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    Dry toners containing methinefanal pigments
    1.
    发明授权
    Dry toners containing methinefanal pigments 失效
    含有次甲醛颜料的干性调色剂

    公开(公告)号：US4849306A

    公开(公告)日：1989-07-18

    申请号：US158520

    申请日：1988-02-22

    申请人： Roderich Raue ,  Hubertus Psaar ,  Horst Berneth

    发明人： Roderich Raue ,  Hubertus Psaar ,  Horst Berneth

    IPC分类号： G03G9/097 ,  C09B23/00 ,  C09B55/00 ,  G03G9/09

    CPC分类号： G03G9/0916 ,  G03G9/0922

    摘要： Dry toners for developing latent electrostatic images in electrostatic recording and printing methods contain, as charge-control substance, a pigment of the formulaF.sup.+ A.sup.- (I)in whichF represent a cationic radical of a methine dyestuff andA.sup.- represents an anion of a heteropolyacid based on tungsten and/or molybdenum with phosphorus, silicon, vanadium, cobalt, aluminum, manganese, chromium and/or nickel or a copper(I) hexacyanoferrate anion.

    摘要翻译： 用于在静电记录和印刷方法中显影静电潜像的干性调色剂含有作为电荷控制物质的式F + A-（I）的颜料，其中F表示次甲基染料的阳离子基团，A-表示阴离子 基于钨和/或钼与磷，硅，钒，钴，铝，锰，铬和/或镍或铜（I）六氰基铁酸盐阴离子的杂多酸。

    3H-Indol-2-yl cationic hydrazone dyestuffs
    3.
    发明授权
    3H-Indol-2-yl cationic hydrazone dyestuffs 失效
    3H-吲哚-2-基阳离子腙染料

    公开(公告)号：US4496719A

    公开(公告)日：1985-01-29

    申请号：US466709

    申请日：1983-02-15

    申请人： Roderich Raue

    发明人： Roderich Raue

    IPC分类号： C09B26/02 ,  C09B26/04 ,  C07D209/12 ,  C07D403/12

    CPC分类号： C09B26/04

    摘要： Hydrazone dyestuffs of the formula ##STR1## in which R denotes optionally substituted alkyl,R.sup.1 denotes alkyl and the two radicals can form a closed ring,R.sup.2 denotes optionally substituted alkyl,R.sup.3 denotes alkyl, alkoxy or halogen,R.sup.4 denotes alkyl, halogen, alkoxy, phenoxy, benzyloxy, benzyl, carboxyl, alkyl carboxylate, carboxamide, sulphonamide, alkylsulphonyl, phenylsulphonyl, cyano, nitro, trifluoromethyl, acetyl or benzoyl,B denotes ##STR2## D denotes alkylene, phenylene or naphthylene, E denotes halogen, hydroxyl, alkoxy or ##STR3## Z and Z.sup.1 denote hydrogen or --Y--Z.sup.2, Y denotes alkylene,Z.sup.2 denotes hydrogen, hydroxyl, pyridinium, ##STR4## Z.sup.3, Z.sup.4 and Z.sup.5 denote hydrogen or optionally substituted alkyl,Z.sup.3 also denotes phenyl, benzyl or ##STR5## Y.sup.1 denotes alkylene and s denotes 1-8, orZ and Z.sup.1 as well as Z.sup.3 and Z.sup.4 form a closed ring,G denotes alkylene, phenylene orG denotes alkylene, phenylene or ##STR6## m and n denote 0, 1 or 2 and X.sup.(-) denotes an anion,are used in particular for dyeing paper.

    摘要翻译： 其中R表示任选取代的烷基，R 1表示烷基且两个基团可以形成闭环，R 2表示任选取代的烷基，R 3表示烷基，烷氧基或卤素，R 4表示烷基， ，卤素，烷氧基，苯氧基，苄氧基，苄基，羧基，羧酸烷基酯，甲酰胺，磺酰胺，烷基磺酰基，苯基磺酰基，氰基，硝基，三氟甲基，乙酰基或苯甲酰基，B表示亚烷基，亚苯基或 亚萘基，E表示卤素，羟基，烷氧基或Z表示氢或-Y-Z2，Y表示亚烷基，Z2表示氢，羟基，吡啶鎓，Z3，Z4和Z5表示氢或任选取代的烷基 Z3也表示苯基，苄基或Y1表示亚烷基，s表示1-8或Z和Z1以及Z3和Z4形成闭环，G表示亚烷基，亚苯基或G表示亚烷基，亚苯基或 m和n表示0,1或2，X（ - ）表示阴离子 特别用于染色纸。

    Process for the preparation of trimethine dyestuffs
    4.
    发明授权
    Process for the preparation of trimethine dyestuffs 失效
    三甲基染料的制备方法

    公开(公告)号：US4419511A

    公开(公告)日：1983-12-06

    申请号：US344262

    申请日：1982-01-28

    申请人： Roderich Raue

    发明人： Roderich Raue

    IPC分类号： C09B23/00 ,  C09B23/06

    CPC分类号： C09B23/06

    摘要： To prepare trimethine dyestuffs of the general formula ##STR1## wherein R represents a C.sub.1 - to C.sub.4 -alkyl radical,R.sup.1 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, benzyl, cyclohexyl, C.sub.1 - to C.sub.4 -alkoxy, benzyloxy, phenoxy, halogen, trifluoromethyl, acetylamino, carboxylic acid C.sub.1 - to C.sub.4 -alkyl esters, carbonamide which may be substituted by C.sub.1 - to C.sub.4 -alkyl and/or phenyl, C.sub.1 - to C.sub.4 -alkylsulphonyl, phenylsulphonyl, cyano, nitro, benzoxazol-2-yl, benzimidazol-2-yl, benzthiazol-2-yl and sulphonamide which may be monosubstituted or disubstituted by C.sub.1 - to C.sub.4 -alkyl, or two radicals R.sup.1 represent a fused benzene ring,n denotes 1 to 4 andA.sup.- denotes an anionic radical, first an alkali metal salt of formic acid is reacted with a mixture of acetic acid and acetic anhydride and the product is then reacted with indoline compounds of the general formula ##STR2## in which R, R.sup.1 and n have the abovementioned meaning.

    摘要翻译： 为了制备通式“IMAGE”的三甲基染料，其中R表示C 1〜C 4 - 烷基，R 1表示氢，C 1至C 4 - 烷基，苄基，环己基，C 1至C 4 - 烷氧基，苄氧基，苯氧基，卤素 三氟甲基，乙酰氨基，羧酸C 1至C 4烷基酯，可被C 1至C 4 - 烷基和/或苯基取代的碳酰胺，C 1至C 4 - 烷基磺酰基，苯基磺酰基，氰基，硝基，苯并恶唑-2-基 苯并咪唑-2-基，苯并噻唑-2-基和磺酰胺，其可以被C 1 -C 4烷基单取代或二取代，或两个基团R 1表示稠合苯环，n表示1至4，A-表示阴离子基团 首先将甲酸的碱金属盐与乙酸和乙酸酐的混合物反应，然后使产物与其中R，R 1和n具有上述含义的通式为“IMAGE”的二氢吲哚化合物反应。

    Fluorescent dyestuffs
    6.
    发明授权
    Fluorescent dyestuffs 失效
    荧光染料

    公开(公告)号：US4301091A

    公开(公告)日：1981-11-17

    申请号：US73773

    申请日：1979-09-10

    申请人： Rudolf Schieder ,  Helmut Telle ,  Roderich Raue ,  Wolfgang Brinkwerth

    发明人： Rudolf Schieder ,  Helmut Telle ,  Roderich Raue ,  Wolfgang Brinkwerth

    IPC分类号： C09B57/00 ,  C07C309/28 ,  C07C309/32 ,  C07F9/40 ,  C09B23/14 ,  D06L3/12 ,  H01S3/20 ,  H01S3/213 ,  C07C143/24 ,  D06P1/38

    CPC分类号： C07C309/00 ,  C07F9/4056 ,  H01S3/20 ,  H01S3/213

    摘要： Fluorescent dyestuffs of the formula ##STR1## wherein: R.sub.1 and R.sub.2 independently of one another represent hydrogen, a salt-forming cation, an alkyl radical with 1 to 8 carbon atoms or an aralkyl radical which is optionally substituted by non-chromophoric groups,R.sub.2 to R.sub.5 independently of one another represent hydrogen, alkyl, trifluoromethyl, alkoxy, aralkoxy, alkenyloxy, halogen or the carboxyl, cyano, alkylsulphonyl, arylsulphonyl, carboxamide or sulphonamide group or a carboxylic acid ester group, m and n independently of one another denote 0, 1 or 2 and the sum of m+n must be at least 2, and o, p, q and r independently of one another represent 0, 1 or 2.processes for their preparation, their use for whitening organic materials and a process for the production of a coherent laser emission using the fluorescent dyestuffs according to formula I.

    摘要翻译： 具有式（I）的荧光染料其中：R 1和R 2彼此独立地表示氢，形成盐的阳离子，具有1至8个碳原子的烷基或任选被非发色团取代的芳烷基 R 2至R 5彼此独立地表示氢，烷基，三氟甲基，烷氧基，芳烷氧基，烯氧基，卤素或羧基，氰基，烷基磺酰基，芳基磺酰基，甲酰胺或磺酰胺基或羧酸酯基，m和n独立地为一个 另一个表示0,1或2，m + n的和必须至少为2，o，p，q和r彼此独立地表示0,1或2。

    Dyestuff laser
    7.
    发明授权
    Dyestuff laser 失效
    染料激光

    公开(公告)号：US4271395A

    公开(公告)日：1981-06-02

    申请号：US866521

    申请日：1978-01-03

    申请人： Uwe Brinkmann ,  Helmut Telle ,  Roderich Raue

    发明人： Uwe Brinkmann ,  Helmut Telle ,  Roderich Raue

    IPC分类号： H01S3/20 ,  C09B57/00 ,  H01S3/213

    CPC分类号： H01S3/213

    摘要： Laser light in the wavelength range of 420-480 nm is obtained with a dyestuff laser containing a dyestuff of the general formula ##STR1## wherein R and R.sub.1 independently of one another represent ##STR2## R.sub.2 denotes an optionally substituted alkyl radical with 1-4 C atoms, R.sub.3 and R.sub.4 independently of one another represent hydrogen or optionally substituted C.sub.1 -C.sub.4 -alkyl or conjointly with the nitrogen can form a 5-membered or 6-membered heterocyclic ring andm and n denote 1 or 2, andwhereinthe aromatic radicals contained in the formula can be further substituted, in a solvent which does not interfere with the emission, at a concentration, which emits laser beams, of, preferably, 10.sup.-2 to 10.sup.-5 mols/liter.

    摘要翻译： 使用含有通式为＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;的染料的染料激光获得波长范围为420-480nm的激光，其中R和R 1彼此独立地表示，表示任选取代的烷基 具有1-4个C原子的基团，R 3和R 4彼此独立地表示氢或任选取代的C 1 -C 4烷基或与氮稠合形成5元或6元杂环，m和n表示1或2 并且其中式中所含的芳族基团可以在发射激光束的浓度不优于10-2至10-5摩尔/升的不干扰发射的溶剂中被进一步取代。

    Cationic dyestuffs
    8.
    发明授权
    Cationic dyestuffs 失效
    阳离子染料

    公开(公告)号：US4145537A

    公开(公告)日：1979-03-20

    申请号：US514999

    申请日：1974-10-15

    申请人： Hubertus Psaar ,  Roderich Raue

    发明人： Hubertus Psaar ,  Roderich Raue

    IPC分类号： C09B23/00 ,  C09B23/01 ,  C09B23/10 ,  D06P1/42 ,  D06P3/02 ,  C07D417/06

    CPC分类号： D06P1/42 ,  C09B23/005 ,  C09B23/0058 ,  C09B23/105 ,  D06P3/022

    摘要： Dyestuffs of the formula ##STR1## IN WHICH R denotes hydrogen, alkyl, alkenyl, cycloalkyl, aralkyl, aryl, alkoxy, aralkoxy, aryloxy, alkylamino, aralkylamino, arylamino, acylamino, carboxylic acid ester, carbonamido, acyl, halogen or nitrile, R.sub.1 denotes hydrogen, alkyl or aralkyl, R.sub.2 denotes hydrogen, alkyl, alkenyl, carbonamide or nitrile, R.sub.3 denotes alkyl, alkenyl or aralkyl, R.sub.4 denotes hydrogen, alkyl, alkenyl, aralkyl, alkoxy or aralkoxy, alkylamino, aralkylamino, acylamino, carbonamido, nitrile, nitro or halogen, R.sub.5 and R.sub.6 denote hydrogen, alkyl, aralkyl or a cycloaliphatic 5-membered or 6-membered ring, or R.sub.6 together with R.sub.1 forms a hydroaromatic 6-membered ring and An.sup.(-) represents an anion, and Processes for their preparation and their use for dyeing and printing natural and synthetic materials.

    摘要翻译： 式中，R表示氢，烷基，烯基，环烷基，芳烷基，芳基，烷氧基，芳烷氧基，芳氧基，烷基氨基，芳烷基氨基，芳基氨基，酰氨基，羧酸酯，碳酰氨基，酰基，卤素或腈，R1 表示氢，烷基或芳烷基，R2表示氢，烷基，烯基，碳酰胺或腈，R3表示烷基，烯基或芳烷基，R4表示氢，烷基，烯基，芳烷基，烷氧基或芳烷氧基，烷基氨基，芳烷基氨基，酰氨基， ，硝基或卤素，R 5和R 6表示氢，烷基，芳烷基或脂环族5元或6元环，或者R 6与R 1一起形成水合芳族六元环，并且An（ - ）表示阴离子，而PROCESSES FOR 他们的制备及其用于染色和印刷天然和合成材料的使用。

    Dyestuff laser
    9.
    发明授权
    Dyestuff laser 失效
    染料激光

    公开(公告)号：US4100509A

    公开(公告)日：1978-07-11

    申请号：US702080

    申请日：1976-07-02

    申请人： Herbert Walther ,  Wolfgang Hartig ,  Adolf Friedrich ,  Roderich Raue

    发明人： Herbert Walther ,  Wolfgang Hartig ,  Adolf Friedrich ,  Roderich Raue

    IPC分类号： H01S3/20 ,  H01S3/213

    CPC分类号： H01S3/20 ,  H01S3/213

    摘要： A dye laser employing a solution of: ##STR1## wherein R and R.sub.1 independently of one another represent hydrogen, alkyl, cycloalkyl or aralkyl or can form, with R.sub.2 or R.sub.3, or with R.sub.4 or R.sub.5, a partially hydrogenated 5-membered or 6-membered heterocyclic ring, R.sub.2 - R.sub.5 independently of one another represent hydrogen, alkyl, alkoxy or halogen or can form, with R or R.sub.1, a partially hydrogenated 5-membered or 6-membered heterocyclic ring,Me represents hydrogen, a monovalent or divalent metal cation, or the ammonium, monoalkylammonium, dialkylammonium or trialkylammonium radical, and m and n denote a number between 1 and 4,And whereinThe rings, A, B and C as well as the aliphatic or aromatic radicals present in the formula can also be substituted further,In a concentration which emits laser beams, preferably of 10.sup.-2 to 10.sup.-5 mol litre.

    摘要翻译： 使用以下溶液的染料激光：其中R和R 1彼此独立地表示氢，烷基，环烷基或芳烷基，或者可以与R 2或R 3，或与R 4或R 5形成部分氢化的5元或6元 R 2 -R 5彼此独立地表示氢，烷基，烷氧基或卤素，或者可以与R或R 1形成部分氢化的5元或6元杂环，Me表示氢，一价或二价 金属阳离子或铵，单烷基铵，二烷基铵或三烷基铵基，m和n表示1至4之间的数字，并且环，A，B和C以及式中存在的脂族或芳族基团也可以 在进一步的替代品中，以10-2至10-5 MOL LITER的优先权为特征。