity values as to be readily handled in plant operations, yet which exhibit controlled breakdown under milling to lower Mooney values suitable, for a variety of uses.

    摘要翻译： 在共轭二烯的水乳液聚合中任选使用乙烯基共聚单体的双（1,3-二烯基）二烷基锡，铅和锗化合物提供具有足够高门尼粘度值的聚合物，以便在工厂操作中容易地处理， 在铣削下控制击穿以降低门尼值适用于各种用途。

    Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups
    9.
    发明授权
    Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups 失效
    具有末端共轭不饱和脂环官能团的共轭二烯的聚合物

    公开(公告)号：US4258162A

    公开(公告)日：1981-03-24

    申请号：US55680

    申请日：1979-07-10

    申请人： Carl A. Uraneck ,  John E. Burleigh

    发明人： Carl A. Uraneck ,  John E. Burleigh

    IPC分类号： C08C19/44 ,  C08F36/04 ,  C08F4/48 ,  C08C19/30 ,  C08C19/32 ,  C08C19/40

    CPC分类号： C08C19/44 ,  C08F36/04

    摘要： Alicyclic organomonolithium compounds having delocalized conjugated unsaturation are effective initiators in the preparation of polymers of conjugated dienes. Polymers of conjugated dienes, prepared with or without the alicyclic organomonolithium compounds, are terminated with alicyclic compounds having conjugated unsaturation. Either or both approaches can be used to provide polymers containing alicylic conjugated unsaturated functional groups. Alternatively, polymers prepared from the alicyclic organomonolithium compounds can be coupled to produce linear or branched polymers. Polymers prepared from multichelic lithium compounds also can be terminated with alicyclic conjugated unsaturated compounds.

    摘要翻译： 具有离域共轭不饱和键的脂环族有机单体锂化合物是制备共轭二烯的聚合物的有效引发剂。 用或不含脂环族有机锂化合物制备的共轭二烯的聚合物用具有共轭不饱和键的脂环族化合物封端。 可以使用这两种方法来提供含有丙烯酸共轭的不饱和官能团的聚合物。 或者，由脂环族有机锂化合物制备的聚合物可以偶联以产生直链或支链聚合物。 由多种锂化合物制备的聚合物也可以用脂环族共轭不饱和化合物封端。

    Emulsion polymerization process utilizing a highly dispersed organosulfur molecular weight modifier
    10.
    发明授权
    Emulsion polymerization process utilizing a highly dispersed organosulfur molecular weight modifier 失效
    使用高度分散的有机硫分子量调节剂的乳液聚合方法

    公开(公告)号：US4245072A

    公开(公告)日：1981-01-13

    申请号：US18092

    申请日：1979-03-06

    申请人： Carl A. Uraneck ,  Earl Clark

    发明人： Carl A. Uraneck ,  Earl Clark

    IPC分类号： C08F2/24 ,  C08F2/38 ,  C08F12/08 ,  C08F12/34

    CPC分类号： C08F2/24

    摘要： A highly dispersed emulsion of an organosulfur compound is obtained by use of a coemulsification system of a surfactant, and an electrolyte, and a cosurfactant and optionally a hydrocarbon; such as a petroleum sulfonate with potassium chloride and hexyl alcohol. Conversion of organosulfur compounds into highly dispersed emulsions increases the reactivity of the organosulfur compound as a molecular weight modifier in an aqueous emulsion polymerization system and permits the efficient use of high molecular weight organosulfur compounds.

    摘要翻译： 通过使用表面活性剂和电解质，辅助表面活性剂和任选的烃的共乳化系统获得有机硫化合物的高度分散的乳液; 例如石油磺酸盐与氯化钾和己醇。 将有机硫化合物转化为高度分散的乳液增加了在水性乳液聚合体系中作为分子量调节剂的有机硫化合物的反应性，并且有效地使用高分子量有机硫化合物。