公开(公告)号：US09812263B2

公开(公告)日：2017-11-07

申请号：US15081023

申请日：2016-03-25

申请人： ADEKA CORPORATION

发明人： Minoru Hanaya ,  Kenji Kakiage ,  Masafumi Unno ,  Yohei Aoyama ,  Toru Yano ,  Daisuke Sawamoto ,  Hiroyuki Osada

IPC分类号： H01L31/04 ,  H01G9/20 ,  H01L51/00 ,  C07F17/02 ,  C07F7/18 ,  H01L31/0256 ,  C09B1/16 ,  C09B23/01 ,  C09B23/14 ,  C09B23/16 ,  C09B29/08 ,  C09B57/00

CPC分类号： H01G9/2059 ,  C07F7/1804 ,  C07F17/02 ,  C09B1/16 ,  C09B23/0075 ,  C09B23/14 ,  C09B23/145 ,  C09B23/164 ,  C09B29/0808 ,  C09B57/00 ,  H01G9/2031 ,  H01L31/0256 ,  H01L51/005 ,  H01L51/0052 ,  H01L51/0055 ,  H01L51/006 ,  H01L51/0061 ,  H01L51/0065 ,  H01L51/0068 ,  H01L51/007 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0083 ,  H01L51/0094 ,  Y02E10/542

摘要： Disclosed is a novel compound represented by formula (1) below. In the formula, A represents an optionally substituted aromatic hydrocarbon ring or aromatic heterocyclic group, B represents a group including a chain of one to four pieces of one or more groups selected from groups represented by specific formulae (B-1) to (B-13) (such as —C═C— or —N═N—, specifically see the description), R1 to R3 each represent an optionally substituted hydrocarbon or hydrocarbonoxy group, at least one of R1 to R3 represents an optionally substituted hydrocarbonoxy group, R4 and R5 each represent an optionally substituted hydrocarbon group, R4 and R5 may be linked together to form a ring, and R4 and R5 may be each independently linked with A to form a ring

公开(公告)号：US09805879B2

公开(公告)日：2017-10-31

申请号：US14353661

申请日：2012-11-27

申请人： ADEKA CORPORATION

发明人： Kensaku Akimoto ,  Toru Yano ,  Koichi Sakamaki

IPC分类号： H01G9/20 ,  H01L51/00 ,  C09B69/00 ,  C07F15/00 ,  C07F17/02 ,  C07F7/18

CPC分类号： H01G9/204 ,  C07F7/1804 ,  C07F15/0053 ,  C07F17/02 ,  C09B69/008 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0064 ,  H01L51/0086 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/0094 ,  Y02E10/542 ,  Y02E10/549

摘要： A dye-sensitized solar cell including a working electrode having a photocatalytic film, a counter electrode, and an electrolyte-containing layer or solid charge-transfer layer containing a basic compound, wherein the photocatalytic film includes an oxide semiconductor layer containing a dye compound represented by the following formula (1), wherein Y is an optionally substituted hydrocarbon group having 1 to 20 carbon atoms and having —CO—NR4— or —SO2—NR4— in the group, or a direct bond, Z is a conjugated group, R1, R2, and R3 each represent an optionally substituted hydrocarbon group or an optionally substituted hydrocarbonoxy group, at least one of R1, R2, and R3 is an optionally substituted hydrocarbonoxy group, and R4 represents a hydrogen atom or an optionally substituted hydrocarbon group having 1 to 20 carbon atoms.

公开(公告)号：US10734684B2

公开(公告)日：2020-08-04

申请号：US15749513

申请日：2016-09-14

申请人： ADEKA CORPORATION

发明人： Yuta Nohara ,  Kenji Kakiage ,  Tomofumi Yokomizo ,  Hiroaki Watanabe ,  Yohei Aoyama ,  Toru Yano

IPC分类号： H01M10/0567 ,  C07F7/18 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/42

摘要： Disclosed is a nonaqueous secondary battery having a nonaqueous electrolyte containing a lithium salt dissolved in an organic solvent, in which the positive electrode active material is preferably a manganese-containing, lithium transition metal oxide salt. The nonaqueous electrolyte contains at least one compound of general formula (1), preferably at least one compound of general formula (1′). The content of the compound of formula (1) or (1′) in the nonaqueous electrolyte is preferably 0.001 to 10 mass %. The symbols in formulae (1) and (1′) are as defined in the description.

公开(公告)号：US10096858B2

公开(公告)日：2018-10-09

申请号：US15109902

申请日：2015-03-06

申请人： ADEKA CORPORATION

发明人： Tomofumi Yokomizo ,  Toru Yano ,  Hiroaki Watanabe ,  Yohei Aoyama ,  Tomomi Seri ,  Yuta Nohara

IPC分类号： H01M10/0567 ,  H01M10/0525

摘要： Provided are a nonaqueous electrolyte excellent in the prevention of overcharge and capable of retaining a small internal resistance and a high electrical capacity even after charge/discharge cycles and a nonaqueous secondary battery using the same. Specifically, the nonaqueous electrolyte is a lithium salt solution in an organic solvent and contains at least one compound having general formula (1), and the nonaqueous secondary battery includes a negative electrode capable of intercalating and deintercalating lithium, a positive electrode containing a transition metal and lithium, and the nonaqueous electrolyte. The details of formula (1) are also provided.

公开(公告)号：US20140252278A1

公开(公告)日：2014-09-11

申请号：US14236225

申请日：2012-10-22

申请人： ADEKA CORPORATION

发明人： Mineki Hasegawa ,  Toru Yano ,  Ryo Taniuchi

IPC分类号： H01L31/0256

CPC分类号： H01L31/0256 ,  B82Y10/00 ,  C07D493/06 ,  C08G61/125 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/312 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3242 ,  C08G2261/3246 ,  C08G2261/3327 ,  C08G2261/3328 ,  C08G2261/344 ,  C08G2261/364 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253 ,  H01L2031/0344 ,  Y02E10/549

摘要： Disclosed is a p-type organic semiconductive material that is easy to produce and that has a high planarity in its polymer skeleton, and also provides a photoelectric conversion material, a photoelectric conversion layer, a photoelectric conversion element, and an organic thin film solar cell each having high photoelectric conversion efficiency and using the p-type organic semiconductive material. Specifically, the invention provides a bibenzo[b]furan compound having at least one constitutional unit represented by the following formula (1) or (2), as well as a photoelectric conversion material, a photoelectric conversion layer, a photoelectric conversion element, and an organic thin film solar cell each using that compound for a p-type organic semiconductive material. (In the formulae, R13 and R14 each represent a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, an optionally substituted hydrocarbon group, an optionally substituted hydrocarbonoxy group, or an optionally substituted heterocyclic group.)

摘要翻译： 公开了易于生产并且在其聚合物骨架中具有高平坦度的p型有机半导体材料，并且还提供了光电转换材料，光电转换层，光电转换元件和有机薄膜太阳能电池 各自具有高的光电转换效率并且使用p型有机半导体材料。 具体地说，本发明提供具有由下式（1）或（2）表示的至少一个结构单元的双苯并[b]呋喃化合物，以及光电转换材料，光电转换层，光电转换元件和 每个使用该化合物用于p型有机半导体材料的有机薄膜太阳能电池。 （式中，R 13和R 14分别表示氢原子，氟原子，氯原子，溴原子，碘原子，任意取代的烃基，任意取代的烃氧基或任意取代的杂环基。

公开(公告)号：US20150034162A1

公开(公告)日：2015-02-05

申请号：US14387417

申请日：2013-03-27

申请人： ADEKA CORPORATION

发明人： Sadakazu Hirose ,  Toshiyuki Okamoto ,  Miwa Matsune ,  Toru Yano ,  Hiroyuki Osada ,  Yohei Aoyama

IPC分类号： H01G9/20 ,  H01L51/00

CPC分类号： H01G9/2063 ,  C07D209/14 ,  C07D209/24 ,  C07D209/32 ,  C07D417/14 ,  C09B23/0058 ,  C09B23/04 ,  C09B23/083 ,  C09B23/148 ,  C09B67/0033 ,  H01G9/2027 ,  H01G9/2031 ,  H01G9/204 ,  H01G9/2095 ,  H01L51/0064 ,  H01L51/0069 ,  H01L51/0072 ,  H01L2251/308 ,  Y02E10/542 ,  Y02E10/549 ,  Y02P70/521

摘要： A dye-sensitized solar cell and a method for making the same allow for greatly broadening the light absorption wavelength range without using a metal complex dye, thereby achieving excellent photovoltaic characteristics. The dye-sensitized solar cell includes a photoelectrode having a substrate, a transparent conductive layer on the substrate, and a metal oxide porous layer containing metal oxide particles on the transparent conductive layer. The metal oxide porous layer has sensitizing dyes adsorbed thereon. The sensitizing dyes include an organic cyanine dye and an indoline dye having an indoline structure. The organic cyanine dye and the indoline dye are supported by the metal oxide porous layer in a plurality of levels such that the organic cyanine dye is present in a higher concentration than the indoline dye on the surface of the metal oxide particles.

摘要翻译： 染料敏化太阳能电池及其制造方法允许在不使用金属络合染料的情况下大大地拓宽光吸收波长范围，从而获得优异的光电特性。 染料敏化太阳能电池包括具有基板的光电极，基板上的透明导电层和在透明导电层上含有金属氧化物颗粒的金属氧化物多孔层。 金属氧化物多孔层具有吸附在其上的敏化染料。 敏化染料包括有机花青染料和具有二氢吲哚结构的二氢吲哚染料。 有机花青染料和二氢吲哚染料由金属氧化物多孔层以多个水平负载，使得有机花青染料以比金属氧化物颗粒表面上的二氢吲哚染料更高的浓度存在。

公开(公告)号：US20140299191A1

公开(公告)日：2014-10-09

申请号：US14353661

申请日：2012-11-27

申请人： ADEKA CORPORATION

发明人： Kensaku Akimoto ,  Toru Yano ,  Koichi Sakamaki

IPC分类号： H01G9/20

CPC分类号： H01G9/204 ,  C07F7/1804 ,  C07F15/0053 ,  C07F17/02 ,  C09B69/008 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0064 ,  H01L51/0086 ,  H01L51/0091 ,  H01L51/0092 ,  H01L51/0094 ,  Y02E10/542 ,  Y02E10/549

摘要： A dye-sensitized solar cell including a working electrode having a photocatalytic film, a counter electrode, and an electrolyte-containing layer or solid charge-transfer layer containing a basic compound, wherein the photocatalytic film includes an oxide semiconductor layer containing a dye compound represented by the following formula (1), wherein Y is an optionally substituted hydrocarbon group having 1 to 20 carbon atoms and having —CO—NR4— or —SO2—NR4— in the group, or a direct bond, Z is a conjugated group, R1, R2, and R3 each represent an optionally substituted hydrocarbon group or an optionally substituted hydrocarbonoxy group, at least one of R1, R2, and R3 is an optionally substituted hydrocarbonoxy group, and R4 represents a hydrogen atom or an optionally substituted hydrocarbon group having 1 to 20 carbon atoms.

摘要翻译： 1.一种染料敏化太阳能电池，包括具有光催化膜的工作电极，对电极和含电解质的层或含有碱性化合物的固体电荷转移层，其中所述光催化膜包括含有代表性的染料化合物的氧化物半导体层 通式（1）中，Y为碳原子数1〜20的可具有取代基的烃基，-CO-NR4-或-SO2-NR4-，或直接键合，Z为共轭基团， R 1，R 2和R 3各自表示任选取代的烃基或任选取代的烃氧基，R 1，R 2和R 3中的至少一个是任选取代的烃氧基，并且R 4表示氢原子或任选取代的具有 1至20个碳原子。

公开(公告)号：US09450119B2

公开(公告)日：2016-09-20

申请号：US14236225

申请日：2012-10-22

申请人： ADEKA CORPORATION

发明人： Mineki Hasegawa ,  Toru Yano ,  Ryo Taniuchi

IPC分类号： H01L51/42 ,  H01L31/0256 ,  C07D493/06 ,  C08G61/12 ,  H01L51/00 ,  B82Y10/00

CPC分类号： H01L31/0256 ,  B82Y10/00 ,  C07D493/06 ,  C08G61/125 ,  C08G2261/1412 ,  C08G2261/1424 ,  C08G2261/312 ,  C08G2261/3223 ,  C08G2261/3241 ,  C08G2261/3242 ,  C08G2261/3246 ,  C08G2261/3327 ,  C08G2261/3328 ,  C08G2261/344 ,  C08G2261/364 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253 ,  H01L2031/0344 ,  Y02E10/549

摘要： Disclosed is a p-type organic semiconductive material that is easy to produce and that has a high planarity in its polymer skeleton, and also provides a photoelectric conversion material, a photoelectric conversion layer, a photoelectric conversion element, and an organic thin film solar cell each having high photoelectric conversion efficiency and using the p-type organic semiconductive material. Specifically, the invention provides a bibenzo[b]furan compound having at least one constitutional unit represented by the following formula (1) or (2), as well as a photoelectric conversion material, a photoelectric conversion layer, a photoelectric conversion element, and an organic thin film solar cell each using that compound for a p-type organic semiconductive material. (In the formulae, R13 and R14 each represent a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, an optionally substituted hydrocarbon group, an optionally substituted hydrocarbonoxy group, or an optionally substituted heterocyclic group.)

摘要翻译： 公开了易于生产并且在其聚合物骨架中具有高平坦度的p型有机半导体材料，并且还提供了光电转换材料，光电转换层，光电转换元件和有机薄膜太阳能电池 各自具有高的光电转换效率并且使用p型有机半导体材料。 具体地说，本发明提供具有由下式（1）或（2）表示的至少一个结构单元的双苯并[b]呋喃化合物，以及光电转换材料，光电转换层，光电转换元件和 每个使用该化合物用于p型有机半导体材料的有机薄膜太阳能电池。 （式中，R 13和R 14分别表示氢原子，氟原子，氯原子，溴原子，碘原子，任意取代的烃基，任意取代的烃氧基或任意取代的杂环基。