公开(公告)号：US3761501A

公开(公告)日：1973-09-25

申请号：US3761501D

申请日：1971-06-02

Applicant: ALLIED CHEM

Inventor： WOOLF C ,  DEAR R ,  YOUNG D

IPC: C07C119/04

CPC classification number: C07C261/02

Abstract: Tertiary perfluoroalkyl cyanates are prepared by reacting the corresponding tertiary perfluoroalkoxide with cyanogen chloride or cyanogen bromide. The cyanates are novel compounds useful as intermediates in the preparation of low surface energy compounds useful as repellent coatings.

Abstract translation: 通过使相应的叔全氟烷氧基与氯化氰或溴化氰反应来制备三级全氟烷基氰酸酯。 氰酸酯是可用作中间体的新型化合物，用于制备用作驱避剂涂层的低表面能化合物。

公开(公告)号：US3755405A

公开(公告)日：1973-08-28

申请号：US3755405D

申请日：1968-10-30

Applicant: ALLIED CHEM

Inventor： GOULD D ,  YOUNG D ,  FOX W

IPC: C07C71/00 ,  A01N31/02 ,  A01N51/00 ,  C07C67/00 ,  C07C69/96 ,  C07C201/00 ,  C08F4/00 ,  D06L3/06 ,  F16B7/04

CPC classification number: A01N51/00 ,  C07C71/00 ,  D06L4/20

Abstract: TERTIARY POLYFLUOROALKYL HYPOCHLORITES OF THE FORMULA:

R-(OCI)N

WHEREIN N IS 1 OR 2, R CONTAINS AT LEAST FOUR CARBON ATOMS AND IS AN OPEN CHAN YZ-PERFLUOROALKYL GROUP WHEN N IS 1, R IS AN OPEN CHAIN YZ-PERFLUOROALKYLENE GROUP WHEN N IS 2, WHEREIN Y AND Z ARE SUBSTITUENTS ON THE R MOIETY AND ARE THE SAME OR DIFFERENT ELECTRONEGATIVE GROUPS SELECTED FROM F, FSO2, FSO3, NO2, PERFLUOROALKYL, PERFLUOROCYCLOALKYL AND PERFLUOROARYL, WITH THE PROVISO THAT THE CARBON ATOM OR ATOMS ATTACHED TO THE -OCL GROUP OR GROUPS ARE EACH BONDED TO THREE OTHER CARBON ATOMS; MAY BE PREPARED BY REACTING CORRESPONDING TERTIARY ALCOHOLS WITH CHLORINE MONOFLUORIDE (CIF). THE NOVEL TERTIARY POLYFLUOROALKYL HYPOCHLORITES ARE USEFUL AS POLYMERIZATION INITIATORS, AS CHLORINATING AGENTS, AS BLEACHING AGENTS AND ARE VALUABLE INTERMEDIATES FOR THE SYNTHESIS OF OTHER USEFUL COMPOUNDS.

公开(公告)号：US3732274A

公开(公告)日：1973-05-08

申请号：US3732274D

申请日：1969-08-25

Applicant: ALLIED CHEM

Inventor： YOUNG D ,  ANDERSON L ,  GOULD D ,  FOX W

IPC: A01N47/02 ,  C07C69/64 ,  A01N9/12

CPC classification number: A01N47/02

Abstract: HYDROGEN CONTAINING FLUOROALKYL CHLOFORMATES OF FORMULA:

R3COC(O)CL

WHEREIN R IS SELECTED FROM THE GROUP CONSISTING OF HYDROGEN, ALKYL, FLUOROALKYL AND ARYL WITH THE PROVISO THAT AT LEAST ONE R SUBSTITUENT IS FLUOROALKYL, AND AT LEAST ONE CARBON-HYDROGEN BOND IS PRESENT IN THE MOLECULE. THE ALKYL AND FLUOROALKYL MOIETIES MAY BE MADE UP OF THE SAME OF A DIFFERENT NUMBER OF CARBON ATOMS AND EACH MAY CONTAIN UP TO SIX CARBONS (LOWER ALKYL), IN A STRAIGHT OR BRANCHED CHAIN STRUCTURE AND WHEN R CONTAINS SIX CARBON ATOMS, IT MAY REPRESENT CYCLIC ALKYL. THESE NOVEL HYDROGEN CONTAINING FLUORINATED CHLOROFORMATE PRODUCTS BELONG TO A CLASS OF HALOGENATED ALKYL CHLOROFORMATES, BEING USEFUL AS INTERMEDIATES FOR THE PREPARATION OF CORRESPONDING CARBONATE ESTERS, PEROXIDES, AS POLYMERIZATION CATALYSTS AND AS INSECTICIDES AND FUMIGANTS. THESE NOVEL HYDROGEN CONTAINING FLUORINATED CHLOROFORMATES MAY BE PREPARED BY REACTING THE CORRESPONDING HYPOCHLORITE HAVING THE FORMULA:

R3COCL

WHEREIN R IS DEFINED AS ABOVE, WITH CARBON MONOXIDE AT A TEMPERATURE OF UP TO 75*C., OR HIGHER. THIS METHOD MAY ALSO BE USED TO PREPARE TERTIARY PERFLUORINATED ALKYL CHLOROFORMATES HAVING NO HYDROGEN-TO-CARBON BONDS IN THE MOLECULE.

公开(公告)号：US3716570A

公开(公告)日：1973-02-13

申请号：US3716570D

申请日：1969-06-05

Applicant: ALLIED CHEM

Inventor： GOULD D ,  ANDERSON L ,  YOUNG D ,  FOX W

IPC: A01N31/02 ,  A01N51/00 ,  C07C31/34 ,  C07C67/00 ,  C07C71/00 ,  C07C201/00 ,  C08F4/00 ,  C11D7/54

CPC classification number: C07C71/00 ,  A01N51/00 ,  C07C31/34

Abstract: Hydrogen containing fluoroalkyl hypochlorites of the formula:

Abstract translation: 含有下式的含氟烷基次氯酸盐：R3COCl，其中每个R可以是氢，低级烷基，芳基和氟烷基，条件是至少一个R取代基是氟代烷基，一个R取代基含有至少一个氢原子。 烷基和氟烷基部分可以含有相同或不同数目的碳原子，并且每个碳原子可以含有至多六个碳（低级烷基），直链或支链结构，当R含有六个碳原子时，它可以代表脂环族 部分。 这些含氢氟烷基次氯酸盐的新型氢可以通过在不存在催化剂的情况下使相应的醇与一氯氟化物（ClF）反应来制备。 这些化合物可用作聚合引发剂，氯化剂，漂白剂，并且是用于合成其它有用化合物的有价值的中间体。

公开(公告)号：US3842156A

公开(公告)日：1974-10-15

申请号：US77792068

申请日：1968-11-21

Applicant: ALLIED CHEM

Inventor： ANDERSON L ,  FOX W ,  YOUNG D ,  GOULD D

IPC: A01N31/02 ,  B01J21/00 ,  B01J31/00 ,  C01B17/45 ,  C01B17/46 ,  C07B61/00 ,  C07C67/00 ,  C07C71/00 ,  C07C201/00

CPC classification number: C01B17/4561 ,  C07C71/00

Abstract: 1. IN THE PROCESS FOR PREPARING HYPOCHLORITIES COMPRISING REACTING A STARTING COMPOUND SELECTED FROM THE GROUP CONSISTING OF SOF4 AND A COMPOUND CONTAINING AT LEAST 4 ATOMS AND HAVING ONE OF THE FOLLOWING FORMULAE:

R''-CO-R'' OR F-CO-X-CO-F

WHEREIN R'' IS FLUROINE OR AN OPEN-CHAIN PERHALOALKYL GROUP AND X IS AN OPEN CHAIN PERHALOALKYLENE GROUP AND WHEREIN THE MINIMUM NUMBER OF FLUORIDE ATOMS IS AT LEAST EQUAL TO ONE HALF THE TOTAL NUMBER OF HALOGEN ATOMS, WITH CIF; THE IMPROVEMENT WHICH CONSISTS OF CATALYZING THE REACTION BY INTRODUCING CATALYTIC AMOUNTS OF A COMPOUND SELECTED FROM THE GROUP CONSISTING OF GASEOUS HF, GASEOUS BF3, GASEOUS ASF5 AND SBF5.