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1.发明授权Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups 失效具有末端共轭不饱和脂环官能团的共轭二烯的聚合物
公开(公告)号：US4258162A
公开(公告)日：1981-03-24
申请号：US55680
申请日：1979-07-10
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
摘要： Alicyclic organomonolithium compounds having delocalized conjugated unsaturation are effective initiators in the preparation of polymers of conjugated dienes. Polymers of conjugated dienes, prepared with or without the alicyclic organomonolithium compounds, are terminated with alicyclic compounds having conjugated unsaturation. Either or both approaches can be used to provide polymers containing alicylic conjugated unsaturated functional groups. Alternatively, polymers prepared from the alicyclic organomonolithium compounds can be coupled to produce linear or branched polymers. Polymers prepared from multichelic lithium compounds also can be terminated with alicyclic conjugated unsaturated compounds.
摘要翻译： 具有离域共轭不饱和键的脂环族有机单体锂化合物是制备共轭二烯的聚合物的有效引发剂。 用或不含脂环族有机锂化合物制备的共轭二烯的聚合物用具有共轭不饱和键的脂环族化合物封端。 可以使用这两种方法来提供含有丙烯酸共轭的不饱和官能团的聚合物。 或者，由脂环族有机锂化合物制备的聚合物可以偶联以产生直链或支链聚合物。 由多种锂化合物制备的聚合物也可以用脂环族共轭不饱和化合物封端。
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2.发明授权Mixing of organosulfur molecular weight modifier with emulsifier for emulsion polymerization systems 失效将有机硫分子量调节剂与用于乳液聚合体系的乳化剂混合
公开(公告)号：US4125481A
公开(公告)日：1978-11-14
申请号：US825803
申请日：1977-08-18
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
摘要： Organosulfur molecular weight regulators for emulsion polymerization systems, such as mercaptan compounds, are mixed and agitated with the aqueous emulsifier prior to use in emulsion polymerization systems. The modifying efficiency of the organosulfur molecular weight modifiers can be controlled by the degree of agitation. In many cases, adding the agitated mixture incrementally to the emulsion polymerization system further improves effectiveness of the modifier.
摘要翻译： 用于乳液聚合体系的有机硫分子量调节剂如硫醇化合物在用于乳液聚合体系之前与水性乳化剂混合并搅拌。 有机硫分子量调节剂的改性效果可以通过搅拌程度来控制。 在许多情况下，将搅拌的混合物逐渐加入到乳液聚合体系中进一步提高了改性剂的有效性。
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3.发明授权Adhesive formulations incorporating hydroxyl-containing polymers and alkyl silicates, borates or carbonates 失效含有羟基的聚合物和烷基硅酸盐，硼酸盐或碳酸盐的粘合剂配方
公开(公告)号：US4092465A
公开(公告)日：1978-05-30
申请号：US747143
申请日：1976-12-03
申请人： Carl A. Uraneck , John E. Burleigh , Oren L. Marrs
发明人： Carl A. Uraneck , John E. Burleigh , Oren L. Marrs
IPC分类号： C08F236/04 , C08K5/38 , C08K5/54 , C08K5/5419 , C08K5/55 , C08K5/59 , C08L83/04
CPC分类号： C08K5/5419 , C08F236/04 , C08K5/38 , C08K5/54 , C08K5/55 , C08K5/59 , C08L83/04 , C08G77/18
摘要： Pressure-sensitive adhesive incorporates an hydroxyl-containing polymer with alkyl silicon, boron or CO containing compounds. The hydroxyl-containing polymer is a rubbery polymer having an alkadienol constituent.
摘要翻译： 压敏粘合剂含有含羟基的聚合物与烷基硅，含硼或含CO的化合物。 含羟基的聚合物是具有链二烯醇组分的橡胶状聚合物。
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公开(公告)号：US3998998A
公开(公告)日：1976-12-21
申请号：US540570
申请日：1975-01-13
IPC分类号： C08F236/04 , C08F236/14 , C08F220/70 , C08F220/42 , C08F222/30 , C08F234/00
CPC分类号： C08F236/04 , C08F236/14
摘要： Novel copolymers are produced by polymerizing 2,3-dicyano-substituted 1,3-dienes with at least one monomer copolymerizable therewith selected from conjugated dienes and vinylaromatic compounds. Some of the copolymeric products are elastomeric while others are thermosetting.
摘要翻译： 通过将2,3-二氰基取代的1,3-二烯与至少一种可共聚合的单体选自共轭二烯和乙烯基芳族化合物聚合来制备新型共聚物。 一些共聚产物是弹性体，而另一些是热固性的。
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5.发明授权
公开(公告)号：US4537932A
公开(公告)日：1985-08-27
申请号：US636052
申请日：1984-07-30
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
CPC分类号： C08C19/44 , B60C1/0016
摘要： Solution polymerized rubbery conjugated diene homopolymers and copolymers with monovinylarenes are terminated with a hydrocarbyl phosphite or thiophosphite. The phosphite terminated polymers, particularly medium-vinyl polybutadiene, can be incorporated in rubber/carbon black/oil tread stock compounds employing up to 65 parts of rubber per 100 parts of polymer and up to 30 parts of oil per 100 parts of polymer for higher resilience, lower hysteresis, and generally higher tensile strength after vulcanization.
摘要翻译： 溶液聚合的橡胶状共轭二烯均聚物和单乙烯基芳烃的共聚物用亚磷酸烃基或硫代亚磷酸酯封端。 亚磷酸酯封端的聚合物，特别是中乙烯基聚丁二烯，可以加入到每100份聚合物中使用高达65份橡胶的橡胶/炭黑/油性胎面胶料中，每100份聚合物最多使用30份油 弹性，较低的滞后性和硫化后的拉伸强度一般较高。
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公开(公告)号：US4297451A
公开(公告)日：1981-10-27
申请号：US55868
申请日：1979-07-10
CPC分类号： C07F1/02 , C08C19/44 , C08F297/02 , C08F4/488 , C08G81/02
摘要： Polymers are prepared using dienyllithium initiators, a reaction product of organolithium with a 1,4-diolefin, to polymerize olefinically unsaturated monomers such as conjugated dienes under solution polymerization conditions to provide unsaturated polymers, branched polymers, graft polymers, polymers prepared by sequential polymerization, and coupled polymers.
摘要翻译： 使用二烯基锂引发剂（有机锂与1,4-二烯烃的反应产物）在溶液聚合条件下聚合烯属不饱和单体如共轭二烯制备聚合物，以提供不饱和聚合物，支链聚合物，接枝聚合物，通过顺序聚合制备的聚合物， 和偶联聚合物。
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7.发明授权Polymers of conjugated dienes which have terminal conjugated unsaturated alicyclic functional groups 失效具有末端共轭不饱和脂环官能团的共轭二烯的聚合物
公开(公告)号：US4284741A
公开(公告)日：1981-08-18
申请号：US186786
申请日：1980-09-12
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
摘要： Alicyclic organomonolithium compounds having delocalized conjugated unsaturation are effective initiators in the preparation of polymers of conjugated dienes. Polymers of conjugated dienes, prepared with or without the alicyclic organomonolithium compounds, are terminated with alicyclic compounds having conjugated unsaturation. Either or both approaches can be used to provide polymers containing alicyclic conjugated unsaturated functional groups. Alternatively, polymers prepared from the alicyclic organomonolithium compounds can be coupled to produce linear or branched polymers. Polymers prepared from multichelic lithium compounds also can be terminated with alicyclic conjugated unsaturated compounds.
摘要翻译： 具有离域共轭不饱和键的脂环族有机单体锂化合物是制备共轭二烯的聚合物的有效引发剂。 用或不含脂环族有机锂化合物制备的共轭二烯的聚合物用具有共轭不饱和键的脂环族化合物封端。 可以使用这两种方法来提供含有脂环族共轭不饱和官能团的聚合物。 或者，由脂环族有机锂化合物制备的聚合物可以偶联以产生直链或支链聚合物。 由多种锂化合物制备的聚合物也可以用脂环族共轭不饱和化合物封端。
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8.发明授权
公开(公告)号：US4485833A
公开(公告)日：1984-12-04
申请号：US500680
申请日：1983-06-03
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
IPC分类号： C08L7/00 , B60C1/00 , C08C19/24 , C08C19/44 , C08F8/00 , C08F8/40 , C08F236/00 , C08F236/10 , C08L9/06 , C08L21/00
CPC分类号： B60C1/0016 , C08C19/44 , Y10S152/905
摘要： Solution polymerized rubbery conjugated diene homopolymers and copolymers with monovinylarenes are terminated with a hydrocarbyl phosphite or thiophosphite. The phosphite terminated polymers, particularly medium-vinyl polybutadiene, can be incorporated in rubber/carbon black/oil tread stock compounds employing up to 65 parts of rubber per 100 parts of polymer and up to 30 parts of oil per 100 parts of polymer for higher resilience, lower hysteresis, and generally higher tensile strength after vulcanization.
摘要翻译： 溶液聚合的橡胶状共轭二烯均聚物和单乙烯基芳烃的共聚物用亚磷酸烃基或硫代亚磷酸酯封端。 亚磷酸酯封端的聚合物，特别是中乙烯基聚丁二烯，可以加入到每100份聚合物中使用高达65份橡胶的橡胶/炭黑/油性胎面胶料中，每100份聚合物最多使用30份油 弹性，较低的滞后性和硫化后的拉伸强度一般较高。
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公开(公告)号：US4071679A
公开(公告)日：1978-01-31
申请号：US625746
申请日：1975-10-24
IPC分类号： C08F236/14
CPC分类号： C08F236/14
摘要： Copolymers of 2,4-pentadien-1-ol with conjugated dienes, optionally with copolymerizable olefinically unsaturated monomers, are prepared by aqueous emulsion polymerization.
摘要翻译： 通过水乳液聚合制备2,4-戊二烯-1-醇与共轭二烯的共聚物，任选具有可共聚的烯属不饱和单体。
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10.发明授权Mixing of organosulfur molecular weight modifier with emulsifier for emulsion polymerization systems 失效将有机硫分子量调节剂与用于乳液聚合体系的乳化剂混合
公开(公告)号：US4064337A
公开(公告)日：1977-12-20
申请号：US314107
申请日：1972-12-11
申请人： Carl A. Uraneck , John E. Burleigh
发明人： Carl A. Uraneck , John E. Burleigh
摘要： Organosulfur molecular weight regulators for emulsion polymerization systems, such as mercaptan compounds, are mixed and agitated with the aqueous emulsifier prior to use in emulsion polymerization systems. The modifying efficiency of the organosulfur molecular weight modifiers can be controlled by the degree of agitation. In many cases, adding the agitated mixture incrementally to the emulsion polymerization system further improves effectiveness of the modifier.
摘要翻译： 用于乳液聚合体系的有机硫分子量调节剂如硫醇化合物在用于乳液聚合体系之前与水性乳化剂混合并搅拌。 有机硫分子量调节剂的改性效果可以通过搅拌程度来控制。 在许多情况下，将搅拌的混合物逐渐加入到乳液聚合体系中进一步提高了改性剂的有效性。
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