Abstract:
The present invention relates to a process for the preparation of 2,6-di-tert-butyl phenol by reacting phenol with isobutylene in presence of an aluminum phenoxide catalyst, comprising i) preparing an aluminum phenoxide catalyst and phenol comprising mixture a) by mix-ing aluminum metal with phenol, and activating the catalyst by heating the mixture to a temperature of 100 to 180° C., and ii) carrying out a reaction b) by reacting mixture a) with an isobutylene comprising stream comprising 20 to 90% by weight of isobutylene and 10 to 80% by weight of 1-butene and/or 2-butene, which reaction is carried out under pressure and the maximum pressure is 5 to 20 bar.
Abstract:
The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound of formula 1-P, 1-O or I-M. Further embodiments are a compound of formula 1-P, 1-O or 1-M, a process for protection of the organic material by the compound, the use of the compound for stabilizing the organic material, an additive composition comprising the compound, a process for manufacturing the compound and intermediates involved therein.
Abstract:
The present invention relates to a process for the preparation of a polyarylene ether sulfone polymer (P) by converting a reaction mixture (RG) which comprises, among others, at least one aromatic dihalogen sulfone and at least one dihydroxy component comprising at least 20 mol-% of trimethylhydroquinone based on the total amount of the at least one dihydroxy component. The present invention furthermore relates to the Ouse of a polyarylene ether sulfone polymer (P) obtainable by the inventive process in a membrane (M) and to a membrane (M) comprising the polyarylene ether sulfone polymer (P) obtainable by the inventive process, as well as to a method for the preparation of a membrane (M).
Abstract:
The present invention relates to a process for the preparation of a sulfonated polyarylene ether sulfone polymer (sP) by converting a reaction mixture (RG) which comprises, among others, at least one non-sulfonated aromatic dihalogen sulfone, at least one sulfonated aromatic dihalogen sulfone and at least one aromatic dihydroxy component comprising trimethylhydroquinone. The present invention furthermore relates to a sulfonated polyarylene ether sulfone polymer (sP) obtainable by the inventive process and to its use in a membrane (M). Furthermore, the present invention relates to a membrane (M) comprising this sulfonated polyarylene ether sulfone polymer (sP) and to a method for the preparation of the membrane (M).
Abstract:
The invention relates to a composition comprising an organic material susceptible to oxidative, thermal or light-induced degradation and a compound of formula I-P, I-O or I-M. Further embodiments are a compound of formula I-P, I-O or I-M, a process for protection of the organic material by the compound, the use of the compound against degradation of the organic material, an additive composition comprising the compound, a process for manufacturing the compound and an intermediate involved therein.
Abstract:
A compound of the formula (A) wherein the radicals R1 are independently of one another methyl, ethyl or n-propyl, and X is C2-C8alkylene or C2-C8alkylene interrupted by sulfur, is useful for stabilizing an organic material against degradation induced by light, heat or oxidation.