公开(公告)号：US4826978A

公开(公告)日：1989-05-02

申请号：US139342

申请日：1987-12-29

申请人： Cyril A. Migdal ,  John B. Hines ,  Edward W. Kluger

发明人： Cyril A. Migdal ,  John B. Hines ,  Edward W. Kluger

IPC分类号： C07D251/24 ,  C08K5/3492 ,  C07D251/12

CPC分类号： C08K5/3492 ,  C07D251/24

摘要： Triazine compounds are disclosed which are useful for imparting UV screening properties to polymers of the formula: ##STR1## wherein R is an electron withdrawing group; R.sub.1 is H, ##STR2## where R.sub.3 is an alkyl group having from one to about six carbon atoms; and R.sub.2 is selected from H and CH.sub.3, also disclosed are polymer compositions having improved UV screening properties containing said triazine compounds.

摘要翻译： 公开了三嗪化合物，其可用于赋予下式的聚合物的UV屏蔽性能：其中R是吸电子基团; R1是H，其中R3是具有1至约6个碳原子的烷基; 并且R 2选自H和CH 3，还公开了具有包含所述三嗪化合物的改进的UV屏蔽性质的聚合物组合物。

公开(公告)号：US4962142A

公开(公告)日：1990-10-09

申请号：US270871

申请日：1988-11-14

申请人： Cyril A. Migdal ,  John B. Hines ,  Edward W. Kluger

发明人： Cyril A. Migdal ,  John B. Hines ,  Edward W. Kluger

IPC分类号： C07D251/24 ,  C08K5/3492

CPC分类号： C07D251/24 ,  C08K5/3492

摘要： Triazine compounds are disclosed which are useful for imparting UV screening properties to polymers of the formula: ##STR1## wherein R is an electron withdrawing group; R.sub.1 is H, ##STR2## where R.sub.3 is an alkyl group having from one to about six carbon atoms; and R.sub.2 is selected from H and CH.sub.3, also disclosed are polymer compositions having improved UV screening properties containing said triazine compounds.

摘要翻译： 公开了三嗪化合物，其可用于赋予下式的聚合物的UV屏蔽性能：其中R是吸电子基团; R1是H，其中R3是具有1至约6个碳原子的烷基; 并且R 2选自H和CH 3，还公开了具有包含所述三嗪化合物的改进的UV屏蔽性质的聚合物组合物。

公开(公告)号：US4992204A

公开(公告)日：1991-02-12

申请号：US397079

申请日：1989-08-22

申请人： Edward W. Kluger ,  Patrick D. Moore ,  John B. Hines ,  John G. Lever

发明人： Edward W. Kluger ,  Patrick D. Moore ,  John B. Hines ,  John G. Lever

IPC分类号： D06M23/00 ,  D06Q1/00

CPC分类号： D06Q1/00 ,  D06M23/00

摘要： A method for tagging one or a mixture of natural or synthetic materials comprising contacting the same with one or a mixture of tagging compounds containing one or more non-ionic luminophore moieties attached to at least one poly(oxyalkylene) moiety by means of a linking moiety; wherein said tagging compound has substantial absorbance within the range of from about 300 to about 400 nm and reemits substantial visible light, said contacting effecting at least a temporary association between said material and said compound wherein said compound is present in an amount between about 0.0001 and about 10 percent by weight of said material.

摘要翻译： 用于标记天然或合成材料的一种或混合物的方法，包括使其与含有通过连接部分连接至至少一个聚（氧化烯）部分的一个或多个非离子发光体部分的标记化合物或其混合物接触 ; 其中所述标记化合物具有在约300至约400nm范围内的实质吸光度，并且重新产生显着的可见光，所述接触至少在所述材料和所述化合物之间起暂时的缔合作用，其中所述化合物的存在量为约0.0001至 约10重量％的所述材料。

公开(公告)号：US5591833A

公开(公告)日：1997-01-07

申请号：US104276

申请日：1993-08-10

申请人： John B. Hines ,  David J. Moody ,  Edward W. Kluger

发明人： John B. Hines ,  David J. Moody ,  Edward W. Kluger

IPC分类号： C09B69/00 ,  C09B69/10 ,  D06P5/13

CPC分类号： C09B69/00

摘要： Colorants and compositions useful as a fugitive or permanent colorant for a variety of substrates, or as intermediates for their manufacture, and having one or more improved properties of enhanced aqueous washability, compatibility with and non-extractibility from thermoplastic resins, or reactivity with resins having reactive functionality, said composition having the formula C(Z).sub.1-8 wherein:C is the residue of a reactant having from 1-8 nucleophilic site residues to which the Z moieties are attached; said Z moieties containing at least about 60 weight percent of poly(oxyalkylene) which is comprised of(a) at least one glycidol residue segment of 2-6 glycidol residues attached to a nucleophilic site of C, wherein said poly(oxyalkylene) contains a total of from 2-20 glycidol residues,(b) and wherein said poly(oxyalkylene) further contains the residues of one or more other epoxide reactants of ethylene oxide (EO), propylene oxide (PO), or butylene oxide (BO), or mixtures thereof, wherein said poly(oxyalkylene) contains a total of from about 10 to about 600 of said EO, PO or BO residues, or mixtures thereof, at least about 75 mole percent of which are EO residues,(c) and with the provisions that the ratio of the total of --0--PO-- and --O--BO-- linkages of all glycidol residues to the total of all functional oxy linkages of said glycidol residues is less than one, and the molar ratio of EO residues to glycidol residues is from 4 to 75.

摘要翻译： 可用作各种底物的挥发性或永久性着色剂的着色剂和组合物，或作为其制造的中间体，并且具有一种或多种改进的水性洗涤性，与热塑性树脂的相容性和不可萃取性的改进性能，或与具有 所述组合物具有式C（Z）1-8，其中：C是具有与Z部分连接的1-8个亲核位点残基的反应物的残基; 所述Z部分包含至少约60重量％的聚（氧化烯），其由（a）至少一个连接到C的亲核位点的2-6个缩水甘油残基的缩水甘油残基部分组成，其中所述聚（氧化烯）含有 总共2-20个缩水甘油残基，（b），其中所述聚（氧化烯）还含有环氧乙烷（EO），环氧丙烷（PO）或环氧丁烷（BO））的一种或多种其它环氧化物反应物的残基， 或其混合物，其中所述聚（氧化烯）含有总共约10至约600的所述EO，PO或BO残基或其混合物，其至少约75摩尔％为EO残基，（c）和 所有缩水甘油残基的-O-PO-和-O-BO-键的总和与所述缩水甘油残基的所有功能氧键的总和的比例小于1，EO残基与 缩水甘油残基为4-75。

公开(公告)号：US5290921A

公开(公告)日：1994-03-01

申请号：US461852

申请日：1990-01-08

申请人： David J. Moody ,  Edward W. Kluger ,  John W. Rekers

发明人： David J. Moody ,  Edward W. Kluger ,  John W. Rekers

IPC分类号： C08G65/26 ,  C09B69/00 ,  C09B29/033 ,  C09B29/09 ,  D06P3/24

CPC分类号： C09B69/00 ,  C08G65/2627 ,  Y10S534/01

摘要： The present invention provides primary hydroxyl enhanced colorants having markedly improved reactivities in e.g., polyurethane foams for imparting permanent coloring thereto, the colorants having the formulaC--(Z).sub.1-4are provided wherein C is an azo, methine, or azamethine chromogen and Z is a poly(oxyalkylene) moiety comprised of (1) at least two (A) units independently selected from those of the formulae--CH.sub.2 CH(O--T)CH.sub.2 O-- or --CH.sub.2 CH(O--T)CH.sub.2 O--Tand (2) from none to about 200 (B) units of the formula (--RO--) wherein R is straight or branched chain hydrocarbon of 2-4 carbons, T is a moiety of the formula--CH.sub.2 CH(R.sub.1)--O--(RO).sub.0-40 --CH.sub.2 CH.sub.2 OHwherein R.sub.1 is selected from unsubstituted or substituted alkyl, aryl, alkenyloxyalkyl, alkoxyalkyl or aryloxyalkyl, and wherein the A units comprise at least 0.5 percent of the total A+B units.

摘要翻译： 本发明提供具有明显改善的反应性的主要羟基增强着色剂，例如用于赋予永久性着色的聚氨酯泡沫，提供了具有式C-（Z）1-4的着色剂，其中C是偶氮，次甲基或氮杂酮色原体， Z是由（1）独立地选自式-CH 2 CH（OT）CH 2 O-或-CH 2 CH（OT）CH 2 O-T的单元中的至少两个（A）单元组成的聚（氧化烯）部分，（2） 约200（B）单位的式（-RO-）其中R是2-4个碳的直链或支链烃，T是式-CH 2 CH（R 1）-O-（RO）0-40- 其中R 1选自未取代或取代的烷基，芳基，烯氧基烷基，烷氧基烷基或芳氧基烷基，其中A单元占总A + B单元的至少0.5％。

公开(公告)号：US5177200A

公开(公告)日：1993-01-05

申请号：US354184

申请日：1989-05-19

申请人： Edward W. Kluger ,  John W. Rekers ,  David J. Moody

发明人： Edward W. Kluger ,  John W. Rekers ,  David J. Moody

IPC分类号： C08K5/43 ,  C09B47/18 ,  C09B47/20 ,  C09B47/22 ,  C09B47/26 ,  C09B69/00

CPC分类号： C09B47/18 ,  C08K5/43 ,  C09B47/20 ,  C09B47/22 ,  C09B47/26 ,  C09B69/00

摘要： A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.2 is selected for example from hydrogen, methyl, cyclohexyl, phenyl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted for example with halogen, alkyl, alkoxy, alkylthio, or aryloxy; Y is a poly(oxyalkylene) moiety containing at least three monomeric units or mixtures thereof of the formula (--RO--) wherein each R is straight or branched alkylene of 2-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups such as alkyleneoxy, --NH--, or --NHCONH--, and wherein Y can be terminated by hydrogen, or by at branch subsituents, containing 1-3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substituents may themselves be substituted with up to four substituents selected, for example, from alkyl, halogen, mercapto, alkoxycarbonyl, hydroxy, alkoxy, or the like; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.

摘要翻译： 具有式A- [SO 2 -N（R 2）-Y] 1-4的天然或合成树脂或聚合物材料的着色剂; 其中：R2选自例如氢，甲基，环己基，苯基或Y; A是非离子金属酞菁发色团，其可以被卤素，烷基，烷氧基，烷硫基或芳氧基取代; Y是含有至少三个单体单元的聚（氧化烯）部分或其混合物（-RO-），其中每个R是2-4个碳原子的直链或支链亚烷基或其混合物，最多约20摩尔％ 单体单元可以通过一个或多个连接基团例如亚烷基氧基，-NH-或-NHCONH-连接，并且其中Y可以被氢封端，或者在支链取代基处含有1-3个选自烷基， 环烷基，酰基或芳基; 其中任何上述烃基，部分或取代基本身可以被至多四个选自例如烷基，卤素，巯基，烷氧基羰基，羟基，烷氧基等的取代基取代; 并且其中上述基团，部分或取代基的每个脂族烃部分或部分含有1-20个碳。

公开(公告)号：US4624980A

公开(公告)日：1986-11-25

申请号：US717049

申请日：1985-03-28

申请人： John W. Rekers ,  Edward W. Kluger

发明人： John W. Rekers ,  Edward W. Kluger

IPC分类号： C08K5/17 ,  C08K5/37 ,  C08L23/00

CPC分类号： C08K5/17

摘要： An N-t-alkyl-N-sec-alkyl secondary amine compound of the formula: ##STR1## wherein X, Y and Z are each independently selected from --H, --OH, or an alkyl group having from 1 to about 15 carbon atoms; and n is an integer of from 3 to about 6.

摘要翻译： 具有下式的N-t-烷基-N-仲烷基仲胺化合物：其中X，Y和Z各自独立地选自-H，-OH或具有1至约15个碳原子的烷基; n为3〜6的整数。

公开(公告)号：US4427597A

公开(公告)日：1984-01-24

申请号：US346788

申请日：1982-02-08

申请人： Edward W. Kluger

发明人： Edward W. Kluger

IPC分类号： C07C255/24 ,  C07C121/417

CPC分类号： C07C255/00

摘要： Nitrogen-containing compounds are provided of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from H or a lower alkyl group having from 1 to about 6 carbon atoms. Also provided is a process involving selective cyanoalkylation of amidoalkyldialkanolamines whereby nitrogen-containing compounds may be prepared.

摘要翻译： 含氮化合物由下式提供：其中R 1，R 2和R 3各自独立地选自H或具有1至约6个碳原子的低级烷基。 还提供了包括选择性氰基烷基化酰氨基烷基二烷醇胺的方法，由此可以制备含氮化合物。

公开(公告)号：US4352921A

公开(公告)日：1982-10-05

申请号：US230723

申请日：1981-02-02

申请人： Edward W. Kluger ,  Calvin D. Welch

发明人： Edward W. Kluger ,  Calvin D. Welch

IPC分类号： C08G59/50 ,  C08G59/64

CPC分类号： C07C255/00 ,  C08G59/504 ,  C08G59/64

摘要： Aminoalkoxyhexane compounds are provided having the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 are independently selected from H and ##STR2## wherein R.sub.6 is selected from H and a lower alkyl group having from 1 to about 4 carbon atoms.

摘要翻译： 提供具有下式的氨基烷氧基己烷化合物：其中R 1，R 2，R 3，R 4和R 5独立地选自H和其中R 6选自H和具有1至约4个碳的低级烷基 原子

公开(公告)号：US4351934A

公开(公告)日：1982-09-28

申请号：US230722

申请日：1981-02-02

申请人： Edward W. Kluger ,  Calvin D. Welch

发明人： Edward W. Kluger ,  Calvin D. Welch

IPC分类号： C08G59/50 ,  C08G59/64

CPC分类号： C08G59/64 ,  C08G59/504

摘要： Novel epoxy resin compositions are provided, comprising an epoxy resin and at least one aminoalkoxypropane of the formula: ##STR1## where R.sub.1, and R.sub.2 are independently selected from H and ##STR2## where R.sub.3 is selected from H and a lower alkyl group having from 1 to about 4 carbon atoms.

摘要翻译： 提供了新的环氧树脂组合物，其包含环氧树脂和至少一种下式的氨基烷氧基丙烷：其中R 1和R 2独立地选自H和，其中R 3选自H和低级烷基， 1至约4个碳原子。