公开(公告)号：US20240360063A1

公开(公告)日：2024-10-31

申请号：US18685337

申请日：2022-10-26

Applicant: University of Cape Town

Inventor： Eric Wilhelmus Josephus van Steen ,  Junfeng Guo ,  Malefane Gerard Leteba ,  Nasseela Hytoolakhan Lal Mahomed ,  Sinqobile Vuyisile Lusanda Mahlabe

IPC: C07C45/33 ,  B01J21/06 ,  B01J21/18 ,  B01J23/42 ,  B01J23/50 ,  B01J23/652 ,  B01J23/89 ,  B01J35/30 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C07C29/50

CPC classification number: C07C45/33 ,  B01J21/063 ,  B01J21/18 ,  B01J23/42 ,  B01J23/50 ,  B01J23/6525 ,  B01J23/892 ,  B01J35/394 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/088 ,  B01J37/18 ,  C07C29/50

Abstract: A continuous process for aerobic oxidation of methane. The process includes a reactor (10) comprising a bed of a metal-based catalyst (16), a methane feed stream (30) into the reactor (10), an oxygen feed stream (30) into the reactor (10), and a water feed stream (12) into the reactor (10). The methane is oxidised in a single step in the reactor (10) over the metal-based catalyst (16) in the presence of liquid water to produce a reaction product including compounds selected from formaldehyde, oligomers of formaldehyde, methanediol, and products of addition reactions between methanol and formaldehyde, and mixtures thereof.

公开(公告)号：US20240326022A1

公开(公告)日：2024-10-03

申请号：US18604220

申请日：2024-03-13

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Nam Dong KIM ,  Jae Young JUNG ,  Sung Jong YOO ,  Bon-Cheol KU ,  Min Woo KIM ,  Hyeonsu JEONG

IPC: B01J23/75 ,  B01J21/18 ,  B01J35/30 ,  B01J35/45 ,  B01J35/50 ,  B01J35/61 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J23/75 ,  B01J21/185 ,  B01J35/393 ,  B01J35/394 ,  B01J35/45 ,  B01J35/505 ,  B01J35/617 ,  B01J37/0221 ,  B01J37/088

Abstract: Provided is a single atom catalyst based on a carbon nanotube according to the present invention including a carbon support; and single atom metals supported on the carbon support, wherein the carbon support has a cone shape with an empty space formed therein and includes at least one carbon support having an open tip of the corn-shaped carbon support.

公开(公告)号：US20240307854A1

公开(公告)日：2024-09-19

申请号：US18413452

申请日：2024-01-16

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Hiroki SHIRAKAWA ,  Takahiro NISHIO ,  Shogo SHIRAKAWA

IPC: B01J23/46 ,  B01D53/94 ,  B01J21/04 ,  B01J37/02 ,  B01J37/08 ,  F01N3/28

CPC classification number: B01J23/464 ,  B01D53/9413 ,  B01J21/04 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/088 ,  F01N3/2803 ,  B01D2255/1025 ,  B01D2257/404 ,  B01D2258/01 ,  F01N2370/02

Abstract: The present disclosure provides an exhaust gas purifying catalyst having improved durability of rhodium, which comprises a carrier and rhodium (Rh), wherein the carrier comprises aluminum oxide (Al2O3), and 15% to 60% of the rhodium is dissolved in the carrier.

公开(公告)号：US12070738B2

公开(公告)日：2024-08-27

申请号：US17642885

申请日：2020-09-15

Applicant: SYNTHOS DWORY 7 SPÓŁKA Z OGRANICZONA̧ ODPOWIEDZIALNOŚCIA̧

Inventor： Ewelina Jankowiak ,  Szymon Skowronek ,  Piotr Zapala

IPC: B01J23/20 ,  B01J21/08 ,  B01J35/61 ,  B01J37/02 ,  B01J37/08 ,  C07C1/207

CPC classification number: B01J23/20 ,  B01J21/08 ,  B01J35/615 ,  B01J35/617 ,  B01J37/0213 ,  B01J37/0236 ,  B01J37/088 ,  C07C1/2072 ,  C07C2521/08 ,  C07C2523/20

Abstract: The invention relates to a process for the production of 1,3-butadiene from a feed comprising ethanol and acetaldehyde in the presence of a supported tantalum catalyst obtainable by aqueous impregnation of the support with a water-soluble tantalum precursor. Furthermore, the present invention relates to a process for the production of a supported tantalum catalyst, and the supported tantalum catalyst. Finally, the invention relates to the use of the supported tantalum catalyst for the production of 1,3-butadiene from a feed comprising ethanol and acetaldehyde to increase one or both of selectivity and yield of the reaction.

公开(公告)号：US12043800B2

公开(公告)日：2024-07-23

申请号：US17779519

申请日：2020-11-17

Applicant: Petróleo Brasileiro S.A.—Petrobras

Inventor： Adriano do Couto Fraga ,  Andrea de Rezende Pinho ,  Marlon Brando Bezerra de Almeida ,  Vitor Loureiro Ximenes

IPC: C10G1/08 ,  B01J23/04 ,  B01J37/08 ,  C10G3/00 ,  C10G1/00

CPC classification number: C10G1/086 ,  B01J23/04 ,  B01J37/088 ,  C10G3/44 ,  C10G1/002 ,  C10G2300/1014 ,  C10G2300/4081

Abstract: The present invention addresses to a hydrothermal liquefaction process capable of generating a liquid stream, rich in renewable molecules, with lower oxygen content, lower percentage of water and lower acidity compared to other products of thermochemical processes of biomass conversion. In order to effectively carry out this process, a catalyst was developed, obtained from the calcination of castor bean hull, to be used in the field of biofuels in order to provide an environmentally friendly alternative for the production of fuels.

公开(公告)号：US12042786B2

公开(公告)日：2024-07-23

申请号：US18073742

申请日：2022-12-02

Applicant: BP P.L.C.

Inventor： Manuel Ojeda Pineda ,  Alexander James Paterson

IPC: B01J21/06 ,  B01J23/75 ,  B01J23/889 ,  B01J35/00 ,  B01J35/02 ,  B01J35/30 ,  B01J35/40 ,  B01J35/50 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  C10G2/00

CPC classification number: B01J23/8892 ,  B01J21/063 ,  B01J23/75 ,  B01J35/19 ,  B01J35/393 ,  B01J35/40 ,  B01J35/50 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/0236 ,  B01J37/088 ,  B01J37/18 ,  C10G2/331 ,  C10G2300/70

Abstract: The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C5+ hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.

公开(公告)号：US20240228404A9

公开(公告)日：2024-07-11

申请号：US18547530

申请日：2022-02-18

Applicant: Dow Global Technologies LLC

Inventor： Glenn Pollefeyt ,  Fang Du ,  Ewa Tocha ,  Alexey Kirilin ,  Christopher Ho ,  David F. Yancey ,  Davy L. S. Nieskens ,  Andrzej Malek

IPC: C07C1/12 ,  B01J21/04 ,  B01J21/06 ,  B01J23/10 ,  B01J29/85 ,  B01J35/00 ,  B01J35/40 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08

CPC classification number: C07C1/12 ,  B01J21/04 ,  B01J21/066 ,  B01J23/10 ,  B01J29/85 ,  B01J35/19 ,  B01J35/40 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/088 ,  B01J2229/42 ,  C07C2523/08

Abstract: A process for preparing C2 to C4 hydrocarbons includes introducing a feed stream including hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor, and converting the feed stream into a product stream including C2 to C4 hydrocarbons in the reaction zone in the presence of a formed hybrid catalyst. The formed hybrid catalyst includes a metal oxide catalyst component including gallium oxide and zirconia, a microporous catalyst component that is a molecular sieve having 8-MR (Membered Ring) pore openings, and a binder including alumina, zirconia, or both.

公开(公告)号：US20240226858A1

公开(公告)日：2024-07-11

申请号：US18558408

申请日：2022-05-05

Applicant: BASF SE

Inventor： Thomas HEIDEMANN ,  Stephanie Sybille LINKE ,  Viktor ULRICH ,  Matthias HINRICHS ,  Michael FRIKO

IPC: B01J23/89 ,  B01J21/06 ,  B01J21/08 ,  B01J23/889 ,  B01J35/30 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/18 ,  C07C209/36

CPC classification number: B01J23/892 ,  B01J21/066 ,  B01J21/08 ,  B01J23/8896 ,  B01J35/394 ,  B01J37/0201 ,  B01J37/031 ,  B01J37/088 ,  B01J37/18 ,  C07C209/36

Abstract: The present invention relates to a catalytic material comprising Ni, one or more additional metals M, and an oxidic support material comprising Si and Zr, both in oxidic form, as well as a process for preparation thereof. In addition thereto, the present invention relates to a use of the inventive catalytic material as a catalyst or catalyst component, especially in a hydrogenation reaction.

公开(公告)号：US20240207822A1

公开(公告)日：2024-06-27

申请号：US18545922

申请日：2023-12-19

Applicant: PETROLEO BRASILEIRO S.A. - PETROBRAS ,  UNIVERSIDADE FEDERAL DO CEARA

Inventor： Solange Assunção QUINTELLA ,  Jose Andre Cavalcanti Da Silva ,  Francisco Murilo Tavares De Luna ,  Charles Lima Bessa Assuncao ,  Maria Thiciane Almeida Costa ,  Celio Loreiro Cavalcante, JR. ,  Maria Imaculada G. Silveira Teixeira

IPC: B01J23/20 ,  B01J21/08 ,  B01J35/30 ,  B01J35/45 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07C67/26 ,  C10M105/34 ,  C10N20/00 ,  C10N20/02

CPC classification number: B01J23/20 ,  B01J21/08 ,  B01J35/394 ,  B01J35/45 ,  B01J35/617 ,  B01J35/635 ,  B01J35/638 ,  B01J35/647 ,  B01J37/009 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/04 ,  B01J37/088 ,  C07C67/26 ,  C10M105/34 ,  C10M2207/2815 ,  C10N2020/02 ,  C10N2020/081

Abstract: The present invention relates to a multifunctional hybrid catalyst with niobium and tin supported on hexagonal mesoporous silicas (HMSNb—Sn), synthesis process thereof through isomorphic substitutions and the process for obtaining biodegradable lubricating base oils using said catalyst.

公开(公告)号：US12017206B2

公开(公告)日：2024-06-25

申请号：US17955012

申请日：2022-09-28

Applicant: ZHEJIANG UNIVERSITY OF TECHNOLOGY

Inventor： Feng Feng ,  Xiaonian Li ,  Lingling Guo ,  Yanxia Sun ,  Chunshan Lu ,  Qunfeng Zhang ,  Jiatong Jin ,  Xiaoliang Xu

IPC: C07D241/42 ,  B01J21/04 ,  B01J23/89 ,  B01J37/00 ,  B01J37/02 ,  B01J37/04 ,  B01J37/08

CPC classification number: B01J23/894 ,  B01J21/04 ,  B01J37/009 ,  B01J37/024 ,  B01J37/04 ,  B01J37/088 ,  C07D241/42

Abstract: A preparation method of Cu—Pd—CeO2/γ-Al2O3@NP catalyst and a synthesis method of benzopyrazine compounds. The preparation method of the Cu—Pd—CeO2/γ-Al2O3@NP catalyst comprises the following steps: (1) preparing a CeO2/γ-Al2O3 carrier; (2) preparing a CeO2/γ-Al2O3@NP carrier; (3) preparing the Cu—Pd—CeO2/γ-Al2O3@NP catalyst by impregnation method. A one-pot method for synthesizing benzopyrazine compounds of formula (III) includes using an o-nitroaniline compound of formula (I) and an aliphatic diol compound of formula (II) as raw materials, carrying out the one-pot synthesis of the benzopyrazine compound of formula (III) under solvent-free condition and under the combined action of the Cu—Pd—CeO2/γ-Al2O3@NP catalyst prepared by the method and an alkali. The Cu—Pd—CeO2/γ-Al2O3@NP catalyst increases the number of basic sites by doping N and P, and meanwhile loads CeO2 to assist in the extraction of protons, thereby improving the dehydrogenation activity and product selectivity.