公开(公告)号：US20160152549A1

公开(公告)日：2016-06-02

申请号：US14706670

申请日：2015-05-07

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Chao-Huang CHEN ,  Chiou-Hwang LEE ,  Hsi-Yen HSU

IPC: C07C209/72 ,  B01J23/58

CPC classification number: C07C209/72 ,  B01J23/002 ,  B01J23/58 ,  B01J35/008 ,  B01J35/023 ,  B01J35/1019 ,  B01J37/0205 ,  B01J37/035 ,  B01J37/088 ,  B01J2523/00 ,  C07C2601/14 ,  C07C211/36 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/821 ,  B01J2523/822

Abstract: Disclosed is a catalyst for hydrogenation of 4,4′-methylenedianiline (MDA), including a support, a magnesium-aluminum oxide layer covering the support, and a rhodium-ruthenium active layer loaded on the magnesium-aluminum oxide layer, wherein the rhodium and the ruthenium of the rhodium-ruthenium active layer have a weight ratio of 40:60 to 10:90. The hydrogenation catalyst can be collocated with hydrogen for hydrogenation of the MDA to form bis(para-amino cyclohexyl) methane (PACM), and the PACM contains O mol % to 25 mol % of (t,t)-isomer.

Abstract translation: 公开了一种用于氢化4,4'-亚甲基二苯胺（MDA）的催化剂，包括载体，覆盖载体的镁 - 铝氧化物层和负载在镁 - 氧化铝层上的铑 - 钌活性层，其中铑 铑 - 钌活性层的钌的重量比为40:60〜10:90。 氢化催化剂可以与氢配位以氢化MDA以形成双（对 - 氨基环己基）甲烷（PACM），PACM含有0mol％至25mol％的（t，t） - 异构体。

公开(公告)号：US20230348278A1

公开(公告)日：2023-11-02

申请号：US18346549

申请日：2023-07-03

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Kuo-Ching WU ,  Hsi-Yen HSU ,  Chao-Huang CHEN ,  Yuan-Peng DU

IPC: B01J21/06 ,  C01B32/40 ,  B01J21/04 ,  B01J23/00 ,  B01J23/889 ,  B01J29/08

CPC classification number: C01B32/40 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/002 ,  B01J23/8892 ,  B01J29/084

Abstract: A method for selectively chemically reducing CO2 to form CO includes providing a catalyst, and contacting H2 and CO2 with the catalyst to chemically reduce CO2 to form CO. The catalyst includes a metal oxide having a chemical formula of FexCoyMn(1-x-y)Oz, in which 0.7≤x≤0.95, 0.01≤y≤0.25, and z is an oxidation coordination number.

公开(公告)号：US20230183074A1

公开(公告)日：2023-06-15

申请号：US17550895

申请日：2021-12-14

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Kuo-Ching WU ,  Hsi-Yen HSU ,  Chao-Huang CHEN ,  Yuan-Peng DU

IPC: C01B32/40 ,  B01J23/889 ,  B01J23/00 ,  B01J21/06 ,  B01J21/04 ,  B01J29/08

CPC classification number: C01B32/40 ,  B01J21/04 ,  B01J21/063 ,  B01J21/066 ,  B01J23/002 ,  B01J23/8892 ,  B01J29/084

Abstract: A method for selectively chemically reducing CO2 to form CO includes providing a catalyst, and contacting H2 and CO2 with the catalyst to chemically reduce CO2 to form CO. The catalyst includes a metal oxide having a chemical formula of FexCoyMn(1-x-y)Oz, in which 0.7≤x≤0.95, 0.01≤y≤0.25, and z is an oxidation coordination number.

公开(公告)号：US20210197177A1

公开(公告)日：2021-07-01

申请号：US17135515

申请日：2020-12-28

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Chao-Huang CHEN ,  Jyun-Da WU ,  Tzong-Shyan LU ,  Ying-Chieh LEE

IPC: B01J23/46 ,  B01J21/10 ,  B01J37/02 ,  B01J35/10 ,  B01J8/02 ,  C07C209/72

Abstract: A catalyst composition for hydrogenating 4,4′-methylenedianiline derivatives is provided. The catalyst composition includes a carrier including aluminum oxide and magnesium oxide, a rhodium-ruthenium active layer loaded on the surface of the carrier, and a solvent including an organic amine. The weight percentage of magnesium oxide in the carrier is between 12% and 30%. A method for preparing 4,4′-methylene bis(cyclohexylamine) derivatives using the catalyst composition is also provided.

公开(公告)号：US20240198318A1

公开(公告)日：2024-06-20

申请号：US18433005

申请日：2024-02-05

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Kuo-Ching WU ,  Pao-Tsern LIN ,  Hsi-Yen HSU ,  Chao-Huang CHEN

IPC: B01J23/745 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  C07C1/12

CPC classification number: B01J23/745 ,  B01J35/615 ,  B01J35/633 ,  B01J35/647 ,  C07C1/12 ,  C07C2523/745

Abstract: A method of hydrogenating carbon dioxide, including contacting carbon dioxide and hydrogen with an iron-based catalyst to form a liquid and a gas. The liquid includes CnH2n, CnH2n+2, or a combination thereof and water, wherein n is 5 to 18. The gas includes CH4, CmH2m, CmH2m+2, or a combination thereof, hydrogen, and carbon dioxide, wherein m is 2 to 9. The iron-based catalyst includes 70 mol % to 97 mol % of porous FeO(OH)x (wherein 1

公开(公告)号：US20210197174A1

公开(公告)日：2021-07-01

申请号：US16731783

申请日：2019-12-31

Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

Inventor： Chao-Huang CHEN ,  Jyun-Da WU ,  Tzong-Shyan LU ,  Ying-Chieh LEE

IPC: B01J23/46 ,  B01J21/10 ,  B01J21/04 ,  B01J35/10 ,  C07C209/72

Abstract: A catalyst composition for hydrogenating 4,4′-methylenedianiline is provided. The catalyst composition includes a carrier including aluminum oxide and magnesium oxide, a rhodium-ruthenium active layer loaded on the surface of the carrier, and organic amine solvent. The weight percentage of magnesium oxide in the carrier is between 12% and 30%. A method for preparing 4,4′-methylene bis(cyclohexylamine) using the catalyst composition is also provided.