摘要:
Copolymers of blocks of polymers of cyclic aliphatic carbonates, cyclic aliphatic esters or cyclic aliphatic carbonates and cyclic aliphatic esters on the one hand and blocks of polymers of cyclic aromatic carbonates on the other hand and a process for their production by multistage polymerization, in which a block polymer is initially prepared from the aliphatic monomer and the aromatic polymer is produced in the presence of this block.
摘要:
Thermoplastic moulding compositions composed ofI) 99.8-95% by weight of(A) 0-100% by weight of one or more graft polymers comprise the monomers styrene, .alpha.-methyl styrene, methyl methacrylate or a mixture of 95-50% by weight of styrene, .alpha.-methyl styrene, ring substituted styrene, methyl methacrylate or mixtures thereof with 5-50% by weight of methacrylonitrile, acrylonitrile, maleric acid anhydride, N-substituted malerimides or mixtures thereof, grafted onto a rubber substrate, andB) 100 to 0%, by weight of one or more thermoplastic vinyl polymers, andII) 0.2 to 5% by weight of a polyalkylene ether modified by a radical former which can be compounds conventionally used as an initiator for radical polymerization such as peroxides.
摘要:
Thermoplastic moulding compounds composed of99.8-95% by weight of A) 0-100% by weight of a graft polymer B) 100-0% by weight of a thermoplastic polymer of vinyl monomers and0.2 to 5% by weight of a polyalkylene ether which has been grafted with a polymer of C.sub.1 -C.sub.6 alkyl acrylates, cycloalkyl acrylates or methacrylates and optionally styrene or .alpha.-methyl styrene.
摘要:
Organic carbonates containing at least one aromatic ester group can be obtained in a continuous manner from carbonates containing at least one aliphatic ester group and a phenolic compound in the presence of a transesterification catalyst known per se by carrying out the reaction in at least two stirred containers connected one behind the other in such a way that, in each case, the phenolic compound is metered in liquid form into the first stirred container and the carbonate containing at least one aliphatic ester group is metered in liquid form into one or more of the stirred containers. The carbonate containing at least one aromatic ester group is removed in liquid form from the last stirred container. Volatile reaction products, for example alcohol which has been cleaved out or a dialkyl carbonate are removed in gaseous form from one or more stirred containers.
摘要:
Cyclic carbonic acid esters are produced by reaction of hydroxy compounds with phosgene in the presence of a heterocyclic compound containing at least one nitrogen atom as ring member in an aromatic ring.
摘要:
Carbonates with aromatic ester groups may be prepared by reacting aromatic monohydroxy compounds with phosgene or with chloroformates of aromatic monohydroxy compounds, wherein reaction takes place at a temperature in the range 50.degree. to 350.degree. C. in the presence of aluminum oxides as heterogeneous catalysts.
摘要:
Thermoplastic moulding compounds of 99.8-95% by weight of a mixture consisting of an aromatic polycarbonate, a graft polymer and optionally a thermoplastic vinyl polymer and/or the usual additives and 0.2 to 5% by weight of a polyalkylene ether which has been grafted with a polymer of C.sub.1 -C.sub.6 alkyl(meth)acrylates, cyclo-alkylacrylates or -methacrylates and optionally styrene or .alpha.-methylstyrene.
摘要:
This invention relates to mixtures of polycarbonates with graft polymers and copolymers which have been rendered flame resistant and which are characterized by containing modified polyalkylene ethers as antistatic agents.
摘要:
Polyalkylene terephthalates which contain small quantities of aliphatic polycarbonate show improved fracture behavior, without a significant adverse effect on the strength and the flowability in the melt. Moreover, the compositions show improved behavior in hot-air ageing.
摘要:
The present invention relates to a process for the continuous production of carbonates having aromatic ester groups by reacting aromatic hydroxy compounds with phosgene in the gas phase in the presence of heterogeneous catalysts.