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公开(公告)号：US07008698B2
公开(公告)日：2006-03-07
申请号：US10866897
申请日：2004-06-14
申请人： Chadwick E. Marlow , Charles D. Carlson, Jr. , Robert G. Posey , Gary R. Garner , Russell S. Foxhall
发明人： Chadwick E. Marlow , Charles D. Carlson, Jr. , Robert G. Posey , Gary R. Garner , Russell S. Foxhall
CPC分类号： C08J5/18 , C08J2367/02 , Y10S428/91 , Y10T428/1328 , Y10T428/1331 , Y10T428/266 , Y10T428/269 , Y10T428/31786
摘要： A shrinkable polymer film including a modified polyester resin polymerized from monomers including a dicarboxylic acid and a glycol, wherein the glycol includes 2-methyl-1,3-propanediol, and wherein the polymer film shrinks at least about 50% in a main shrinkage direction after ten seconds in an 80 degree Celsius hot water bath.
摘要翻译： 一种包含由包含二羧酸和二元醇的单体聚合的改性聚酯树脂的收缩性聚合物膜，其中所述二醇包括2-甲基-1,3-丙二醇，并且其中所述聚合物膜在主收缩方向上收缩至少约50％ 在80摄氏度的热水浴中经过十秒钟。
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公开(公告)号：US4493872A
公开(公告)日：1985-01-15
申请号：US558126
申请日：1983-12-05
CPC分类号： C08J7/047 , C08G63/6886 , C08J2467/00 , Y10T428/26 , Y10T428/263 , Y10T428/265 , Y10T428/31507 , Y10T428/31598 , Y10T428/31681 , Y10T428/31786 , Y10T428/31797
摘要： A coated, oriented plastic film material is provided wherein the coating is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C and D or their polyester forming equivalents as follows:(A) about 65 to 95 mole percent of isophthalic acid;(B) about 0 to 30 mole percent of at least one aliphatic dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) about 5 to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities of about 100 mole percent of at least one copolymerizable aliphatic or cycloaliphatic alkylene glycol having about from 2 to 11 carbon atoms.The copolyester coating layer may be applied to the film, e.g., polyester film, at any suitable stage during manufacture of the film, i.e., before, during, or after the stretching operations. The resultant coated polyester film is found to provide excellent adhesion to metallic coatings subsequently applied thereto by metallizing techniques.
摘要翻译： 提供一种涂覆的取向塑料薄膜材料，其中将涂层涂覆在包含基本由组分A，B，C和D的缩合产物或它们的聚酯形成等效物的水分散性共聚酯的水性介质中，其如下：（A）约 65〜95摩尔％的间苯二甲酸; （B）约0至30摩尔％的至少一种式HOOC（CH 2）n COOH的脂族二羧酸，其中n的范围为约1-11; （C）约5至约15摩尔％的至少一种含有连接到二羧基芳香核上的碱金属磺酸盐基团的磺化单体，和（D）化学计量的约100摩尔％的至少一种可共聚的脂族或脂环族亚烷基二醇，其具有 约2至11个碳原子。 在膜的制造期间，即在拉伸操作之前，期间或之后，可以在任何合适的阶段将共聚酯涂层施加到膜，例如聚酯膜上。 发现所得到的涂覆聚酯膜对随后通过金属化技术施加到其上的金属涂层提供优异的粘合性。
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公开(公告)号：US4476189A
公开(公告)日：1984-10-09
申请号：US495192
申请日：1983-05-16
IPC分类号： C08G63/00 , B29C55/02 , B29C55/12 , B29K67/00 , B29L9/00 , B32B27/36 , C08G63/181 , C08G63/688 , C08J5/18 , C08J7/04 , B32B27/06
CPC分类号： C08J5/18 , B29C55/026 , C08J7/042 , C08J2367/02 , Y10S428/91 , Y10T428/265 , Y10T428/31786 , Y10T428/31797
摘要： A primer coated, oriented polyester film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations. The resultant primed polyester film is found to provide excellent adhesion to many aqueous or organic solvent based coatings subsequently applied thereto.
摘要翻译： 提供底漆涂布的取向聚酯薄膜材料，其中将底漆涂布在水性介质中，该水性介质包含主要由组分A，B，C和D的缩合产物组成的水分散性共聚酯或其聚酯形成等同物，如下所示：（A ）约60〜75摩尔％的对苯二甲酸; （B）约15至25摩尔％的至少一种式HOOC（CH 2）n COOH的二羧酸，其中n为约1-11; （C）大于约6至约15摩尔％的至少一种含有连接到二羧基芳香核上的碱金属磺酸盐基团的磺化单体，和（D）化学计量的量，即约100摩尔％的至少一种脂族 或可与其共聚的脂环族亚烷基二醇，其具有约2至11个碳原子。 在膜的制造期间，即在拉伸操作之前或期间，可以在任何合适的阶段将共聚酯起动层施加到聚酯膜上。 发现所得的底漆聚酯膜对随后施加到其上的许多水性或有机溶剂基涂料提供优异的粘合性。
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4.发明授权
公开(公告)号：US5672428A
公开(公告)日：1997-09-30
申请号：US544246
申请日：1995-10-17
IPC分类号： B05D7/04 , B05D7/24 , B29C55/02 , B29K67/00 , B29K83/00 , B29L7/00 , B29L9/00 , B32B27/00 , C08J7/04 , C08L83/00 , C08L83/02 , C08L83/04 , C09D183/00 , C09D183/04 , C09D183/07 , C09J7/02 , B32B7/12
CPC分类号： C09J7/025 , C09D183/04 , C08L83/04 , C09J2467/006 , C09J2483/005 , Y10T428/2839 , Y10T428/31663 , Y10T428/31797
摘要： A silicone release polyester film coated with an aqueous silicone coating composition on one surface. The aqueous silicone release coating composition is made up of an alkylvinylpolysiloxane containing vinyl groups, a tin or platinum catalyst, a glycidoxysilane and an alkylhydrogenpolysiloxane. A process for coating a polyester film with the aqueous silicone coating composition is also disclosed, where the coating occurs in-line, disclosing the manufacturing process for the film before it is heat-set. The silicone release coated polyester film has an acceptable release value when subjected to solvents or heat.
摘要翻译： 在一个表面上涂覆有水性硅氧烷涂料组合物的硅氧烷释放聚酯膜。 水性有机硅剥离涂料组合物由含乙烯基的烷基乙烯基聚硅氧烷，锡或铂催化剂，缩水甘油氧基硅烷和烷基氢聚硅氧烷组成。 还公开了一种使用含水硅氧烷涂料组合物涂覆聚酯膜的方法，其中涂层在线发生，揭示了在热固化之前该膜的制造过程。 有机硅脱模涂层的聚酯薄膜在经受溶剂或热时具有可接受的释放值。
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公开(公告)号：US5077925A
公开(公告)日：1992-01-07
申请号：US512459
申请日：1990-04-23
摘要： A frame is disclosed herein having an elongated base with opposite side rails defining an exposed message area therebetween occupied by a resilient pad. A message sheet is placed between the pad and a transparent window or layer which is slidably carried on the side rails to cover and protect the message sheet. Stop abutments are provided to limit sliding of the window and a snap-lock mechanism is employed for releasably retaining the window in place over the message sheet.
摘要翻译： 本文公开了一种具有细长基部的框架，其具有相对的侧轨道，其限定了由弹性垫占据的暴露的消息区域。 消息表放置在垫和可滑动地携带在侧轨上的透明窗或层之间以覆盖和保护消息页。 提供停止支座以限制窗口的滑动，并且采用卡扣锁定机构以将窗口可释放地保持在消息板上的适当位置。
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6.发明授权Controlled release coating comprising blend of silicone polymer and adhesion promoter 失效控制释放涂层包括硅氧烷聚合物和粘合促进剂的混合物
公开(公告)号：US6020412A
公开(公告)日：2000-02-01
申请号：US985098
申请日：1997-12-04
IPC分类号： C08L83/04 , C09D183/04 , C09J7/02 , C08K5/09
CPC分类号： C09J7/0225 , C09D183/04 , C08L83/04 , C09J2483/005
摘要： A reclaimable release coating composition is provided which includes a blend of an adhesion promoter and a silicone release agent which may be applied from an aqueous solution, dispersion or emulsion. The components form regions of adhesion promoting sites disrupted by regions of release sites on the surface of a release backing substrate coated with the composition. The different regions are substantially homogeneously distributed across the entirety of the release surface. When used as a release coating for a backing to protect an adhesive, a controlled release force of a predictable value may be obtained by providing a known weight ratio of adhesion promoter to silicone release agent in the coating composition. A substantially linear relationship is also provided between the release force required to peel a non-silicone adhesive from the release coating surface, and the weight ratio of vinyl-functional polyorganosiloxane oil to hydrogen-functional siloxane crosslinker in the release agent, such that a consistent, uniform and repeatable release force from the surface may be obtained.
摘要翻译： 提供了一种可回收剥离涂料组合物，其包括可从水溶液，分散体或乳液中施加的粘合促进剂和有机硅脱模剂的共混物。 组分形成由涂覆有组合物的剥离背衬基材的表面上的释放位点的区域破坏的粘附促进位点的区域。 不同的区域基本均匀地分布在整个释放表面上。 当用作背衬的防粘涂层以保护粘合剂时，可以通过在涂料组合物中提供已知的粘合促进剂与硅氧烷脱模剂的重量比来获得可预测值的控制释放力。 在从脱模涂层表面剥离非硅氧烷粘合剂的释放力和脱模剂中的乙烯基官能聚有机硅氧烷油与氢官能硅氧烷交联剂的重量比之间也提供了基本上线性的关系，使得一致 ，可以获得来自表面的均匀且可重复的释放力。
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7.发明授权
公开(公告)号：US4745019A
公开(公告)日：1988-05-17
申请号：US804558
申请日：1986-01-23
CPC分类号： C08J5/18 , B29C55/026 , C08J7/047 , C08J2367/02 , C08J2467/02 , Y10S430/151 , Y10T428/24372 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/273 , Y10T428/31786 , Y10T428/31797
摘要： A primer coated, oriented polyester film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) Stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations. The resultant primed polyester film is found to provide excellent adhesion to many aqueous or organic solvent based coatings subsequently applied thereto.
摘要翻译： 提供底漆涂布的取向聚酯薄膜材料，其中将底漆涂布在水性介质中，该水性介质包含主要由组分A，B，C和D的缩合产物组成的水分散性共聚酯或其聚酯形成等同物，如下所示：（A ）约60〜75摩尔％的对苯二甲酸; （B）约15至25摩尔％的至少一种式HOOC（CH 2）n COOH的二羧酸，其中n为约1-11; （C）大于约6至约15摩尔％的至少一种含有连接到二羧基芳香核上的碱金属磺酸盐基团的磺基单体，和（D）化学计量的量，即约100摩尔％的至少一种脂族 或可与其共聚的脂环族亚烷基二醇，其具有约2至11个碳原子。 在膜的制造期间，即在拉伸操作之前或期间，可以在任何合适的阶段将共聚酯起动层施加到聚酯膜上。 发现所得的底漆聚酯膜对随后施加到其上的许多水性或有机溶剂基涂料提供优异的粘合性。
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公开(公告)号：US4585687A
公开(公告)日：1986-04-29
申请号：US605434
申请日：1984-04-30
CPC分类号： C08J5/18 , B29C55/026 , C08J7/047 , C08J2367/02 , C08J2423/06 , Y10S428/91 , Y10T428/24372 , Y10T428/24802 , Y10T428/31786 , Y10T428/31797
摘要： A primer coated, oriented polyester film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations. The resultant primed polyester film is found to provide excellent adhesion to many aqueous or organic solvent based coatings subsequently applied thereto.
摘要翻译： 提供底漆涂布的取向聚酯薄膜材料，其中将底漆涂布在水性介质中，该水性介质包含主要由组分A，B，C和D的缩合产物组成的水分散性共聚酯或其聚酯形成等同物，如下所示：（A ）约60〜75摩尔％的对苯二甲酸; （B）约15至25摩尔％的至少一种式HOOC（CH 2）n COOH的二羧酸，其中n为约1-11; （C）大于约6至约15摩尔％的至少一种含有连接到二羧基芳香核上的碱金属磺酸盐基团的磺化单体，和（D）化学计量的量，即约100摩尔％的至少一种脂族 或可与其共聚的脂环族亚烷基二醇，其具有约2至11个碳原子。 在膜的制造期间，即在拉伸操作之前或期间，可以在任何合适的阶段将共聚酯起动层施加到聚酯膜上。 发现所得的底漆聚酯膜对随后施加到其上的许多水性或有机溶剂基涂料提供优异的粘合性。
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公开(公告)号：US4525419A
公开(公告)日：1985-06-25
申请号：US634514
申请日：1984-07-26
CPC分类号： C08J5/18 , B29C55/026 , C08J7/042 , C08J2367/02 , C08J2423/06 , Y10T428/263 , Y10T428/265 , Y10T428/31736 , Y10T428/31786 , Y10T428/31797
摘要： A primer coated, oriented plastic film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the plactic film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations. The resultant primed plastic film is found to provide excellent adhesion to many aqueous or organic solvent based coatings subsequently applied thereto.
摘要翻译： 提供底漆涂覆的取向塑料薄膜材料，其中将底漆涂布在水性介质中，该水性介质包含主要由组分A，B，C和D的缩合产物组成的水分散性共聚酯或其聚酯形成的等同物如下：（A ）约60〜75摩尔％的对苯二甲酸; （B）约15至25摩尔％的至少一种式HOOC（CH 2）n COOH的二羧酸，其中n为约1-11; （C）大于约6至约15摩尔％的至少一种含有连接到二羧基芳香核上的碱金属磺酸盐基团的磺化单体，和（D）化学计量的量，即约100摩尔％的至少一种脂族 或可与其共聚的脂环族亚烷基二醇，其具有约2至11个碳原子。 在膜的制造期间，即在拉伸操作之前或期间，可以在任何合适的阶段将共聚酯起动层施加到该层压薄膜上。 发现所得到的底漆塑料膜对随后施加到其上的许多水性或有机溶剂基涂料提供优异的粘合性。
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