Carrier system and photoelectric conversion device

    公开(公告)号:US10141118B2

    公开(公告)日:2018-11-27

    申请号:US15108912

    申请日:2015-01-26

    Abstract: A carrier system carries a dye (A) and a co-adsorbent (B) represented by general formula (1): wherein, ring A represents a 5- or 6-membered heterocycle and may further be fused; a hydrogen atom in the ring A may be replaced by a halogen atom, a cyano group, a nitro group, an —OR2 group, an —SR2 group, or a hydrocarbon group that may have a substituent; Z represents a divalent aliphatic hydrocarbon group that is interrupted zero to three times by —O— etc.; Z1 represents a divalent aromatic group; R1 represents a carboxylic acid group, a sulfonic acid group, a phosphoric acid group, or a phosphonic acid group; R2 and R3 each represent a hydrogen atom or a hydrocarbon group that may have a substituent; Anm− represents an m-valent anion; m represents an integer of 1 or 2; and p represents a coefficient for keeping the electrical charge neutral.

    Organo sulfur-based electrode active material

    公开(公告)号:US11594732B2

    公开(公告)日:2023-02-28

    申请号:US16960782

    申请日:2019-02-25

    Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.

    DYE-SENSITIZED SOLAR CELL AND METHOD FOR MAKING SAME
    6.
    发明申请
    DYE-SENSITIZED SOLAR CELL AND METHOD FOR MAKING SAME 审中-公开
    透明的太阳能电池及其制造方法

    公开(公告)号:US20150034162A1

    公开(公告)日:2015-02-05

    申请号:US14387417

    申请日:2013-03-27

    Abstract: A dye-sensitized solar cell and a method for making the same allow for greatly broadening the light absorption wavelength range without using a metal complex dye, thereby achieving excellent photovoltaic characteristics. The dye-sensitized solar cell includes a photoelectrode having a substrate, a transparent conductive layer on the substrate, and a metal oxide porous layer containing metal oxide particles on the transparent conductive layer. The metal oxide porous layer has sensitizing dyes adsorbed thereon. The sensitizing dyes include an organic cyanine dye and an indoline dye having an indoline structure. The organic cyanine dye and the indoline dye are supported by the metal oxide porous layer in a plurality of levels such that the organic cyanine dye is present in a higher concentration than the indoline dye on the surface of the metal oxide particles.

    Abstract translation: 染料敏化太阳能电池及其制造方法允许在不使用金属络合染料的情况下大大地拓宽光吸收波长范围,从而获得优异的光电特性。 染料敏化太阳能电池包括具有基板的光电极,基板上的透明导电层和在透明导电层上含有金属氧化物颗粒的金属氧化物多孔层。 金属氧化物多孔层具有吸附在其上的敏化染料。 敏化染料包括有机花青染料和具有二氢吲哚结构的二氢吲哚染料。 有机花青染料和二氢吲哚染料由金属氧化物多孔层以多个水平负载,使得有机花青染料以比金属氧化物颗粒表面上的二氢吲哚染料更高的浓度存在。

    NOVEL COMPOUND AND SUPPORT MATERIAL SUPPORTING THIS NOVEL COMPOUND
    7.
    发明申请
    NOVEL COMPOUND AND SUPPORT MATERIAL SUPPORTING THIS NOVEL COMPOUND 有权
    新型化合物和支持材料支持本新化合物

    公开(公告)号:US20140261647A1

    公开(公告)日:2014-09-18

    申请号:US14350171

    申请日:2012-08-21

    Abstract: A novel compound represented by general formula (1), a support supporting this novel compound, and a photoelectric transduction element using this support. (In the formula, Y is an optionally substituted hydrocarbon group having 1-20 carbon atoms having —CO—NR4- or —SO2—NR4- in the group; Z is a group of a conjugated system; R1, R2, and R3 represent optionally substituted hydrocarbon groups or optionally substituted hydrocarbon-oxy groups; at least one of R1, R2, and R3 is an optionally substituted hydrocarbon-oxy group; R4 represents a hydrogen atom or an optionally substituted hydrocarbon group having 1-20 carbon atoms; R4 and Z may join together to form a ring. However, Y excludes groups represented by partial structural formulas (Y-11) and (Y-12).)

    Abstract translation: 由通式(1)表示的新化合物,支持该新型化合物的载体和使用该载体的光电转导元件。 (式中,Y为在基团中具有-CO-NR4-或-SO2-NR4-具有1-20个碳原子的任选取代的烃基; Z是共轭体系的基团; R1,R2和R3表示 任选取代的烃基或任选取代的烃 - 氧基; R 1,R 2和R 3中的至少一个是任选取代的烃 - 氧基; R 4表示氢原子或具有1-20个碳原子的任选取代的烃基; R 4 Z可以结合形成环,但Y不包括由部分结构式(Y-11)和(Y-12)表示的基团。

    NOVEL COMPOUND AND CARRIER SYSTEM HAVING THE COMPOUND
    10.
    发明申请
    NOVEL COMPOUND AND CARRIER SYSTEM HAVING THE COMPOUND 有权
    具有化合物的新型化合物和载体体系

    公开(公告)号:US20140353553A1

    公开(公告)日:2014-12-04

    申请号:US14372462

    申请日:2013-02-27

    Abstract: A novel compound represented by general formula (1), a carrier system including a carrier having the novel compound fixed thereon, and a photoelectric conversion device having the carrier system. In formula (1), Z is a C1-C50 conjugated group; R1 is a C6-C20 aromatic hydrocarbon group, a C7-C20 aromatic hydrocarbon group substituted by an aliphatic hydrocarbon group, or a C1-C20 aliphatic hydrocarbon group, each substituted by carboxyl, cyano, amino, amide, or nitro, the aliphatic hydrocarbon group being optionally interrupted by —O—, etc.; R2 is hydrogen or an optionally substituted C1-C20 hydrocarbon group; R30, R31, R32, R33, R40, R41, R42, R43, and R44 are each hydrogen or optionally substituted hydrocarbon group, and adjacent two of them may be connected to form a ring; R5 is hydrogen or cyano; and R11 is represented by formula (11-1) or (11-2), wherein n, ring A, and the like are as defined in the description.

    Abstract translation: 由通式(1)表示的新型化合物,包含固定有新化合物的载体的载体体系和具有载体体系的光电转换装置。 在式(1)中,Z为C1-C50共轭基团; R1是C6-C20芳族烃基,被脂肪族烃基取代的C7-C20芳族烃基,或被羧基,氰基,氨基,酰胺或硝基取代的C1-C20脂族烃基,脂族烃 基团任选被-O-间断等; R2是氢或任选取代的C 1 -C 20烃基; R 30,R 31,R 32,R 33,R 40,R 41,R 42,R 43和R 44各自为氢或任选取代的烃基,并且其中相邻的两个可以连接形成环; R5是氢或氰基; 并且R 11由式(11-1)或(11-2)表示,其中n,环A等如说明书中所定义。

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