公开(公告)号：US20160145459A1

公开(公告)日：2016-05-26

申请号：US14897986

申请日：2014-05-27

Applicant: BASF SE

Inventor： Regina KLEIN ,  Tina SCHRÖDER-GRIMONPONT ,  Patrick LIEBACH ,  Britta KATZ ,  Peter HAHN ,  Achim PIESCH ,  Jutta BRUST ,  Joseph STRACKE

IPC: C09D133/12 ,  C11D17/00 ,  A01N25/28 ,  C11D3/386 ,  A61Q19/00 ,  A61K8/11 ,  C11D3/395

CPC classification number: C09D133/12 ,  A01N25/04 ,  A01N25/28 ,  A61K8/11 ,  A61K8/8152 ,  A61K2800/10 ,  A61K2800/412 ,  A61Q19/00 ,  B01J13/18 ,  C04B20/1033 ,  C04B38/02 ,  C04B2103/0058 ,  C11D3/38672 ,  C11D3/3942 ,  C11D3/395 ,  C11D17/0039 ,  C04B22/002 ,  C04B22/082 ,  C04B28/02 ,  C04B40/0641

Abstract: The present invention relates to a process for producing a microcapsule dispersion comprising microcapsules comprising a hydrophilic capsule core and a capsule wall polymer, wherein a water-in-oil emulsion comprising a hydrophobic diluent as continuous phase, and the hydrophilic capsule core material, a monomer composition and an amphiphilic polymer is produced and then the monomers are free-radically polymerized,where the monomer composition comprises30 to 100% by weight of one or more monomers selected from C1-C24-alkyl esters of acrylic acid and/or methacrylic acid (monomers I),0 to 70% by weight of one or more monomers selected from acrylic acid, methacrylic acid, maleic acid, acrylic acid esters and/or methacrylic acid esters which carry hydroxy and/or carboxy groups (monomers II),0 to 50% by weight of one or more monomers which has two or more ethylenically unsaturated radicals, (monomers III) and0 to 30% by weight of one or more other monomers (monomers IV)in each case based on the total weight of the monomers, and the amphiphilic polymer is obtainable by free-radical polymerization of a monomer composition comprising at least one ethylenically unsaturated hydrophilic monomer and at least one ethylenically unsaturated hydrophobic monomer, to the microcapsules obtainable thereby, and to their use for the delayed release of active ingredients for construction, cosmetics, detergents and cleaners or crop protection applications.

Abstract translation: 本发明涉及包含亲水胶囊核心和胶囊壁聚合物的微胶囊的微胶囊分散体的制造方法，其中包含作为连续相的疏水性稀释剂的油包水乳液和亲水性胶囊芯材料，单体 制备组合物和两亲性聚合物，然后单体是自由基聚合的，其中单体组合物包含30至100重量％的一种或多种选自丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯的单体（ 单体I），0至70重量％的选自丙烯酸，甲基丙烯酸，马来酸，带有羟基和/或羧基的丙烯酸酯和/或甲基丙烯酸酯（单体II）的一种或多种单体，0至70重量％ 50重量％的一种或多种具有两个或多个烯属不饱和基团的单体（单体III）和0至30重量％的一种或多种其它单体（单体IV）在每种情况下为 可以通过将包含至少一种烯属不饱和亲水性单体和至少一种烯属不饱和疏水性单体的单体组合物自由基聚合到由此获得的微胶囊中获得，并且其两端聚合物 用于建筑活性成分的延迟释放，化妆品，洗涤剂和清洁剂或作物保护应用。

公开(公告)号：US20150361227A1

公开(公告)日：2015-12-17

申请号：US14763983

申请日：2014-01-22

Applicant: BASF SE

Inventor： Marco SCHMIDT ,  Tina SCHROEDER-GRIMONPONT ,  Regina KLEIN ,  Joachim PAKUSCH

IPC: C08J3/16 ,  B29C45/00 ,  B29B9/12 ,  B29C47/00 ,  C08J3/20 ,  B29B9/10

CPC classification number: C08J3/16 ,  B29B9/10 ,  B29B9/12 ,  B29B2009/125 ,  B29C45/0001 ,  B29C45/0013 ,  B29C48/022 ,  B29C48/08 ,  B29C48/09 ,  B29C48/12 ,  B29K2023/00 ,  B29K2105/16 ,  B29K2433/04 ,  B29L2007/002 ,  B29L2023/00 ,  B29L2031/001 ,  C08J3/203 ,  C08J2333/12 ,  C08J2433/06 ,  C08J2433/12 ,  C08K9/10 ,  C08L33/02 ,  C08L2201/54 ,  C09K5/063 ,  Y10T428/1372 ,  Y10T428/2989

Abstract: The present invention relates to particulate microcapsule compositions comprising microcapsules and an emulsion polymer, obtainable via spray drying of an aqueous microcapsule dispersion, where the microcapsules comprise a capsule core and a polymer as capsule wall and the polymer is composed offrom 30 to 90% by wt. of one or more monomers (monomers I) from the group consisting of C1-C24-alkyl esters of acrylic and/or methacrylic acid, acrylic acid, methacrylic acid, and maleic acid,from 10 to 70% by wt. of one or more ethylenically unsaturated monomers having two, three, four, or more ethylenically unsaturated moieties (monomers II), andfrom 0 to 40% by wt. of one or more other monomers (monomers III), based in each case on the total weight of the monomers,with use of an aqueous dispersion of one or more emulsion polymers which comprises in copolymerized formfrom 50 to 99.9% by wt. of esters of acrylic and/or methacrylic acid with alkanols having from 1 to 12 carbon atoms and/or styrene, orfrom 50 to 99.9% by wt. of styrene and/or butadiene, orfrom 50 to 99.9% by wt. of vinyl chloride and/or vinylidene chloride, orfrom 50 to 99.9% by wt. of vinyl acetate, vinyl propionate, vinyl esters of versatic acid, vinyl esters of long-chain fatty acids, and/or ethylene,as spraying aid, to a process for producing these, and also to their use for producing thermoplastic moldings.

Abstract translation: 本发明涉及包含微胶囊和乳液聚合物的颗粒微胶囊组合物，其可通过水性微胶囊分散体的喷雾干燥获得，其中微胶囊包含胶囊核心和聚合物作为胶囊壁，并且所述聚合物由30至90％ 重量 的一种或多种由丙烯酸和/或甲基丙烯酸的C 1 -C 24烷基酯，丙烯酸，甲基丙烯酸和马来酸组成的组中的单体（单体I），10-70重量％ 的一种或多种具有两个，三个，四个或更多个烯属不饱和部分（单体II）的烯属不饱和单体和0-40重量％ 一种或多种其它单体（单体III），基于每种情况下基于单体的总重量，使用一种或多种乳液聚合物的水分散体，其包含共聚形式为50至99.9重量％ 的丙烯酸和/或甲基丙烯酸的酯与具有1至12个碳原子的链烷醇和/或苯乙烯，或50至99.9重量％ 的苯乙烯和/或丁二烯，或50-99.9重量％。 的氯乙烯和/或偏二氯乙烯，或50至99.9重量％。 的醋酸乙烯酯，丙酸乙烯酯，十八烷酸的乙烯基酯，长链脂肪酸的乙烯基酯和/或乙烯，作为喷涂助剂，用于制备它们的方法，以及它们用于生产热塑性模制品的用途。