Production method of sulfur-modified polyacrylonitrile

    公开(公告)号:US12209156B2

    公开(公告)日:2025-01-28

    申请号:US17763839

    申请日:2020-09-14

    Abstract: The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).

    Nonaqueous electrolyte and nonaqueous secondary battery

    公开(公告)号:US10096858B2

    公开(公告)日:2018-10-09

    申请号:US15109902

    申请日:2015-03-06

    Abstract: Provided are a nonaqueous electrolyte excellent in the prevention of overcharge and capable of retaining a small internal resistance and a high electrical capacity even after charge/discharge cycles and a nonaqueous secondary battery using the same. Specifically, the nonaqueous electrolyte is a lithium salt solution in an organic solvent and contains at least one compound having general formula (1), and the nonaqueous secondary battery includes a negative electrode capable of intercalating and deintercalating lithium, a positive electrode containing a transition metal and lithium, and the nonaqueous electrolyte. The details of formula (1) are also provided.

    Organo sulfur-based electrode active material

    公开(公告)号:US11594732B2

    公开(公告)日:2023-02-28

    申请号:US16960782

    申请日:2019-02-25

    Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

    Non-aqueous electrolyte, and non-aqueous electrolyte secondary cell

    公开(公告)号:US10388989B2

    公开(公告)日:2019-08-20

    申请号:US15549441

    申请日:2016-03-02

    Abstract: A nonaqueous electrolyte having a lithium salt dissolved in an organic solvent and a nonaqueous secondary battery using the same are disclosed. The nonaqueous electrolyte is characterized by containing (A) at least one compound represented by general formula (1) (wherein symbols are as defined in the description) and (B) at least one compound having two or more groups selected from a vinyl group, an allyl group, and a propargyl group per molecule. Component (B) is preferably a compound having an ethylenically and acetylenically unsaturated bond equivalent of 150 or smaller.

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