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公开(公告)号：US6100337A
公开(公告)日：2000-08-08
申请号：US80822
申请日：1998-05-18
IPC分类号： C08F255/00 , C08F255/02 , C08F255/08 , C08F283/12 , C08L27/22 , C08L25/02 , C08L25/18
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an .alpha.-olefin capable of producing an amorphous backbone with a comonomer which provides a "hook" for grafting to with a living polystyrene chain. Another method is to copolymerize an .alpha.-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an .alpha.-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够制备无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在较不优选的实施方案中，常规EPDM聚合物可以被金属化，并且由主链生长的单烯基芳族化合物阴离子可聚合单体。
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公开(公告)号：US06319990B1
公开(公告)日：2001-11-20
申请号：US09502646
申请日：2000-02-11
IPC分类号： C08L2722
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够生产无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在不太优选的实施方案中，常规EPDM聚合物可以被金属化，并且从主链生长的单烯基芳族化合物阴离子聚合性单体。
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3.发明授权Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers 失效通过将卤代硅烷接枝到聚烯烃/二烯聚合物上制备嵌段共聚物的方法
公开(公告)号：US5693713A
公开(公告)日：1997-12-02
申请号：US453241
申请日：1995-05-30
CPC分类号： C08G81/021 , C08F8/42
摘要： A method of producing graft block copolymers which comprises (a) grafting a halosilane of the formula HSiX.sub.n R.sub.3-n wherein X is halogen, R is alkyl or aryl, and n=1-3, onto a .alpha.-olefin/diene copolymer made from at least one .alpha.-olefin and at least one diene, (b) anionically polymerizing at least one anionically polymerizable monomer to form living polymer chains, and (c) reacting the products of (a) and (b) together wherein the living polymer chains react with the halosilane groups on the .alpha.-olefin/diene copolymer and are added thereto as pendant side chains.
摘要翻译： 一种制备接枝嵌段共聚物的方法，其包括（a）将由式HSiXnR3-n表示的卤代硅烷接枝到由下式制备的α-烯烃/二烯共聚物上，其中X是卤素，R是烷基或芳基，n = 1-3， 至少一种α-烯烃和至少一种二烯，（b）阴离子聚合至少一种阴离子聚合单体以形成活性聚合物链，和（c）使（a）和（b）的产物反应在一起，其中活性聚合物链反应 其中α-烯烃/二烯共聚物上的卤代硅烷基团作为侧链加入其中。
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公开(公告)号：US06750289B2
公开(公告)日：2004-06-15
申请号：US10349839
申请日：2003-01-23
IPC分类号： C08F25502
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够生产无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在较不优选的实施方案中，常规EPDM聚合物可以被金属化，并且由主链生长的单烯基芳族化合物阴离子可聚合单体。
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公开(公告)号：US06552125B2
公开(公告)日：2003-04-22
申请号：US09872625
申请日：2001-06-01
IPC分类号： C08G6348
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
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公开(公告)号：USH1902H
公开(公告)日：2000-10-03
申请号：US680310
申请日：1996-07-11
IPC分类号： C08F297/02 , C08G81/02 , C08F295/00
CPC分类号： C08F297/026 , C08G81/021 , C08G81/022
摘要： The invention described herein is an asymmetric radial block copolymer having at least one set of arms formed of at least one polymer block of at least one vinyl aromatic hydrocarbon and/or at least one polymer block formed of at least one conjugated diene and at least one set of arms formed of at least one polymer block of at least one acrylic monomer.
摘要翻译： 本文描述的本发明是具有至少一组由至少一种乙烯基芳族烃的聚合物嵌段和/或至少一种由至少一种共轭二烯形成的聚合物嵌段和至少一种共轭二烯形成的臂的不对称的径向嵌段共聚物 由至少一种丙烯酸类单体的至少一种聚合物嵌段形成的臂组。
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7.发明授权Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants 失效用于粘合剂和密封剂的径向或星形嵌段共聚物
公开(公告)号：US5639831A
公开(公告)日：1997-06-17
申请号：US537482
申请日：1995-10-02
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F8/46 , C08F297/04 , C08L53/02 , C09J153/02
CPC分类号： C08L53/025 , C08F297/044 , C09J153/025 , Y10T428/28 , Y10T428/2839 , Y10T428/2852 , Y10T428/2861 , Y10T428/31855 , Y10T428/31931 , Y10T428/31938
摘要： Radial or star asymmetric block copolymer of the following formulae and improved adhesive and sealant compositions containing them(A-HD).sub.x -Y-(UD).sub.z (I)or(UD)-A-HD).sub.x -Y (II)or((UD).sub.y -A-HD).sub.x -Y-(UD).sub.z (III)wherein A is a vinyl aromatic hydrocarbon block having a molecular weight of from 4000 to 20,000, HD is a hydrogenated conjugated diene block having a molecular weight of from 10,000 to 100,000, Y is a multifunctional coupling agent, UD is a partially hydrogenated conjugated diene block having a molecular weight of from 1000 to 80,000, x is an integer from 2 to 30, y is 0 or 1, z is an integer from 1 to 20, and x+z ranges from 3 to 30.
摘要翻译： （A-HD）xY-（UD）z（I）或（UD）-A-HD）xY（II）或（（UD））的具有下式的径向或星形不对称嵌段共聚物和改进的粘合剂和密封剂组合物 yA-HD）xY-（UD）z（III）其中A是分子量为4000至20,000的乙烯基芳族烃嵌段，HD是分子量为10,000至100,000的氢化共轭二烯嵌段，Y为 UD是多官能偶联剂，UD是分子量为1000〜80,000的部分氢化共轭二烯嵌段，x为2〜30的整数，y为0或1，z为1〜20的整数，x + z范围从3到30。
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