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    Water- and oil-repellent fluorourethanes and fluoroureas
    2.
    发明申请
    Water- and oil-repellent fluorourethanes and fluoroureas 审中-公开
    防水和防油氟聚氨酯和氟脲

    公开(公告)号：US20060142530A1

    公开(公告)日：2006-06-29

    申请号：US11027633

    申请日：2004-12-28

    申请人： George Moore ,  Ramesh Kumar ,  Zai-Ming Qiu ,  John Clark ,  Chetan Jariwala

    发明人： George Moore ,  Ramesh Kumar ,  Zai-Ming Qiu ,  John Clark ,  Chetan Jariwala

    IPC分类号： C08G18/00

    CPC分类号： C08G18/2885 ,  C08G18/2845 ,  C08G18/3228 ,  C08G18/61 ,  C08G18/6212 ,  C08G18/6705 ,  C08G18/71 ,  C09D175/04 ,  Y10T428/31551

    摘要： A fluorochemical compound comprises the reaction product of: (a) the reaction product of: (i) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 6, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, q=1 to 8; and (ii) at least one unbranched symmetric diisocyanate, and (b) at least one co-reactant comprising two or more functional groups that are capable of reacting with an isocyanate group.

    摘要翻译： 含氟化合物包括以下反应产物：（a）反应产物：（i）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-Line Formulas”end =“lead” 其中：在线式公式描述=“在线公式”end =“tail”→>其中： n = 1至6，R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n N +1，y = 0〜6，q = 1〜8; 和（ii）至少一种非支化的对称二异氰酸酯，和（b）至少一种包含两个或更多个能够与异氰酸酯基团反应的官能团的共反应物。

    Fluoroacrylate-multifunctional acrylate copolymer compositions
    6.
    发明申请
    Fluoroacrylate-multifunctional acrylate copolymer compositions 有权
    氟丙烯酸酯 - 多官能丙烯酸酯共聚物组合物

    公开(公告)号：US20060142519A1

    公开(公告)日：2006-06-29

    申请号：US11027612

    申请日：2004-12-28

    申请人： Zai-Ming Qiu ,  George Moore ,  John Clark ,  Ramesh Kumar

    发明人： Zai-Ming Qiu ,  George Moore ,  John Clark ,  Ramesh Kumar

    IPC分类号： C08F118/02

    CPC分类号： C08F220/38 ,  Y10T428/3154 ,  Y10T442/2311 ,  Y10T442/232 ,  Y10T442/2754

    摘要： A composition comprises a copolymer comprising repeating units derived from at least one co-reactant comprising two or more acrylate groups and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y 32 0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion; wherein the composition is coatable.

    摘要翻译： 组合物包含共聚物，其包含衍生自至少一种包含两个或更多个丙烯酸酯基团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，所述重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： in-line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description 其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C 1， n = 2n + 1，n = 1〜5，y 32 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2-30个碳原子的2-氟丙烯酸酯单体; 其中所述组合物是可涂覆的。

    Fluoroacrylate-mercaptofunctional copolymers
    7.
    发明申请
    Fluoroacrylate-mercaptofunctional copolymers 有权
    氟丙烯酸酯 - 巯基官能共聚物

    公开(公告)号：US20060142518A1

    公开(公告)日：2006-06-29

    申请号：US11027605

    申请日：2004-12-28

    申请人： Zai-Ming Qiu ,  John Clark ,  Ramesh Kumar

    发明人： Zai-Ming Qiu ,  John Clark ,  Ramesh Kumar

    IPC分类号： C08F118/02

    CPC分类号： C08F220/38

    摘要： A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.

    摘要翻译： 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，该重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： -line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description = “直链式”末端=“尾”→其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f -C n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。

    FLUOROACRYLATE-MERCAPTOFUNCTIONAL COPOLYMERS
    8.
    发明申请
    FLUOROACRYLATE-MERCAPTOFUNCTIONAL COPOLYMERS 有权
    氟代丙烯酸酯共聚物

    公开(公告)号：US20080071021A1

    公开(公告)日：2008-03-20

    申请号：US11859295

    申请日：2007-09-21

    申请人： Zai-Ming Qiu ,  John Clark ,  Ramesh Kumar

    发明人： Zai-Ming Qiu ,  John Clark ,  Ramesh Kumar

    IPC分类号： C08L69/00

    CPC分类号： C08F220/38

    摘要： A copolymer comprises repeating units derived from at least one co-reactant comprising two or more mercapto functional groups, and repeating units derived from a fluoroacrylate comprising the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: C4F9—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, n=1 to 5, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoroacrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.

    摘要翻译： 共聚物包含衍生自至少一种包含两个或多个巯基官能团的共反应物的重复单元和衍生自氟代丙烯酸酯的重复单元，该重复单元包含以下反应产物：（a）至少一种由下式表示的含氟醇： -line-formula description =“In-line Formulas”end =“lead”？> C 3 -X-OH <？in-line-formula description = “直链式”末端=“尾”→其中：R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n n = 1〜5，y = 0〜6，q = 1〜8; （b）至少一种非支化对称二异氰酸酯; 和（c）至少一种羟基封端的（甲基）丙烯酸烷基酯或其亚烷基部分具有2至约30个碳原子的2-氟丙烯酸酯单体。

    Water-based release coating containing fluorochemical
    9.
    发明申请
    Water-based release coating containing fluorochemical 有权
    含氟化合物的水性防粘涂层

    公开(公告)号：US20060141194A1

    公开(公告)日：2006-06-29

    申请号：US11027606

    申请日：2004-12-28

    申请人： James Carlson ,  John Clark ,  James DiZio ,  David Kinning ,  Ramesh Kumar ,  Chetan Jariwala

    发明人： James Carlson ,  John Clark ,  James DiZio ,  David Kinning ,  Ramesh Kumar ,  Chetan Jariwala

    IPC分类号： B32B33/00

    CPC分类号： C09D133/02 ,  Y10S525/902 ,  Y10T428/14

    摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —(CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.

    摘要翻译： 一方面，本发明提供了一种水性防粘涂料组合物，其包含以下混合物：A.从0.1至约5wt％的氟（甲基）丙烯酸酯（共）聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物 具有式 - （CF 2）n CF 3，其中n为1至3的整数; B.约5至约99.9重量％的包含a的反应产物的共聚物。 约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，b。 约3至约20重量％的（甲基）丙烯酸，c。 约20至约40重量％的丙烯腈，以及d。 0至约15重量％的乙烯基单体，除了丙烯腈，其中a。 通过d。 等于100％; 和C.0至约94.9重量％的增量聚合物，其中A.，B.和C.的总和为100％，wt％基于组合物中固体的总量。

    Process for preparing fluorochemical monoisocyanates
    10.
    发明申请
    Process for preparing fluorochemical monoisocyanates 失效
    氟化物单异氰酸酯的制备方法

    公开(公告)号：US20050143595A1

    公开(公告)日：2005-06-30

    申请号：US10751142

    申请日：2003-12-31

    申请人： Thomas Klun ,  Alan Kirk ,  George Moore ,  John Clark

    发明人： Thomas Klun ,  Alan Kirk ,  George Moore ,  John Clark

    IPC分类号： C07C303/40 ,  C07C311/09 ,  C07C311/45

    CPC分类号： C07C303/40 ,  C07C311/09

    摘要： A process for preparing fluorochemical monoisocyanates comprises reacting at least one fluorochemical alcohol represented by the formula CnF2n+1SO2NCH3(CH2)mOH, wherein n=2 to 5, and m=2 to 4, with 4,4′-diphenylmethane diisocyanate (MDI) in a solvent in which the resulting fluorochemical monoisocyanate is not soluble; wherein the molar ratio of fluorochemical alcohol:MDI is from about 1:1 to about 1:2.5.

    摘要翻译： 一种制备含氟化合物单异氰酸酯的方法包括使至少一种由式C n 2 N 2n + 1 SO 2 NCH 3表示的含氟化合物醇反应， 其中n = 2〜5，m = 2〜4，与4,4'-二苯基甲烷二异氰酸酯（MDI）反应，得到（CH 2 CH 2）m OH ）在其中所得氟化异氰酸酯不溶于其中的溶剂中; 其中含氟醇：MDI的摩尔比为约1:1至约1:2.5。