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公开(公告)号：US06319990B1
公开(公告)日：2001-11-20
申请号：US09502646
申请日：2000-02-11
IPC分类号： C08L2722
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够生产无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在不太优选的实施方案中，常规EPDM聚合物可以被金属化，并且从主链生长的单烯基芳族化合物阴离子聚合性单体。
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2.发明授权Process for making block graft copolymers by grafting halosilanes onto polyolefin/diene polymers 失效通过将卤代硅烷接枝到聚烯烃/二烯聚合物上制备嵌段共聚物的方法
公开(公告)号：US5693713A
公开(公告)日：1997-12-02
申请号：US453241
申请日：1995-05-30
CPC分类号： C08G81/021 , C08F8/42
摘要： A method of producing graft block copolymers which comprises (a) grafting a halosilane of the formula HSiX.sub.n R.sub.3-n wherein X is halogen, R is alkyl or aryl, and n=1-3, onto a .alpha.-olefin/diene copolymer made from at least one .alpha.-olefin and at least one diene, (b) anionically polymerizing at least one anionically polymerizable monomer to form living polymer chains, and (c) reacting the products of (a) and (b) together wherein the living polymer chains react with the halosilane groups on the .alpha.-olefin/diene copolymer and are added thereto as pendant side chains.
摘要翻译： 一种制备接枝嵌段共聚物的方法，其包括（a）将由式HSiXnR3-n表示的卤代硅烷接枝到由下式制备的α-烯烃/二烯共聚物上，其中X是卤素，R是烷基或芳基，n = 1-3， 至少一种α-烯烃和至少一种二烯，（b）阴离子聚合至少一种阴离子聚合单体以形成活性聚合物链，和（c）使（a）和（b）的产物反应在一起，其中活性聚合物链反应 其中α-烯烃/二烯共聚物上的卤代硅烷基团作为侧链加入其中。
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公开(公告)号：US6100337A
公开(公告)日：2000-08-08
申请号：US80822
申请日：1998-05-18
IPC分类号： C08F255/00 , C08F255/02 , C08F255/08 , C08F283/12 , C08L27/22 , C08L25/02 , C08L25/18
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an .alpha.-olefin capable of producing an amorphous backbone with a comonomer which provides a "hook" for grafting to with a living polystyrene chain. Another method is to copolymerize an .alpha.-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an .alpha.-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够制备无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在较不优选的实施方案中，常规EPDM聚合物可以被金属化，并且由主链生长的单烯基芳族化合物阴离子可聚合单体。
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公开(公告)号：US06750289B2
公开(公告)日：2004-06-15
申请号：US10349839
申请日：2003-01-23
IPC分类号： C08F25502
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
摘要翻译： 使用自由基引发剂和具有至少一个不饱和键的官能化单体来使没有氢化步骤制备的热塑性弹性体功能化。 基础聚合物可以通过使能够生产无定形骨架的α-烯烃与共聚单体共聚来制备，所述共聚单体提供用于与活性聚苯乙烯链接枝的“钩”。 另一种方法是将能够产生无定形骨架的α-烯烃单体体系与含有阴离子可聚合单体从主链生长的官能团的共聚单体共聚。 第三种方法包括使能够产生无定形骨架的α-烯烃单体体系与烯烃封端的聚苯乙烯共聚单体共聚。 在较不优选的实施方案中，常规EPDM聚合物可以被金属化，并且由主链生长的单烯基芳族化合物阴离子可聚合单体。
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公开(公告)号：US06552125B2
公开(公告)日：2003-04-22
申请号：US09872625
申请日：2001-06-01
IPC分类号： C08G6348
CPC分类号： C08F255/02 , C08F255/00 , C08F255/08 , C08F283/12
摘要： A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
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公开(公告)号：USH1902H
公开(公告)日：2000-10-03
申请号：US680310
申请日：1996-07-11
IPC分类号： C08F297/02 , C08G81/02 , C08F295/00
CPC分类号： C08F297/026 , C08G81/021 , C08G81/022
摘要： The invention described herein is an asymmetric radial block copolymer having at least one set of arms formed of at least one polymer block of at least one vinyl aromatic hydrocarbon and/or at least one polymer block formed of at least one conjugated diene and at least one set of arms formed of at least one polymer block of at least one acrylic monomer.
摘要翻译： 本文描述的本发明是具有至少一组由至少一种乙烯基芳族烃的聚合物嵌段和/或至少一种由至少一种共轭二烯形成的聚合物嵌段和至少一种共轭二烯形成的臂的不对称的径向嵌段共聚物 由至少一种丙烯酸类单体的至少一种聚合物嵌段形成的臂组。
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7.发明授权Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants 失效用于粘合剂和密封剂的径向或星形嵌段共聚物
公开(公告)号：US5639831A
公开(公告)日：1997-06-17
申请号：US537482
申请日：1995-10-02
IPC分类号： C08F8/00 , C08F8/04 , C08F8/08 , C08F8/46 , C08F297/04 , C08L53/02 , C09J153/02
CPC分类号： C08L53/025 , C08F297/044 , C09J153/025 , Y10T428/28 , Y10T428/2839 , Y10T428/2852 , Y10T428/2861 , Y10T428/31855 , Y10T428/31931 , Y10T428/31938
摘要： Radial or star asymmetric block copolymer of the following formulae and improved adhesive and sealant compositions containing them(A-HD).sub.x -Y-(UD).sub.z (I)or(UD)-A-HD).sub.x -Y (II)or((UD).sub.y -A-HD).sub.x -Y-(UD).sub.z (III)wherein A is a vinyl aromatic hydrocarbon block having a molecular weight of from 4000 to 20,000, HD is a hydrogenated conjugated diene block having a molecular weight of from 10,000 to 100,000, Y is a multifunctional coupling agent, UD is a partially hydrogenated conjugated diene block having a molecular weight of from 1000 to 80,000, x is an integer from 2 to 30, y is 0 or 1, z is an integer from 1 to 20, and x+z ranges from 3 to 30.
摘要翻译： （A-HD）xY-（UD）z（I）或（UD）-A-HD）xY（II）或（（UD））的具有下式的径向或星形不对称嵌段共聚物和改进的粘合剂和密封剂组合物 yA-HD）xY-（UD）z（III）其中A是分子量为4000至20,000的乙烯基芳族烃嵌段，HD是分子量为10,000至100,000的氢化共轭二烯嵌段，Y为 UD是多官能偶联剂，UD是分子量为1000〜80,000的部分氢化共轭二烯嵌段，x为2〜30的整数，y为0或1，z为1〜20的整数，x + z范围从3到30。
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公开(公告)号：US5773521A
公开(公告)日：1998-06-30
申请号：US574795
申请日：1995-12-19
IPC分类号： C08F297/04
CPC分类号： C08F297/04
摘要： In the production of "inside-out" star polymers where a first polymer lithium chain is formed, coupled and thereafter additional monomer is introduced to produce the "out" polymer chains, improved control over the second polymerization is obtained by coupling with a mixture of a monoalkenyl-substituted aromatic compound and a polyalkenyl-substituted aromatic compound. For example, a mixture of divinylbenzene and styrene can be used. In another embodiment, an ether is introduced after completion of the first polymer chain formation. The presence of the ether also improves the second stage chain formation. Utilization of both the mixed coupling agents and the ether, preferably a diether such as 1,2-diethoxyethane gives the greatest control over the uniformity of the second stage polymerization, making possible the production of narrower molecular weight distribution polymer having no indication of bimodal distribution. The narrow molecular weight distribution is advantageous in many applications.
摘要翻译： 在形成第一聚合物锂链的“内向外”星形聚合物的生产中，偶联并且随后引入另外的单体以产生“外”聚合物链，通过与第二聚合物的混合物 单链烯基取代的芳族化合物和聚链烯基取代的芳族化合物。 例如可以使用二乙烯基苯和苯乙烯的混合物。 在另一个实施方案中，在完成第一聚合物链形成之后引入醚。 醚的存在也改善了第二阶段链的形成。 使用混合偶联剂和醚，优选二醚如1,2-二乙氧基乙烷，可以最大限度地控制第二阶段聚合的均匀性，使得可能生产没有双峰分布指示的较窄分子量分布聚合物 。 狭窄的分子量分布在许多应用中是有利的。
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9.发明授权Organic polymers containing polyethylene or polystyrene polysiloxane diblock copolymers as melt processing aids 失效含有聚乙烯或聚苯乙烯聚硅氧烷二嵌段共聚物作为熔融加工助剂的有机聚合物公开(公告)号：US06331589B1
公开(公告)日：2001-12-18
申请号：US09442220
申请日：1999-11-17
IPC分类号： C08G77442
CPC分类号： C08L53/02 , C08L23/06 , C08L53/025 , C08L2666/02
摘要： The present invention provides organic polymers and compounds containing such polymers which have enhanced melt processing characteristics. A composition of the present invention includes at least one organic polymer and from 0.1 percent by weight to 5 percent by weight of a diblock copolymer of polystyrene and a polysiloxane or polyethylene and a polysiloxane. The overall weight average molecular weight of the diblock copolymer ranges from 500 to 50,000. The polysiloxane content of the block copolymer is from 20 to 90 percent by weight. The organic polymer incorporating the above-described melt processing aid can be incorporated into a compound of the organic polymer and another polymer and/or an oil and/or a filler material. Preferably, the composition includes two different organic polymers, especially including a block copolymer.
摘要翻译： 本发明提供了含有这种聚合物的有机聚合物和具有增强的熔体加工特性的化合物。 本发明的组合物包括至少一种有机聚合物和0.1重量％至5重量％的聚苯乙烯和聚硅氧烷或聚乙烯和聚硅氧烷的二嵌段共聚物。 二嵌段共聚物的总重均分子量为500〜50000。 嵌段共聚物的聚硅氧烷含量为20〜90重量％。 掺入上述熔融加工助剂的有机聚合物可以掺入到有机聚合物和另一种聚合物和/或油和/或填料材料的化合物中。 优选地，组合物包括两种不同的有机聚合物，特别是包括嵌段共聚物。
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10.发明授权
公开(公告)号：US5639830A
公开(公告)日：1997-06-17
申请号：US349705
申请日：1994-12-05
IPC分类号： C08F8/20 , C08F297/04
CPC分类号： C08F8/20 , Y10S525/94
摘要： A block copolymer is provided, the block copolymer halogenated polystyrene comprises the formula:S'--A--(A--S').sub.min which m is 0, 1, 2, 3 or 4, A is a saturated polyalkylene, and S' is a nuclear brominated poly(vinyl aromatic) having from about 0.5 to about 5 bromines per styrene unit. The vinyl aromatic blocks are substantially free of halogen other than bromine and the polyalkylene is substantially free of halogen. The compositions retain the elastomeric properties of the non-halogenated form of the compounds while having significantly reduced flammability along with improved tensile strength and high temperature properties.
摘要翻译： 提供了一种嵌段共聚物，该嵌段共聚物卤化聚苯乙烯包括下式：S'-A-（A-S'）min，m为0,1,2,3或4，A为饱和聚亚烷基，S'为 每个苯乙烯单元具有约0.5至约5个溴的核溴化聚（乙烯基芳族化合物）。 乙烯基芳族嵌段基本上不含溴以外的卤素，聚亚烷基基本上不含卤素。 组合物保持了非卤化形式的化合物的弹性体性质，同时具有显着降低的可燃性以及改进的拉伸强度和高温性能。
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