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    Dinuclear complexes and polymerization catalysts therefrom
    1.
    发明授权
    Dinuclear complexes and polymerization catalysts therefrom 有权
    双核络合物和聚合催化剂

    公开(公告)号：US06235917B1

    公开(公告)日：2001-05-22

    申请号：US09234192

    申请日：1999-01-20

    申请人： David D. Graf ,  Jerzy Klosin ,  Peter N. Nickias ,  Jasson T. Patton

    发明人： David D. Graf ,  Jerzy Klosin ,  Peter N. Nickias ,  Jasson T. Patton

    IPC分类号： C07F1700

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F4/6592 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/03 ,  Y10S526/943 ,  C08F4/65927 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/12

    摘要： Group 3-6 or Lanthanide metal complexes possessing two metal centers joined by means of a divalent bridging group joining trivalent moieties comprising boron or a member of Group 14 of the Periodic Table of the Elements, and optionally also comprising nitrogen, phosphorus, sulfur or oxygen, in the complexes, catalysts derived therefrom by combining the same with strong Lewis acids, Bronsted acid salts, salts containing a cationic oxidizing agent or subjected to bulk electrolysis in the presence of compatible, inert non-coordinating anions and the use of such catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers are disclosed.

    摘要翻译： 具有两个金属中心的第3-6族或镧系元素金属络合物通过连接包含硼或元素周期表第14族成员的三价基团的二价桥连基团连接，并且任选还包含氮，磷，硫或氧 在络合物中，通过将其与强路易斯酸，布朗斯台德酸盐，含有阳离子氧化剂的盐或在相容的惰性非配位阴离子存在下进行本体电解，并将其用于 公开了烯烃，二烯烃和/或炔属不饱和单体的聚合。

    Olefin polymers prepared with substituted indenyl containing metal complexes
    10.
    发明授权
    Olefin polymers prepared with substituted indenyl containing metal complexes 失效
    用含有取代茚基的金属络合物制备的烯烃聚合物

    公开(公告)号：US06420507B1

    公开(公告)日：2002-07-16

    申请号：US09070957

    申请日：1998-05-01

    申请人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    发明人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    IPC分类号： C08F1000

    CPC分类号： C08F210/18 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/19 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/20

    摘要： The subject invention is directed to an olefin polymer produced by polymerizing at least one &agr;-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utility in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.

    摘要翻译： 本发明涉及通过在包含在2或3位被取代的茚基的第4族金属络合物与至少一种选自烃基，全氟取代基的基团的存在下聚合至少一种α-烯烃制备的烯烃聚合物 烃基，甲硅烷基，甲基和其混合物，所述茚基还通过二价配体基团与金属共价结合，其中二价配体包含具有通过伯或仲二价共价键合的脂族或脂环族烃基的氮或磷 碳。 本发明优选的烯烃聚合物的特征在于具有高分子量，窄分子量分布，高乙烯基含量和双峰DSC熔解曲线或解卷积的ATREF或GPC曲线，其显示出至少两个不同的窄峰。 烯烃聚合物可用于各种应用，包括但不限于薄膜，纤维，泡沫，模制部件，以及作为配方的组分，例如粘合剂，密封剂，涂料，填缝剂和沥青。