利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

4 条记录 (耗时 0.01 秒)

    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable
    1.
    发明授权
    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable 失效
    制备α，ω-不饱和共轭化合物的聚合物的方法和由此获得的高分子量共轭聚合物

    公开(公告)号：US5917003A

    公开(公告)日：1999-06-29

    申请号：US304134

    申请日：1994-09-12

    申请人： Joanes Gelan ,  Dirk Vanderzande ,  Frank Louwet

    发明人： Joanes Gelan ,  Dirk Vanderzande ,  Frank Louwet

    IPC分类号： H05B33/20 ,  C08G61/00 ,  C08G61/02 ,  C09K11/06 ,  H01L51/50 ,  H05B33/12 ,  C08G69/08

    CPC分类号： C08G61/02

    摘要： A process for producing polymers of .alpha., .omega.-unsaturated conjugated compounds, which includes reacting a compound of the formula (I),B--A--C (I)whereinB denotes a sp.sup.3 -hybridized carbon atom carrying at least one hydrogen atom,A denotes a conjugated-.pi.-system or a --CH.dbd.CH--group, andC denotes a carbon atom carrying at least one leaving group,with a base in a solvent. On reaction of the base with the compound of the formula (I) a polymer is formed as a by-product essentially soluble in the solvent and a solid is formed as a by-product which is essentially insoluble in the solvent. According to the process, chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the process carry groups that undergo elimination, forming double bonds, high quality electroluminescent materials can be prepared.

    摘要翻译： 一种制备α，ω-不饱和共轭化合物的聚合物的方法，其包括使式（I）的化合物，BAC（I），其中B表示携带至少一个氢原子的sp3-杂化的碳原子，A表示共轭 - π系或-CH = CH-基，C表示携带至少一个离去基团的碳原子，在溶剂中含有碱。 在碱与式（I）化合物的反应中，形成聚合物作为基本上可溶于溶剂的副产物，并且固体形成为基本上不溶于溶剂的副产物。 根据该方法，获得了高纯度和高规则性的化学和热稳定的高分子量聚合物。 如果该方法的产物携带消除的组，形成双键，则可以制备高品质的电致发光材料。

    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds
    4.
    发明授权
    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds 失效
    制备α，ω-不饱和共轭化合物的聚合物的方法

    公开(公告)号：US5763539A

    公开(公告)日：1998-06-09

    申请号：US538409

    申请日：1995-10-02

    申请人： Roland Stern ,  Dirk Vanderzande ,  Frank Louwet ,  Joanes Gelan ,  Anna Issaris ,  Michael van der Broght

    发明人： Roland Stern ,  Dirk Vanderzande ,  Frank Louwet ,  Joanes Gelan ,  Anna Issaris ,  Michael van der Broght

    IPC分类号： C08G61/02 ,  C08G61/00 ,  C09K11/06 ,  H05B33/14 ,  C08F283/00

    CPC分类号： H05B33/14 ,  C08G61/00 ,  C09K11/06

    摘要： A process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, comprising reacting a precursor monomer of the formula I, ##STR1## wherein P denotes --SR.sup.3, --SO--R.sup.3, --SO.sub.2 --R.sup.3, --COOR.sup.3, --NO.sub.2, --CN, --CF.sub.3 or R.sup.3 ; L denotes --Cl, --Br, --I, --O-tosylate, --O-mesylate, --O-triflate, --(NR.sup.3.sub.3).sym. or --(SR.sup.3 R.sup.4).sym.; R.sup.1,R.sup.2 are the same or different and denote H, R.sup.3 or P; R.sup.3, R.sup.4 and A are as defined in the application. This reaction is characterized in that, on reaction of the base with the compound of the formula (I), a polymer is formed which is essentially soluble in said solvent, and a salt is formed as a by-product, which is essentially soluble in the solvent. That solvent comprises a compound selected from the group consisting of a) amides of the general formula (II) R.sup.5 --CO--NR.sup.6 H; b) amines of the general formula (III) R.sup.7.sub.2 --N--R.sup.8 ; c) sulfones of the general formula (IV) R.sup.8 --SO.sub.2 --R.sup.9 ; d) sulfoxides of the general formula (V) R.sup.8 --SO--R.sup.9 ; and e) a solvent from the group consisting of alcohols, polyalcohols, glycols and polyethers, where R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 are as defined in the application. The process provides chemically and thermally stable, high molecular weight polymers of high purity and high regularity, in good yield. When the products of the novel process carry groups that undergo elimination to form double bonds, high quality electroluminescent materials can be prepared.

    摘要翻译： 一种制备α，ω-不饱和共轭化合物的聚合物的方法，包括使式I的前体单体，其中P表示-SR 3，-SO-R 3，-SO 2 -R 3，-COOR 3， - NO 2，-CN，-CF 3或R 3; L表示-Cl，-Br，-I，-O-甲苯磺酸酯，-O-甲磺酸酯，-O-三氟甲磺酸酯， - （NR33）（+）或 - （SR3R4）（+）; R1，R2相同或不同，表示H，R3或P; R3，R4和A如申请中所定义。 该反应的特征在于，在碱与式（I）化合物的反应中，形成基本上可溶于所述溶剂的聚合物，并且盐形成为副产物，其基本上可溶于 溶剂。 该溶剂包括选自以下的化合物：a）通式（II）的酰胺R5-CO-NR6H; b）通式（III）的胺R72-N-R8; c）通式（Ⅳ）的砜：R8-SO2-R9; d）通式（V）的基团：R8-SO-R9; 和e）来自醇，多元醇，二醇和聚醚的溶剂，其中R 5，R 6，R 7，R 8和R 9如本申请中所定义。 该方法以高纯度和高规则性提供化学和热稳定的高分子量聚合物，产率高。 当新工艺的产物携带经过消除形成双键的基团时，可以制备高品质的电致发光材料。