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公开(公告)号：US20050143541A1
公开(公告)日：2005-06-30
申请号：US11027604
申请日：2004-12-28
申请人： Gregg Caldwell , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
发明人： Gregg Caldwell , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
IPC分类号： C07C69/653 , C07C233/18 , C07C271/08 , C07C271/20 , C07C271/28 , C07C311/04 , C07C311/09 , C08F20/24 , C08F220/38 , C08F114/18
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 氟代丙烯酸酯包括以下反应产物：（a）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-line Formulas”end =“lead”？> C
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公开(公告)号：US20060147703A1
公开(公告)日：2006-07-06
申请号：US11026674
申请日：2004-12-30
申请人： Christopher Walker , Roger Mader , Emily Goenner , Brant Kolb , Sharon Wang , Joan Noyola
发明人： Christopher Walker , Roger Mader , Emily Goenner , Brant Kolb , Sharon Wang , Joan Noyola
CPC分类号： G02B1/111 , C07C69/653 , C07C2603/18 , G02B1/10 , G02B1/14 , Y10T428/256 , Y10T428/31504 , Y10T428/3154
摘要： The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.
摘要翻译： 本发明包括含有采用溴取代芴结构的紫外线固化单体的光学涂层。 本发明单体的芴骨架也可以用一种或多种可聚合或反应性官能团官能化，最容易在9位。 本发明的组合物包括与无机纳米颗粒结合的反应性溴取代的芴，特别是具有表现出可聚合官能度的反应性表面改性剂的纳米颗粒。 考虑了表面改性氧化锆等反应性高折射率纳米粒子。
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公开(公告)号：US20080075959A1
公开(公告)日：2008-03-27
申请号：US11866521
申请日：2007-10-03
申请人： Christopher Walker , Roger Mader , Emily Goenner , Brant Kolb , Sharon Wang , Joan Noyola
发明人： Christopher Walker , Roger Mader , Emily Goenner , Brant Kolb , Sharon Wang , Joan Noyola
CPC分类号： G02B1/111 , C07C69/653 , C07C2603/18 , G02B1/10 , G02B1/14 , Y10T428/256 , Y10T428/31504 , Y10T428/3154
摘要： The present invention includes optical coatings containing ultraviolet curable monomers employing a bromine substituted fluorene structure. The fluorene backbone of the monomers of the present invention may also be functionalized with one or more polymerizable or reactive functionalities, and most readily at the 9 position. Compositions of the present invention include the reactive bromosubstituted fluorenes combined with inorganic nanoparticles, particularly nanoparticles with reactive surface modifiers exhibiting polymerizable functionality. Reactive high index nanoparticles such as surface modified zirconia are contemplated.
摘要翻译： 本发明包括含有采用溴取代芴结构的紫外线固化性单体的光学涂料。 本发明单体的芴骨架也可以用一种或多种可聚合或反应性官能团官能化，最容易在9位。 本发明的组合物包括与无机纳米颗粒结合的反应性溴取代的芴，特别是具有表现出可聚合官能度的反应性表面改性剂的纳米颗粒。 考虑了表面改性氧化锆等反应性高折射率纳米粒子。
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公开(公告)号：US20070173149A1
公开(公告)日：2007-07-26
申请号：US11688074
申请日：2007-03-19
申请人： Gregg CALDWELL , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
发明人： Gregg CALDWELL , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
IPC分类号： B32B27/04 , C08L31/00 , C08F8/30 , C07C271/14
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 4, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diusocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译： 氟代丙烯酸酯包括以下反应产物：（a）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-line Formulas”end =“lead”？> C
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公开(公告)号：US20060147702A1
公开(公告)日：2006-07-06
申请号：US11026573
申请日：2004-12-30
申请人： Richard Pokorny , Roger Mader , David Olson , Brant Kolb
发明人： Richard Pokorny , Roger Mader , David Olson , Brant Kolb
CPC分类号： C08F222/1006 , C08F290/06 , C08F290/061 , C08L53/00 , C08L53/005 , C09D4/00 , Y10T428/25 , Y10T428/256 , Y10T428/31935 , C08L2666/02
摘要： The development of new compositions and new aromatic sulfur acrylate monomers results in improved hardcoat films, and improved optical films that contain the hard coat films. The films provide improved display systems when incorporated thereon. The combination of functionalized zirconia nanoparticles with multifunctional acrylate crosslinkers and high index of refraction aromatic sulfur acrylates, about 1.58 or greater, produces abrasion resistant hard coats that have relatively high refractive indices.
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