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公开(公告)号：US3664988A
公开(公告)日：1972-05-23
申请号：US3664988D
申请日：1969-12-05
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , PFANNMUELLER HELMUT , GROPPER HANS , GIERTH VOLKER , BECK GILBERT
Abstract: A process for the production of ethylene copolymers containing hydroxyl groups which contain polymerized units of ethylene, an alkenol and if desired other monomers copolymerizable with ethylene, by copolymerization of a mixture of ethylene, alkenol and the other copolymerizable monomer(s), if any, at superatmospheric pressure and elevated temperature under the action of a free-radical polymerization initiator in the presence or absence of a polymerization regulator. 3-methyl-3-buten-1-ol is used as the alkenol. The process has the advantage that it is more easily carried out than comparable prior art methods and that it gives copolymers containing a relatively high proportion of polymerized units of alkenol.
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公开(公告)号：US3917577A
公开(公告)日：1975-11-04
申请号：US17532471
申请日：1971-08-26
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , PFANNMUELLER HELMUT , URBAN FRIEDRICH , BUECHNER OSKAR , STEIGERWALD KLAUS , BALL WOLFGANG
IPC: C08F110/02 , C08F4/34 , C08F10/02
CPC classification number: C08F110/02 , C08F2/34 , C08F2/38
Abstract: A process for the continuous production of ethylene homopolymers by polymerization of ethylene by means of a polymerization initiator and a polymerization regulator at elevated temperature and superatmospheric pressure in a tubular reactor having two or three successive reaction zones, a mixture of ethylene, the polymerization initiator and the polymerization regulator being introduced continuously at the beginning of each reaction zone. It is characteristic of the process according to the invention that special conditions as regards temperature, pressure, polymerization initiator and polymerization regulator are maintained in the individual reaction zones.
Abstract translation: 在具有两个或三个连续反应区域的管式反应器中，通过聚合引发剂和聚合调节剂在升高的温度和超大气压下聚合乙烯来连续生产乙烯均聚物的方法，乙烯，聚合引发剂和 聚合调节剂在每个反应区的开始处连续引入。 根据本发明的方法的特征在于，在各个反应区域中保持关于温度，压力，聚合引发剂和聚合调节剂的特殊条件。
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公开(公告)号：US3657211A
公开(公告)日：1972-04-18
申请号：US3657211D
申请日：1970-02-11
Applicant: BASF AG
Inventor： STEIGERWALD KLAUS , BUECHNER OSKAR , URBAN FRIEDRICH , PFANNMUELLER HELMUT
Abstract: PRODUCTION OF ETHYLENE HOMOPLYMERS BY POLYMERIZATION OF ETHYLENE UNDER THE ACTION OF ORGANIC HYDROPEROXIDES AND OXYGEN AS FREE-RADICAL-GENERATING POLYMERIZATION INTIATORS AND POLYMERIZATION MODIFIRES AT ELEVATED TEMPERATURE AND SUPERATMOSPHERIC PRESSURE IN A TUBULAR REACTOR HAVING TWO SUCCESSIVE REACTION ZONES, A MIXTURE OF ETHYLENE, POLYMERIZATION INITIATOR AND POLYMERIZATION MODIFIER BEING INTRODUCED CONTINUOUSLY AT THE BEGINNING OF EACH REACTION ZONE. SPECIFIC TEMPERATURE CONDITIONS, A HYDROPEROXIDE HAVING A SPECIFIC RELATIVELY HIGH HALF VALUE TEMPERATURE AND A POLYMERIZATION MODIFIER HAVING A SPECIFIC RELATIVELY HIGH CS-VALUE ARE USED IN THE FIRST REACTION ZONE, AND SPECIFIC TEMPERATURE CONDITIONS, OXYGEN AND A POLYMERIZATION MODIIRE HAVING A SPECIFIC RELATIVELY HIGH CS-VALUE ARE EMPLOYED IN THE SECOND ZONE. THE ETHYLENE HOMOPOLYMERS OBTAINED HAVE A NARROW MOLECULAR WEIGHT DISTRIBUTION AND ARE PRACTICALLY DEVOID OF VERY HIGH MOLECULAR WEIGHT CONSTITUENTS.
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公开(公告)号：US3631017A
公开(公告)日：1971-12-28
申请号：US3631017D
申请日：1970-01-27
Applicant: BASF AG
Inventor： RETTIG AUGUST , BALL WOLFGANG , ZIZLSPERGER JOHANN , URBAN FRIEDRICH , PFANNMUELLER HELMUT
IPC: B29B7/00 , B29B13/02 , B29C47/00 , B29C47/80 , B29C47/82 , B29C47/92 , C08L23/06 , C08F27/00 , C08F27/28
CPC classification number: B29B13/022 , B29C47/0021 , B29C47/0023 , B29C47/0026 , B29C47/786 , B29C47/822 , C08L23/06
Abstract: A METHOD OF AFTER-TREATING HIGH-PRESSURE POLYETHYLENE IN SHEARING UNIT, WHEREIN THE HIGH-PRESSURE POLYETHYLENE IS INTRODUCED INTO THE SHEARING UNIT AT 200* TO 300*C. AND A VISCOSITY OF 5X10**3 TO 1X10**5 POISES AND SUBJECTED TO A SHEARING GRADIENT, THE SHEARING SURFACES CONTACTING THE POLYETHYLENE MELT BEING HEATED A TEMPERATURE WHICH IS AT LEAST AS HIGH AS THAT OF THE POLYETHYLENE MELT AND THE POLYETHYLENE MELT BEING SHEARED AT SUCH A SHEARING SPEED THAT THE PRODUCT OF SHEARING SPEED AND RESIDENCE TIME IN THE SHEARING ZONE IS EQUAL TO 5X10**2 TO 5X10**4.
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公开(公告)号：US3547866A
公开(公告)日：1970-12-15
申请号：US3547866D
申请日：1968-08-27
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , ZEITLER GERHARD , DICKAEUSER HEINER , REUTER LOTHAR , PFANNMUELLER HELMUT
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Patent Agency Ranking6.发明授权Production of polyethylene under high pressure with methyl isobutyl ketone peroxide initiator 失效用甲基异丁基酮过氧化物引发剂在高压下生产聚乙烯
公开(公告)号：US3660370A
公开(公告)日：1972-05-02
申请号：US3660370D
申请日：1970-08-17
Applicant: BASF AG
Inventor： GROPPER HANS , STARK KURT , PFANNMUELLER HELMUT , URBAN FRIEDRICH
Abstract: A PROCESS FOR POLYMERIZING ETHYLENE AT PRESSURES OF MORE THAN 1000 ATMOSPHERES AND AT TEMPERATURES OF FROM 150* TO 400*C. IN THE PRESENCE OF METHYL ISOBUTYL KETONE PEROXIDE. POLYETHYLENE HAVING A DENSITY OF FROM 0.924 TO 0.935 G/CCM. IS OBTAINED IN HIGHER YIELDS THAN IN CONVENTIONAL METHODS; IT IS USED FOR THE PRODUCTION OF TRANSPARENT FILM AND SHEETING.
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7.发明授权Polymerization of propylene with ziegler catalysts in a stirred ga phase reactor 失效丙烯与ZIEGLER催化剂在刺激相态反应器中的聚合
公开(公告)号：US3652527A
公开(公告)日：1972-03-28
申请号：US3652527D
申请日：1969-10-27
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , RAU WOLFGANG , JACOBSEN THEODOR , PFANNMUELLER HELMUT
IPC: B01J8/10 , B01J8/20 , C08F110/06 , C08F1/42 , C08F3/08
CPC classification number: B01J8/20 , B01J8/10 , C08F110/06 , Y10S526/904 , C08F2/34
Abstract: A PROCESS FOR THE POLYMERIZATION OF PROPYLENE IN THE GAS PHASE IN A BED OF POWDERED POLYPROPYLENE BY MEANS OF A CATALYST SYSTEM OF: (A) A SOLUTION OF AN ALUMINUM ALKYL IN A HYDROCARBON; AND (B) A SUSPENSION OF A TITANIUM OR VANADIUM HALIDE COMPOUND IN A HYDROCARBON; IN WHICH THE TWO COMPONENTS (A) AND (B) ARE SUPPLIED SEPARATELY TO THE REACTION ZONE.
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公开(公告)号：US3632532A
公开(公告)日：1972-01-04
申请号：US3632532D
申请日：1968-08-14
Applicant: BASF AG
Inventor： GAETH RUDOLF , PFANNMUELLER HELMUT , STASTNY FRITZ , TRIESCHMANN HANS-GEORGE , TATZEL HERMANN , ZIZLSPERGER JOHANN
CPC classification number: C08J9/0028 , C08G18/6204 , C08G2101/0041 , C08J2323/08 , Y10S521/908
Abstract: PRODUCTION OF EXPANDED MATERIAL BY MIXING COPOLYMERS OF ETHYLENE WITH POLYISOCYANATES AND EXPANDING AGENTS UNDER PRESSURE AND DECOMPRESSING THE HOMOGENEOUS MIXTURES.
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公开(公告)号：US3597408A
公开(公告)日：1971-08-03
申请号：US3597408D
申请日：1968-08-26
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , ZEITLER GERHARD , REUTER LOTHAR , DICKHAEUSER HEINER , PFANNMUELLER HELMUT
Abstract: A CONTINUOUS PROCESS FOR THE CHLORINATION OF RELATIVELY COARSE PARTICLED HIGH PRESSURE POLYETHYLENE AS A SUSPENSION OF 2-6 MM. PARTICLES IN A LIQUID CHLOROHYDROCARBON WITH WITHDRAWAL OF THE CHLORINATED POLYETHYLENE AS A SOLUTION IN THE CHLOROHYDROCARBON.
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10.发明授权
公开(公告)号：US3903203A
公开(公告)日：1975-09-02
申请号：US40428373
申请日：1973-11-05
Applicant: BASF AG
Inventor： TRIESCHMANN HANS-GEORG , PFANNMUELLER HELMUT , URBAN FRIEDRICH , BUECHNER OSKAR , FAUTH KARL-HEINZ , GIERTH VOLKER , PFLEGER KLAUS
CPC classification number: C08L23/0869 , C08L25/06 , C08L25/12 , C08L2205/02 , C08L2205/03 , C08L2666/02
Abstract: Film having improved transparency prepared from a mixture of an ethylene polymer and from 0.05 to 1.0 percent by weight (based on the mixture) of a copolymer of styrene, a graft copolymer of styrene, a homopolymer of propylene or a copolymer of propylene and ethylene; the film may be used as packaging material.
Abstract translation: 由乙烯聚合物的混合物制备的具有改善的透明性的薄膜和苯乙烯共聚物，苯乙烯的接枝共聚物，丙烯的均聚物或丙烯与乙烯的共聚物的共聚物的0.05-1.0重量％（基于混合物） 该膜可以用作包装材料。
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