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    Heteromorphic polymer compositions
    1.
    发明授权
    Heteromorphic polymer compositions 失效
    异形聚合物组合物

    公开(公告)号：US06323285B1

    公开(公告)日：2001-11-27

    申请号：US09004442

    申请日：1998-01-09

    申请人： Robert T. Johnston ,  Evelyn J. Morrison ,  Debra J. Mangold ,  Thoi H. Ho

    发明人： Robert T. Johnston ,  Evelyn J. Morrison ,  Debra J. Mangold ,  Thoi H. Ho

    IPC分类号： C08L2304

    CPC分类号： C08L51/06 ,  C08F255/00 ,  C08F255/02 ,  C08F297/08 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2314/06 ,  C08L2666/02 ,  C09J151/06 ,  C08L2666/04 ,  C08L2666/24

    摘要： The subject invention pertains to heteromorphic polymer compositions characterized as comprising: (a) a homogeneous linear or substantially linear ethylene/&agr;-olefin interpolymer backbone; and (b) a branch appending from the backbone, which branch comprises an ethylene homopolymer or ethylene/&agr;-olefin interpolymer having a density which is at least 0.004 g/cm3 greater than that of the backbone. At least one of the backbone polymer or the branch polymer may be optionally functionalized to promote adhesion to polar surfaces. The heteromorphic polymer compositions of the invention exhibit enhanced upper service temperature. Also disclosed is a process for preparing the heteromorphic polymer compositions of the invention.

    摘要翻译： 本发明涉及异形聚合物组合物，其特征在于包括：（a）均匀的直链或基本上线性的乙烯/α-烯烃互聚物主链; 和（b）从主链附加的分支，该分支包含乙烯均聚物或乙烯/α-烯烃互聚物，其密度比主链的密度高至少0.004g / cm 3。 骨架聚合物或分支聚合物中的至少一种可以任选地官能化以促进与极性表面的粘附。 本发明的异型聚合物组合物表现出增强的上部使用温度。 还公开了制备本发明的异型聚合物组合物的方法。

    Olefin polymers prepared with substituted indenyl containing metal complexes
    3.
    发明授权
    Olefin polymers prepared with substituted indenyl containing metal complexes 失效
    用含有取代茚基的金属络合物制备的烯烃聚合物

    公开(公告)号：US06420507B1

    公开(公告)日：2002-07-16

    申请号：US09070957

    申请日：1998-05-01

    申请人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    发明人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

    IPC分类号： C08F1000

    CPC分类号： C08F210/18 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/19 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/20

    摘要： The subject invention is directed to an olefin polymer produced by polymerizing at least one &agr;-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utility in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.

    摘要翻译： 本发明涉及通过在包含在2或3位被取代的茚基的第4族金属络合物与至少一种选自烃基，全氟取代基的基团的存在下聚合至少一种α-烯烃制备的烯烃聚合物 烃基，甲硅烷基，甲基和其混合物，所述茚基还通过二价配体基团与金属共价结合，其中二价配体包含具有通过伯或仲二价共价键合的脂族或脂环族烃基的氮或磷 碳。 本发明优选的烯烃聚合物的特征在于具有高分子量，窄分子量分布，高乙烯基含量和双峰DSC熔解曲线或解卷积的ATREF或GPC曲线，其显示出至少两个不同的窄峰。 烯烃聚合物可用于各种应用，包括但不限于薄膜，纤维，泡沫，模制部件，以及作为配方的组分，例如粘合剂，密封剂，涂料，填缝剂和沥青。