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1.发明申请公开(公告)号：US20120280186A1
公开(公告)日：2012-11-08
申请号：US13502564
申请日：2010-09-06
摘要： Provided are a composite of nanoparticles of a metal such as gold, silver, a platinum metal, or copper, and a polymer, the composite allowing formation of a metal film having a sufficiently low resistivity in terms of practicality simply by drying at room temperature without requiring any special heating-baking step or any step of removing a protective agent with a solvent; a dispersion liquid of the composite; methods for producing the foregoing; and a plastic substrate formed from the dispersion liquid. When a dispersion liquid of a metal-nanoparticle-containing composite that is prepared by reducing metal ions in an aqueous medium in the presence of a (meth)acrylic-based copolymer having, as side chains, a polyethylene glycol chain and a phosphate residue represented by —OP(O)(OH)2 and having, at at least one end of the molecular chain, —SR (where R represents an alkyl group or the like), is applied to a base material and is then just dried at room temperature, a film having conductivity is formed.
摘要翻译： 提供了金属，金，铂金属或铜等金属的纳米颗粒与聚合物的复合物，该复合物简单地通过在室温下干燥而形成具有足够低的电阻率的金属膜，而没有 需要任何特殊的加热烘烤步骤或用溶剂去除保护剂的任何步骤; 复合材料的分散液; 生产上述方法; 以及由分散液形成的塑料基板。 当含有金属纳米粒子的复合材料的分散液体是通过在含有作为侧链的聚乙二醇链和磷酸酯残基的（甲基）丙烯酸类共聚物存在下在水性介质中还原金属离子制备的， 通过-OP（O）（OH）2，并且在分子链的至少一个末端具有-SR（其中R表示烷基等），并在室温下进行干燥 形成具有导电性的膜。
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2.发明授权Metal-nanoparticle-containing composite, dispersion liquid thereof, and methods for producing the metal-nanoparticle-containing composite and the dispersion liquid 有权含有金属纳米颗粒的复合物，其分散液，以及制备含金属纳米颗粒的复合物和分散液的方法公开(公告)号：US08388870B2
公开(公告)日：2013-03-05
申请号：US13502564
申请日：2010-09-06
摘要： Provided are a composite of nanoparticles of a metal such as gold, silver, a platinum metal, or copper, and a polymer, the composite allowing formation of a metal film having a sufficiently low resistivity in terms of practicality simply by drying at room temperature without requiring any special heating-baking step or any step of removing a protective agent with a solvent; a dispersion liquid of the composite; methods for producing the foregoing; and a plastic substrate formed from the dispersion liquid. The composite comprises a (meth)acrylic-based copolymer having, as side chains, a polyethylene glycol chain and a phosphate residue represented by —OP(O)(OH)2 and having, at at least one end of the molecular chain, —SR (where R represents an alkyl group or the like).
摘要翻译： 提供了金属，金，铂金属或铜等金属的纳米颗粒与聚合物的复合物，该复合物简单地通过在室温下干燥而形成具有足够低的电阻率的金属膜，而没有 需要任何特殊的加热烘烤步骤或用溶剂去除保护剂的任何步骤; 复合材料的分散液; 生产上述方法; 以及由分散液形成的塑料基板。 该复合材料包含（甲基）丙烯酸类共聚物，其具有作为侧链的聚乙二醇链和由-OP（O）（OH）2表示的磷酸酯残基，并且在分子链的至少一端具有 - SR（其中R表示烷基等）。
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3.发明授权Composite of organic compound and copper nanoparticles, composite of organic compound and copper(I) oxide nanoparticles, and methods for producing the composites 有权有机化合物和铜纳米颗粒的复合物，有机化合物和氧化铜（I）纳米粒子的复合材料，以及复合材料的制备方法公开(公告)号：US08530559B2
公开(公告)日：2013-09-10
申请号：US13634344
申请日：2011-02-28
申请人： Yoshiyuki Sano , Ren-Hua Jin , Kaori Kawamura , Masafumi Uota
发明人： Yoshiyuki Sano , Ren-Hua Jin , Kaori Kawamura , Masafumi Uota
IPC分类号： C08K3/10
CPC分类号： C07F1/08 , B22F1/0018 , B22F1/02 , B22F9/24 , B82Y30/00 , B82Y40/00 , C01G3/02 , C01P2002/72 , C01P2004/64 , C07C323/12 , C07C323/20 , C07C323/52 , Y10S977/773 , Y10S977/896
摘要： Provided is a composite including copper nanoparticles or copper(I) oxide nanoparticles and a thioether-containing organic compound represented by X(OCH2CHR1)nOCH2CH(OH)CH2SZ [X represents an alkyl group; R1 represents a hydrogen atom or a methyl group; n represents an integer of 2 to 100; R1 is independent between repeating units and may be the same or different; and Z represents an alkyl group, an allyl group, an aryl group, an arylalkyl group, —R2—OH, —R2—NHR3, or —R2—(COR4)m (where R2 represents a saturated hydrocarbon group; R3 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group, or a benzyloxycarbonyl group; R4 represents a hydroxy group, an alkyl group, or an alkoxy group; and m represents 1 to 3)]. Provided is a method for producing a composite of an organic compound and copper nanoparticles or a composite of an organic compound and copper(I) oxide nanoparticles, the method including reducing a copper compound in the presence of a thioether-containing organic compound represented by the general formula (1) above.
摘要翻译： 提供了包含铜纳米颗粒或氧化铜（I）纳米颗粒和由X（OCH 2 CHR 1）n OCH 2 CH（OH）CH 2 SZ表示的含硫醚的有机化合物[X表示烷基; R1表示氢原子或甲基; n表示2〜100的整数， R1在重复单元之间是独立的，可以相同或不同; Z表示烷基，烯丙基，芳基，芳烷基，-R 2 -OH，-R 2 -NHR 3或-R 2 - （COR 4）m（其中，R 2表示饱和烃基; R 3表示氢 原子，酰基，烷氧基羰基或苄氧基羰基; R 4表示羟基，烷基或烷氧基，m表示1〜3）]。 本发明提供一种有机化合物和铜纳米粒子的复合体的制造方法或有机化合物与氧化铜（I）纳米粒子的复合体的制造方法，其特征在于，在含有硫化物的有机化合物 上述通式（1）。
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4.发明申请COMPOSITE OF ORGANIC COMPOUND AND COPPER NANOPARTICLES, COMPOSITE OF ORGANIC COMPOUND AND COPPER(I) OXIDE NANOPARTICLES, AND METHODS FOR PRODUCING THE COMPOSITES 有权有机化合物和铜纳米粒子的组合物，有机化合物和铜（I）氧化物纳米颗粒的复合物，以及用于生产复合材料的方法公开(公告)号：US20130095320A1
公开(公告)日：2013-04-18
申请号：US13634344
申请日：2011-02-28
申请人： Yoshiyuki Sano , Ren-Hua Jin , Kaori Kawamura , Masafumi Uota
发明人： Yoshiyuki Sano , Ren-Hua Jin , Kaori Kawamura , Masafumi Uota
IPC分类号： C07F1/08
CPC分类号： C07F1/08 , B22F1/0018 , B22F1/02 , B22F9/24 , B82Y30/00 , B82Y40/00 , C01G3/02 , C01P2002/72 , C01P2004/64 , C07C323/12 , C07C323/20 , C07C323/52 , Y10S977/773 , Y10S977/896
摘要： Provided is a composite including copper nanoparticles or copper(I) oxide nanoparticles and a thioether-containing organic compound represented by X(OCH2CHR1)nOCH2CH(OH)CH2SZ [X represents an alkyl group; R1 represents a hydrogen atom or a methyl group; n represents an integer of 2 to 100; R1 is independent between repeating units and may be the same or different; and Z represents an alkyl group, an allyl group, an aryl group, an arylalkyl group, —R2—OH, —R2—NHR3, or —R2—(COR4)m (where R2 represents a saturated hydrocarbon group; R3 represents a hydrogen atom, an acyl group, an alkoxycarbonyl group, or a benzyloxycarbonyl group; R4 represents a hydroxy group, an alkyl group, or an alkoxy group; and m represents 1 to 3)]. Provided is a method for producing a composite of an organic compound and copper nanoparticles or a composite of an organic compound and copper(I) oxide nanoparticles, the method including reducing a copper compound in the presence of a thioether-containing organic compound represented by the general formula (1) above.
摘要翻译： 提供了包含铜纳米颗粒或氧化铜（I）纳米颗粒和由X（OCH 2 CHR 1）n OCH 2 CH（OH）CH 2 SZ表示的含硫醚的有机化合物[X表示烷基; R1表示氢原子或甲基; n表示2〜100的整数， R1在重复单元之间是独立的，可以相同或不同; Z表示烷基，烯丙基，芳基，芳基烷基，-R 2 -OH，-R 2 -NHR 3或-R 2 - （COR 4）m（其中，R 2表示饱和烃基; R 3表示氢 原子，酰基，烷氧基羰基或苄氧基羰基; R 4表示羟基，烷基或烷氧基，m表示1〜3）]。 本发明提供一种有机化合物和铜纳米粒子的复合体的制造方法或有机化合物与氧化铜（I）纳米粒子的复合体的制造方法，其特征在于，在含有硫化物的有机化合物 上述通式（1）。
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