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    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable
    1.
    发明授权
    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable 失效
    制备α，ω-不饱和共轭化合物的聚合物的方法和由此获得的高分子量共轭聚合物

    公开(公告)号：US5917003A

    公开(公告)日：1999-06-29

    申请号：US304134

    申请日：1994-09-12

    申请人： Joanes Gelan ,  Dirk Vanderzande ,  Frank Louwet

    发明人： Joanes Gelan ,  Dirk Vanderzande ,  Frank Louwet

    IPC分类号： H05B33/20 ,  C08G61/00 ,  C08G61/02 ,  C09K11/06 ,  H01L51/50 ,  H05B33/12 ,  C08G69/08

    CPC分类号： C08G61/02

    摘要： A process for producing polymers of .alpha., .omega.-unsaturated conjugated compounds, which includes reacting a compound of the formula (I),B--A--C (I)whereinB denotes a sp.sup.3 -hybridized carbon atom carrying at least one hydrogen atom,A denotes a conjugated-.pi.-system or a --CH.dbd.CH--group, andC denotes a carbon atom carrying at least one leaving group,with a base in a solvent. On reaction of the base with the compound of the formula (I) a polymer is formed as a by-product essentially soluble in the solvent and a solid is formed as a by-product which is essentially insoluble in the solvent. According to the process, chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the process carry groups that undergo elimination, forming double bonds, high quality electroluminescent materials can be prepared.

    摘要翻译： 一种制备α，ω-不饱和共轭化合物的聚合物的方法，其包括使式（I）的化合物，BAC（I），其中B表示携带至少一个氢原子的sp3-杂化的碳原子，A表示共轭 - π系或-CH = CH-基，C表示携带至少一个离去基团的碳原子，在溶剂中含有碱。 在碱与式（I）化合物的反应中，形成聚合物作为基本上可溶于溶剂的副产物，并且固体形成为基本上不溶于溶剂的副产物。 根据该方法，获得了高纯度和高规则性的化学和热稳定的高分子量聚合物。 如果该方法的产物携带消除的组，形成双键，则可以制备高品质的电致发光材料。

    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds
    2.
    发明授权
    Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds 失效
    制备α，ω-不饱和共轭化合物的聚合物的方法

    公开(公告)号：US5763539A

    公开(公告)日：1998-06-09

    申请号：US538409

    申请日：1995-10-02

    申请人： Roland Stern ,  Dirk Vanderzande ,  Frank Louwet ,  Joanes Gelan ,  Anna Issaris ,  Michael van der Broght

    发明人： Roland Stern ,  Dirk Vanderzande ,  Frank Louwet ,  Joanes Gelan ,  Anna Issaris ,  Michael van der Broght

    IPC分类号： C08G61/02 ,  C08G61/00 ,  C09K11/06 ,  H05B33/14 ,  C08F283/00

    CPC分类号： H05B33/14 ,  C08G61/00 ,  C09K11/06

    摘要： A process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, comprising reacting a precursor monomer of the formula I, ##STR1## wherein P denotes --SR.sup.3, --SO--R.sup.3, --SO.sub.2 --R.sup.3, --COOR.sup.3, --NO.sub.2, --CN, --CF.sub.3 or R.sup.3 ; L denotes --Cl, --Br, --I, --O-tosylate, --O-mesylate, --O-triflate, --(NR.sup.3.sub.3).sym. or --(SR.sup.3 R.sup.4).sym.; R.sup.1,R.sup.2 are the same or different and denote H, R.sup.3 or P; R.sup.3, R.sup.4 and A are as defined in the application. This reaction is characterized in that, on reaction of the base with the compound of the formula (I), a polymer is formed which is essentially soluble in said solvent, and a salt is formed as a by-product, which is essentially soluble in the solvent. That solvent comprises a compound selected from the group consisting of a) amides of the general formula (II) R.sup.5 --CO--NR.sup.6 H; b) amines of the general formula (III) R.sup.7.sub.2 --N--R.sup.8 ; c) sulfones of the general formula (IV) R.sup.8 --SO.sub.2 --R.sup.9 ; d) sulfoxides of the general formula (V) R.sup.8 --SO--R.sup.9 ; and e) a solvent from the group consisting of alcohols, polyalcohols, glycols and polyethers, where R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 are as defined in the application. The process provides chemically and thermally stable, high molecular weight polymers of high purity and high regularity, in good yield. When the products of the novel process carry groups that undergo elimination to form double bonds, high quality electroluminescent materials can be prepared.

    摘要翻译： 一种制备α，ω-不饱和共轭化合物的聚合物的方法，包括使式I的前体单体，其中P表示-SR 3，-SO-R 3，-SO 2 -R 3，-COOR 3， - NO 2，-CN，-CF 3或R 3; L表示-Cl，-Br，-I，-O-甲苯磺酸酯，-O-甲磺酸酯，-O-三氟甲磺酸酯， - （NR33）（+）或 - （SR3R4）（+）; R1，R2相同或不同，表示H，R3或P; R3，R4和A如申请中所定义。 该反应的特征在于，在碱与式（I）化合物的反应中，形成基本上可溶于所述溶剂的聚合物，并且盐形成为副产物，其基本上可溶于 溶剂。 该溶剂包括选自以下的化合物：a）通式（II）的酰胺R5-CO-NR6H; b）通式（III）的胺R72-N-R8; c）通式（Ⅳ）的砜：R8-SO2-R9; d）通式（V）的基团：R8-SO-R9; 和e）来自醇，多元醇，二醇和聚醚的溶剂，其中R 5，R 6，R 7，R 8和R 9如本申请中所定义。 该方法以高纯度和高规则性提供化学和热稳定的高分子量聚合物，产率高。 当新工艺的产物携带经过消除形成双键的基团时，可以制备高品质的电致发光材料。

    Method of preparing derivatives of polyarylene vinylene and method of preparing an electronic device including same
    5.
    发明授权
    Method of preparing derivatives of polyarylene vinylene and method of preparing an electronic device including same 有权
    聚亚芳基亚乙烯基衍生物的制备方法及其制备方法

    公开(公告)号：US07511116B2

    公开(公告)日：2009-03-31

    申请号：US11779640

    申请日：2007-07-18

    申请人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    发明人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    IPC分类号： C08G75/12 ,  C08G75/00

    CPC分类号： C08F28/02 ,  C08F28/06 ,  C08F126/06 ,  C08F128/06 ,  C08F228/02 ,  C08F290/14 ,  C08G61/02 ,  C08G61/12 ,  C08G61/126 ,  H01L51/0035 ,  H01L51/0038 ,  Y02E10/549 ,  Y10S428/917

    摘要： A technique is described for the preparation of polymers according to a process in which the starting compound of formula (I) is polymerized in the presence of a base in an organic solvent. No end chain controlling agents are required during the polymerisation to obtain soluble precursor polymers. The precursor polymer such obtained comprises structural units of the formula (II). In a next step, the precursor polymer (II) is subjected to a conversion reaction towards a soluble or insoluble conjugated polymer by thermal treatment. The arylene or heteroarylene polymer comprises structural units of the formula III. In this process the dithiocarbamate group acts as a leaving group and permits the formation of a precursor polymer of structural formula (II), which has an average molecular weight from 5000 to 1000000 Dalton and is soluble in common organic solvents. The precursor polymer with structural units of formula (II) is thermally converted to the conjugated polymer with structural formula (III).

    摘要翻译： 描述了根据其中在碱存在下在有机溶剂中使式（I）的起始化合物聚合的方法制备聚合物的技术。 在聚合期间不需要端链控制剂以获得可溶性前体聚合物。 所得前体聚合物包括式（II）的结构单元。 在下一步骤中，前体聚合物（II）通过热处理对可溶或不溶性共轭聚合物进行转化反应。 亚芳基或亚杂芳基聚合物包含式III的结构单元。 在该方法中，二硫代氨基甲酸酯基团用作离去基团，并且允许形成结构式（II）的前体聚合物，其具有5000至1000000道尔顿的平均分子量，并且可溶于常见的有机溶剂。 将具有式（II）结构单元的前体聚合物热转化为具有结构式（III）的共轭聚合物。

    METHOD OF PREPARING DERIVATIVES OF POLYARYLENE VINYLENE AND METHOD OF PREPARING AN ELECTRONIC DEVICE INCLUDING SAME
    6.
    发明申请
    METHOD OF PREPARING DERIVATIVES OF POLYARYLENE VINYLENE AND METHOD OF PREPARING AN ELECTRONIC DEVICE INCLUDING SAME 有权
    制备聚乙烯乙烯衍生物的方法及其制备包括其的电子设备的方法

    公开(公告)号：US20070287816A1

    公开(公告)日：2007-12-13

    申请号：US11779548

    申请日：2007-07-18

    申请人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    发明人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    IPC分类号： C08F228/02

    CPC分类号： C08F28/02 ,  C08F28/06 ,  C08F126/06 ,  C08F128/06 ,  C08F228/02 ,  C08F290/14 ,  C08G61/02 ,  C08G61/12 ,  C08G61/126 ,  H01L51/0035 ,  H01L51/0038 ,  Y02E10/549 ,  Y10S428/917

    摘要： A technique is described for the preparation of polymers according to a process in which the starting compound of formula (I) is polymerized in the presence of a base in an organic solvent. No end chain controlling agents are required during the polymerisation to obtain soluble precursor polymers. The precursor polymer such obtained comprises structural units of the formula (II). In a next step, the precursor polymer (II) is subjected to a conversion reaction towards a soluble or insoluble conjugated polymer by thermal treatment. The arylene or heteroarylene polymer comprises structural units of the formula III. In this process the dithiocarbamate group acts as a leaving group and permits the formation of a precursor polymer of structural formula (II), which has an average molecular weight from 5000 to 1000000 Dalton and is soluble in common organic solvents. The precursor polymer with structural units of formula (II) is thermally converted to the conjugated polymer with structural formula (III).

    摘要翻译： 描述了根据其中在碱存在下在有机溶剂中使式（I）的起始化合物聚合的方法制备聚合物的技术。 在聚合期间不需要端链控制剂以获得可溶性前体聚合物。 所得前体聚合物包括式（II）的结构单元。 在下一步骤中，前体聚合物（II）通过热处理对可溶性或不溶性共轭聚合物进行转化反应。 亚芳基或亚杂芳基聚合物包含式III的结构单元。 在该方法中，二硫代氨基甲酸酯基团用作离去基团，并且允许形成结构式（II）的前体聚合物，其具有5000至1000000道尔顿的平均分子量，并且可溶于常见的有机溶剂。 将具有式（II）结构单元的前体聚合物热转化为具有结构式（III）的共轭聚合物。

    Conjugated polymers provided with at least one molecular imprinted polymer and a method for their preparation via conjugated macro-iniferters
    7.
    发明申请
    Conjugated polymers provided with at least one molecular imprinted polymer and a method for their preparation via conjugated macro-iniferters 有权
    提供至少一种分子印迹聚合物的共轭聚合物及其通过共轭大分子引发剂制备的方法

    公开(公告)号：US20060079648A1

    公开(公告)日：2006-04-13

    申请号：US11247397

    申请日：2005-10-11

    申请人： Laurence Lutsen ,  Dirk Vanderzande

    发明人： Laurence Lutsen ,  Dirk Vanderzande

    IPC分类号： C08F297/02

    CPC分类号： C08F291/00 ,  C08F289/00 ,  C08L51/08 ,  C08L2666/02

    摘要： The present invention provides a conjugated polymer with provided thereon at least one molecular imprinted polymer (MIP) and a method for preparing such a polymer. The conjugate polymer provided with at least one MIP according to the invention combines both transducer properties and selectivity properties in one single material. Therefore, it is particularly suitable for use in chemo- or bio-sensors. Furthermore, the conjugate polymer provided with at least one MIP may be used in electronic devices and in chromatography, molecular recognition, selective sample enrichment or in catalysis.

    摘要翻译： 本发明提供了在其上提供至少一种分子印迹聚合物（MIP）的共轭聚合物及其制备方法。 根据本发明提供至少一个MIP的共轭聚合物在一种单一材料中结合了换能器性质和选择性。 因此，它特别适用于化学或生物传感器。 此外，提供至少一个MIP的共轭聚合物可以用于电子器件中，也可用于色谱法，分子识别，选择性样品富集或催化。

    Method of preparing derivatives of polyarylene vinylene and method of preparing an electronic device including same
    8.
    发明申请
    Method of preparing derivatives of polyarylene vinylene and method of preparing an electronic device including same 有权
    聚亚芳基亚乙烯基衍生物的制备方法及其制备方法

    公开(公告)号：US20050159581A1

    公开(公告)日：2005-07-21

    申请号：US10971784

    申请日：2004-10-21

    申请人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    发明人： Dirk Vanderzande ,  Laurence Lutsen ,  Anja Henckens ,  Kristof Colladet

    IPC分类号： C08G61/02 ,  C08G61/12 ,  C08G75/30

    CPC分类号： C08F28/02 ,  C08F28/06 ,  C08F126/06 ,  C08F128/06 ,  C08F228/02 ,  C08F290/14 ,  C08G61/02 ,  C08G61/12 ,  C08G61/126 ,  H01L51/0035 ,  H01L51/0038 ,  Y02E10/549 ,  Y10S428/917

    摘要： A technique is described for the preparation of polymers according to a process in which the starting compound of formula (I) is polymerized in the presence of a base in an organic solvent. No end chain controlling agents are required during the polymerisation to obtain soluble precursor polymers. The precursor polymer such obtained comprises structural units of the formula (II). In a next step, the precursor polymer (II) is subjected to a conversion reaction towards a soluble or insoluble conjugated polymer by thermal treatment. The arylene or heteroarylene polymer comprises structural units of the formula III. In this process the dithiocarbamate group acts as a leaving group and permits the formation of a precursor polymer of structural formula (II), which has an average molecular weight from 5000 to 1000000 Dalton and is soluble in common organic solvents. The precursor polymer with structural units of formula (II) is thermally converted to the conjugated polymer with structural formula (III).

    摘要翻译： 描述了根据其中在碱存在下在有机溶剂中使式（I）的起始化合物聚合的方法制备聚合物的技术。 在聚合期间不需要端链控制剂以获得可溶性前体聚合物。 所得前体聚合物包括式（II）的结构单元。 在下一步骤中，前体聚合物（II）通过热处理对可溶性或不溶性共轭聚合物进行转化反应。 亚芳基或亚杂芳基聚合物包含式III的结构单元。 在该方法中，二硫代氨基甲酸酯基团用作离去基团，并且允许形成结构式（II）的前体聚合物，其具有5000至1000000道尔顿的平均分子量，并且可溶于常见的有机溶剂。 将具有式（II）结构单元的前体聚合物热转化为具有结构式（III）的共轭聚合物。

    POLYTHIOPHENE BASED ACTIVE LAYER FOR SOLAR CELLS
    9.
    发明申请
    POLYTHIOPHENE BASED ACTIVE LAYER FOR SOLAR CELLS 有权
    基于聚硅氧烷的活性层用于太阳能电池

    公开(公告)号：US20120279569A1

    公开(公告)日：2012-11-08

    申请号：US13491934

    申请日：2012-06-08

    申请人： Laurence Lutsen ,  Dirk Vanderzande ,  Bert Campo

    发明人： Laurence Lutsen ,  Dirk Vanderzande ,  Bert Campo

    IPC分类号： C08G75/06 ,  H01L51/46 ,  C08L81/02 ,  C07D333/24 ,  B82Y30/00

    CPC分类号： C07D333/28 ,  B82Y10/00 ,  C08G61/126 ,  C08G2261/1412 ,  C08G2261/1426 ,  C08G2261/3223 ,  C08G2261/91 ,  C08K3/04 ,  C08L65/00 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549 ,  Y02P70/521

    摘要： New monomers, polymers, and blends of polymers with an electron acceptor are provided, e.g., for use in a photovoltaic device. The electron acceptor can be a fullerene derivative and the polymer can comprise monomer units according to the formula: wherein L′ is L-C(O)O-J, L-C(O)NR′-J, L-OCO-J′, L-NR′CO-J′, L-SCO-J′, L-O-J, L-S-J, L-Se-J, L-NR′-J or L-CN; L is a linear or branched alkylene group having from 1 to 10 carbon atoms; J is a hydrogen atom or a linear or branched alkyl group having from 1 to 4 carbon atoms; J′ is a group having from 1 to 10 carbon atoms, being saturated or unsaturated, linear or branched, optionally comprising a phenyl unit; and R′ is a hydrogen atom or a linear or branched alkyl group having from 1 to 4 carbon atoms.

    摘要翻译： 提供了新的单体，聚合物和聚合物与电子受体的共混物，例如用于光伏器件。 电子受体可以是富勒烯衍生物，聚合物可以包含下式的单体单元：其中L'是LC（O）OJ，LC（O）NR'-J，L-OCO-J'，L-NR' CO-J'，L-SCO-J'，LOJ，LSJ，L-Se-J，L-NR'-J或L-CN; L是具有1至10个碳原子的直链或支链亚烷基; J是氢原子或具有1至4个碳原子的直链或支链烷基; J'是具有1至10个碳原子的基团，其是饱和或不饱和的，直链或支链的，任选地包含苯基单元; 并且R'是氢原子或具有1至4个碳原子的直链或支链烷基。

    METHODS FOR CONTROLLING THE CRYSTALLINE NANOFIBRE CONTENT OF ORGANIC LAYERS USED IN ORGANIC ELECTRONIC DEVICES
    10.
    发明申请
    METHODS FOR CONTROLLING THE CRYSTALLINE NANOFIBRE CONTENT OF ORGANIC LAYERS USED IN ORGANIC ELECTRONIC DEVICES 有权
    用于控制有机电子设备中使用的有机层的晶体纳米粒子含量的方法

    公开(公告)号：US20110237020A1

    公开(公告)日：2011-09-29

    申请号：US13132304

    申请日：2009-12-18

    申请人： Laurence Lutsen ,  Wilbren Oosterbaan ,  Sabine Bertho ,  Dirk Vanderzande

    发明人： Laurence Lutsen ,  Wilbren Oosterbaan ,  Sabine Bertho ,  Dirk Vanderzande

    IPC分类号： H01L51/30

    CPC分类号： H01L51/0012 ,  C08G2261/141 ,  C08G2261/212 ,  C08G2261/3223 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

    摘要： The present invention relates in a first aspect to methods for producing a nanofibres-containing layer for use as an active layer in an organic electronic device. The method comprising the steps of: a) first heating up a nanofibre-forming polymer in a solvent at a temperature T1, then b) cooling said solution down to a temperature T2 at a rate less than 40° C./h thereby forming a dispersion comprising crystalline nanofibres of said nanofibre-forming polymer, then c) raising the temperature of said dispersion to a temperature T3 higher than T2, but lower than said temperature T1, and then d) coating said dispersion on a substrate at said temperature T3 thereby forming a layer for use as an element of said organic electronic device, wherein before step (d), a step of adding an electron acceptor to the solution or dispersion is performed.

    摘要翻译： 本发明在第一方面涉及用于生产用于有机电子器件中的有源层的含纳米纤维的层的方法。 该方法包括以下步骤：a）首先在温度T1下在溶剂中加热纳米纤维形成聚合物，然后b）以低于40℃/小时的速率将所述溶液冷却至温度T2，从而形成 然后c）将所述分散体的温度升高到高于T2但低于所述温度T1的温度T3，然后d）在所述温度T3下将所述分散体涂覆在基底上，从而使所述分散体包含所述纳米纤维形成聚合物的晶体纳米纤维 形成用作所述有机电子器件的元件的层，其中在步骤（d）之前，进行将电子受体加入到溶液或分散体中的步骤。