公开(公告)号：US4927729A

公开(公告)日：1990-05-22

申请号：US266554

申请日：1988-11-03

Applicant: Horst Harnisch ,  Roderich Raue

Inventor： Horst Harnisch ,  Roderich Raue

IPC: C07D209/48 ,  C07D221/14 ,  G03G9/097

CPC classification number: C07D209/48 ,  C07D221/14

Abstract: Heteropolyacid salts of the formula ##STR1## R.sup.1 and R.sup.2 independently of one another stand for hydrogen, chlorine, bromine, hydroxyl, C.sub.1 - to C.sub.4 -alkoxy, nitro or carboxyl,A stand for C.sub.1 - to C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 -- (m- or p-),m stands for 0 or 1,n stands for 1 or 2,K.sup..sym. stands for ##STR2## R.sup.3 stands for C.sub.1 - to C.sub.24 -alkyl, carbamoyl-C.sub.1 - to C.sub.2 -alkyl, C.sub.1 - to C.sub.4 -alkoxycarbonyl-C.sub.1 - to C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 stands for C.sub.1 - to C.sub.4 -alkyl or a single bond linked to D,R.sup.5 stands for C.sub.1 - to C.sub.4 -alkyl,D stands for --CH.sub.2 --, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH-- or --CH.sub.2 --CO--NH--CH.sub.2 --,W stands for ##STR3## CO or for single bond, Z stands for --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 -- or a single bond and X.sup..crclbar. stands for an anion of a heteropolyacid based on tungsten and/or molybdenum containing phosphorus, silicon, vanadium, cobalt, nickel, manganese, chromium and/or aluminum,are used as additives for reinforcing the positive charge in electrographic toners.

Abstract translation: R 1和R 2彼此独立的杂多酸代表氢，氯，溴，羟基，C 1至C 4 - 烷氧基，硝基或羧基，A代表C 1至C 5 - 亚烷基或 -C 6 H 4 -CH 2 - （m-或对 - ），m代表0或1，n代表1或2，K（+）代表 R3代表C1-至C24-烷基，氨基甲酰基-C1- C 1〜C 4烷氧基羰基-C 1〜C 2烷基，苄基，环己基或烯丙基，R 4表示C 1至C 4烷基或与D连接的单键，R 5表示C 1 -C 4 - 烷基，D代表-CH 2 - ， - CH 2 -CO-， - CH 2 -CO-NH-或-CH 2 -CO-NH-CH 2 - ，W代表单键，Z代表-CH 2 - ， - S - ， - SO 2 - 或单键，X（ - ）表示基于含有磷，硅，钒，钴，镍的钨和/或钼的杂多酸的阴离子， 锰，铬和/或铝被用作增强电摄影调色剂中的正电荷的添加剂。

公开(公告)号：US5292881A

公开(公告)日：1994-03-08

申请号：US838129

申请日：1992-02-19

Applicant: Horst Berneth ,  Horst Harnisch ,  Roderich Raue ,  Jurgen-Rolf Hassdenteufel ,  Matthias Kocher

Inventor： Horst Berneth ,  Horst Harnisch ,  Roderich Raue ,  Jurgen-Rolf Hassdenteufel ,  Matthias Kocher

IPC: C07D221/14 ,  G03G9/097 ,  C07D413/06 ,  H01F1/00

CPC classification number: C07D221/14 ,  G03G9/09758

Abstract: New naphthalimides, useful as additives in toners for controlling the charge and conductivity, of the formula ##STR1## in which R represents C.sub.1 - to C.sub.22 -alkyl,R.sup.1 and R.sup.2 independently of one another in each case represent C.sub.1 - to C.sub.4 -alkyl, or R.sup.1 and R.sup.2, together with the nitrogen atom in between, form a pyrrolidine, piperidine or morpholine ring,n represents 2 or 3 andX.sup..crclbar. represent one equivalentof a benzoate or naphthoate, which is optionally substituted by chlorine, bromine, methyl, methoxy, hydroxyl, cyano and/or hydroxycarbonyl,of a benzenesulphonate which is substituted by hydroxyl, amino or nitro,of a naphthalenesulphonate which is optionally substituted by hydroxyl, amino or a sulphonic acid group, orof a fluorine-substituted anion of a C.sub.4 - to C.sub.18 -alkanecarboxylic or -alkanesulphonic acid.

Abstract translation: 式（*化学结构*）（I）中R表示C 1至C 22 - 烷基，R 1和R 2各自独立地相同的式（*化学结构*）（I）的新型萘二甲酰亚胺可用作用于调节电荷和电导率的调色剂中的添加剂， - 至C 4 - 烷基或R 1和R 2与其间的氮原子一起形成吡咯烷，哌啶或吗啉环，n表示2或3，X（负极）表示1当量的苯甲酸酯或萘甲酸酯，其为 任选被羟基，氨基或磺酸基取代的萘磺酸酯被羟基，氨基或硝基取代的苯磺酸的氯，溴，甲基，甲氧基，羟基，氰基和/或羟基羰基取代，或 的C4-至C18-烷烃羧酸或 - 烷基磺酸的氟取代阴离子。

公开(公告)号：US4997740A

公开(公告)日：1991-03-05

申请号：US438834

申请日：1989-11-17

Applicant: Horst Harnisch ,  Roderich Raue ,  Klaus Wunderlich

Inventor： Horst Harnisch ,  Roderich Raue ,  Klaus Wunderlich

IPC: G03G9/097

CPC classification number: G03G9/09758

Abstract: The invention relates to positively charged electrophotographic toners which, in addition to customary resin and pigment particles, contain an additive which intensifies the cationic charge, of the general formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another represent H, C.sub.1 -C.sub.22 -alkyl, allyl, cyclohexyl, phenyl-C.sub.1 -C.sub.2 -alkyl or phenyl andAn.sup.- denotes an anion,wherein the ring A and the cyclic and acyclic radicals can carry 1-2 nonionic substituents.

Abstract translation: 本发明涉及带正电荷的电子照相调色剂，其除常规树脂和颜料颗粒外，还含有增强阳离子电荷的添加剂，其通式为其中R1和R2彼此独立地表示H，C1 C22-烷基，烯丙基，环己基，苯基-C1-C2-烷基或苯基，An-表示阴离子，其中环A和环状和非环状基团可带有1-2个非离子取代基。

公开(公告)号：US4841052A

公开(公告)日：1989-06-20

申请号：US225329

申请日：1988-07-28

Applicant: Horst Harnisch ,  Roderich Raue

Inventor： Horst Harnisch ,  Roderich Raue

IPC: G03G9/097

CPC classification number: G03G9/09741

Abstract: Positively charged electrophotographic toners contain, in addition to conventional resin and pigment particles, an additive reinforcing the cationic charge, of the general formula ##STR1## in which R.sup.1 and R.sup.2 each represent hydrogen, chlorine,bromine, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or carboxyl,A represents C.sub.1 -C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 -- (m or p),m represents 0 or 1,n represents 1 or 2K.sup..sym. represents ##STR2## R.sup.3 represents C.sub.1 -C.sub.18 -alkyl, carbamoyl-C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 represents C.sub.1 -C.sub.4 -alkyl or a single bond linked to D,R.sup.5 represents C.sub.1 -C.sub.4 -alkyl,D represents --CH.sub.2, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH-- orW represents ##STR3## --CO-- or a single bond,Z represents --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 -- or a single bond and An.sup..crclbar. represents an anion.

Abstract translation: 带正电荷的电子照相色调剂除常规树脂和颜料颗粒外还含有增强阳离子电荷的添加剂，其通式为：其中R 1和R 2各自表示氢，氯，溴，羟基，C 1 C 1-4烷氧基或羧基，A表示C 1 -C 5亚烷基或-C 6 H 4 -CH 2 - （m或p），m表示0或1，n表示1或2 K（+）表示R 3表示C 1 -C 18 - 烷基，氨基甲酰基-C 1 -C 2 - 烷基，C 1 -C 4 - 烷氧基羰基-C 1 -C 2 - 烷基，苄基，环己基或烯丙基，R 4表示C 1 -C 4烷基或与D连接的单键，R 5表示C 1 -C 4 - 烷基，D表示-CH 2，-CH 2 -CO-，-CH 2 -CO-NH-或W表示-CO-或单键，Z表示-CH 2 - ， - ，-SO 2 - 或单键，并且An（ - ）表示阴离子。

公开(公告)号：US4256882A

公开(公告)日：1981-03-17

申请号：US711142

申请日：1976-08-03

Applicant: Adolf Friedrich ,  Horst Harnisch ,  Roderich Raue

Inventor： Adolf Friedrich ,  Horst Harnisch ,  Roderich Raue

IPC: C09B11/00 ,  C09B11/28 ,  C09B62/002 ,  C07D405/12 ,  C07D311/82

CPC classification number: C09B62/0025

Abstract: Reactive dyestuffs which in form of the free acid correspond to the following formula ##STR1## wherein R.sub.1, R.sub.2, W.sub.1, Y, Z, Q, as well as A, B and C have the meaning given in claim 1, and their use for the dyeing and printing of fibre material made of polyamide, for example natural and, in particular, synthetic polyamides, and natural and regenerated cellulose in red and bluish-tinged red fluorescent color.

Abstract translation: 游离酸形式的反应性染料对应于下式：其中R1，R2，W1，Y，Z，Q以及A，B和C具有权利要求1中给出的含义，它们用于 由聚酰胺制成的纤维材料的染色和印花，例如天然的，特别是合成的聚酰胺，以及红色和蓝色的红色荧光色的天然和再生的纤维素。

公开(公告)号：US4035740A

公开(公告)日：1977-07-12

申请号：US557081

申请日：1975-03-10

Applicant: Fritz Peter Schafer ,  Horst Harnisch ,  Roderich Raue

Inventor： Fritz Peter Schafer ,  Horst Harnisch ,  Roderich Raue

IPC: H01S3/20 ,  C09B57/02 ,  H01S3/213 ,  H03F1/22 ,  C09K11/00

CPC classification number: H01S3/213

Abstract: Coherent monochromatic radiation (laser light) in the wave length range of 450 to 560 nm is obtained by exciting with a pump light source a dyestuff solution containing a dyestuff of the formula ##STR1## wherein R.sub.1 represents hydrogen, alkyl, cycloalkyl, aralkyl, an alkylene radical linked to the 6-position of the coumarin ring system or, together with R.sub.2 and the nitrogen atom to which they are bonded, and optionally with inclusion of further heteroatoms as ring members, represents the remaining members of a heterocyclic ring system, R.sub.2 represents alkyl, aralkyl or an alkylene radical linked to the 8-position of the coumarin ring system and R.sub.3 represents hydrogen or an optionally substituted phenyl radical, the rings A and B can carry further substituents and a carbocyclic 5-membered or 6-membered ring can be fused to the ring B, in a solvent which does not interfere with the emission, at a concentration, which emits laser beams, of, preferably, 10.sup.-.sup.2 to 10.sup.-.sup.4 mol/liter.

Abstract translation: 通过用泵浦光源激发含有下式的染料的染料溶液获得在450-560nm的波长范围内的相干单色辐射（激光），其中R 1表示氢，烷基，环烷基，芳烷基， 与香豆素环体系的6-位连接的亚烷基或与R 2和它们所键合的氮原子一起，并且任选地包含另外的杂原子作为环成员，表示杂环系统的剩余成员，R2 代表烷基，芳烷基或连接到香豆素环体系的8-位的亚烷基，R 3表示氢或任选取代的苯基，环A和B可以携带另外的取代基和碳环5元或6元环 可以在发射激光束的浓度下不干扰发射的溶剂中的环B熔融，优选为10 -2至10 -4 mol / L。

公开(公告)号：US5013627A

公开(公告)日：1991-05-07

申请号：US390557

申请日：1989-08-07

Applicant: Horst Harnisch ,  Roderich Raue

Inventor： Horst Harnisch ,  Roderich Raue

IPC: C07D209/44 ,  C07D471/06 ,  C07D487/04 ,  G03G9/097

CPC classification number: C07D471/06 ,  C07D209/44 ,  C07D487/04 ,  G03G9/09758

Abstract: Positively charged electrophotographic toners contain, besides customary resin and pigment particles, an additive which increases the cationic charge and has the general formula(X.sup.1).sup.- K.spsp.+.sup.1 -Y.sup.1 -A-Y.sup.2 -K.spsp.+.sup.2 (X.sub.2).sup.- (I)wherein the symbols have the meaning mentioned in the description.

Abstract translation: 带正电荷的电子照相色调剂除通常的树脂和颜料颗粒外还含有增加阳离子电荷并具有通式（X1）-K + 1-Y1-A-Y2-K + 2（X2） - （I）的添加剂，其中 符号具有说明书中提及的含义。

公开(公告)号：US4812379A

公开(公告)日：1989-03-14

申请号：US10364

申请日：1987-02-03

Applicant: Horst Harnisch ,  Roderich Raue

Inventor： Horst Harnisch ,  Roderich Raue

IPC: G03G9/097 ,  G03G9/16

CPC classification number: G03G9/09741

Abstract: Postively charged electrophotographic toners contain, in addition to conventional resin and pigment particles, an additive reinforcing the cationic charge, of the general formula ##STR1## in which R.sup.1 and R.sup.2 each represent hydrogen, chlorine, bromine, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or carboxyl,A represents C.sub.1 -C.sub.5 -alkylene or --C.sub.6 H.sub.4 --CH.sub.2 --(m or p),m represents 0 to 1,n represents 1 or 2K.sup..sym. represents ##STR2## R.sup.3 represents C.sub.1 -C.sub.18 -alkyl, carbamoyl-C.sub.1 -C.sub.2 -alkyl, C.sub.1 -C.sub.4 -alkoxycarbonyl-C.sub.1 -C.sub.2 -alkyl, benzyl, cyclohexyl or allyl,R.sup.4 represents C.sub.1 -C.sub.4 -alkyl or a single bond linked to D,R.sup.5 represents C.sub.1 -C.sub.4 -alkyl,D represent --CH.sub.2, --CH.sub.2 --CO--, --CH.sub.2 --CO--NH--or --CH.sub.2 --CO--NH--CH.sub.2 --W represents ##STR3## --CO--or a single bond, Z represents --CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 --or a single bond and An.sup..crclbar. represents an anion.

Abstract translation: 除了常规的树脂和颜料颗粒之外，带电荷的电子照相色调剂还包含增强阳离子电荷的添加剂，其通式为：其中R 1和R 2各自表示氢，氯，溴，羟基， C 1 -C 4 - 烷氧基或羧基，A表示C 1 -C 5亚烷基或-C 6 H 4 -CH 2 - （m或p），m表示0至1，n表示1或2 K（+）表示R 3表示C1- C18烷基，氨基甲酰基C1-C2-烷基，C1-C4-烷氧基羰基-C1-C2-烷基，苄基，环己基或烯丙基，R4代表C1-C4-烷基或与D连接的单键，R5代表C1-C4 - 烷基，D表示-CH2，-CH2-CO-，-CH2-CO-NH-或-CH2-CO-NH-CH2-W表示-CO-或单键，Z表示-CH2-， -O - ， - S - ， - SO 2 - 或单键，An（ - ）表示阴离子。

公开(公告)号：US4051134A

公开(公告)日：1977-09-27

申请号：US633781

申请日：1975-11-20

Applicant: Adolf Friedrich ,  Horst Harnisch ,  Roderich Raue

Inventor： Adolf Friedrich ,  Horst Harnisch ,  Roderich Raue

IPC: C09B57/08 ,  C09B62/002 ,  C07D401/10

CPC classification number: C09B62/0025 ,  C09B57/08

Abstract: Reactive dyestuffs of the formula ##STR1## wherein W, T, T', n, R, R.sub.1, R.sub.2, p and Z have the meaning given in the description, their preparation and their use for dyeing and printing materials containing N and materials containing hydroxyl groups, especially fibre materials. The dyestuffs are particularly suitable as fluorescent dyestuffs for dyeing or printing natural and synthetic polyamides and natural and regenerated cellulose, especially cotton. They combine a high fixing yield with outstanding wet fastness properties.

Abstract translation: 其中W，T，T'，n，R，R1，R2，p和Z具有说明书中给出的含义及其制备方法及其用于含有N的染料和印刷材料的用途的反应性染料， 羟基，特别是纤维材料。 该染料特别适用于染色或印刷天然和合成聚酰胺以及天然和再生纤维素，特别是棉花的荧光染料。 它们结合了高定影产率和出色的耐湿牢度性能。

公开(公告)号：US4849306A

公开(公告)日：1989-07-18

申请号：US158520

申请日：1988-02-22

Applicant: Roderich Raue ,  Hubertus Psaar ,  Horst Berneth

Inventor： Roderich Raue ,  Hubertus Psaar ,  Horst Berneth

IPC: G03G9/097 ,  C09B23/00 ,  C09B55/00 ,  G03G9/09

CPC classification number: G03G9/0916 ,  G03G9/0922

Abstract: Dry toners for developing latent electrostatic images in electrostatic recording and printing methods contain, as charge-control substance, a pigment of the formulaF.sup.+ A.sup.- (I)in whichF represent a cationic radical of a methine dyestuff andA.sup.- represents an anion of a heteropolyacid based on tungsten and/or molybdenum with phosphorus, silicon, vanadium, cobalt, aluminum, manganese, chromium and/or nickel or a copper(I) hexacyanoferrate anion.

Abstract translation: 用于在静电记录和印刷方法中显影静电潜像的干性调色剂含有作为电荷控制物质的式F + A-（I）的颜料，其中F表示次甲基染料的阳离子基团，A-表示阴离子 基于钨和/或钼与磷，硅，钒，钴，铝，锰，铬和/或镍或铜（I）六氰基铁酸盐阴离子的杂多酸。