Organosilicone compositions and methods for preparing them
    2.
    发明授权
    Organosilicone compositions and methods for preparing them 有权
    有机硅组合物及其制备方法

    公开(公告)号:US07902314B2

    公开(公告)日:2011-03-08

    申请号:US12718552

    申请日:2010-03-05

    摘要: Disclosed herein is a composition comprising a structure (M1)a(ME)b(D1)c(D2)d(T)e(Q)f, wherein M1=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D1=R6R7SiO2/2; D2=R8R9SiO2/2; T=R10SiO3/2; and Q=SiO4/2; wherein each RE is independently a monovalent hydrocarbon radical containing an epoxy group; R9 comprises a structure -L1-Si(R11)g(OR12)3-g or L2(D3)h(M2)i-L3-Si(R13)g′(OR14)3-g′, wherein L1, L2, and L3 are independently divalent linking groups; g and g′ independently have a value from 0 to 2; M2=R15R16R17SiO1/2; D3=R18R19SiO2/2; wherein R1, R2, R3, R4, R5, R6, R7, R8, R10, R11, R12, R13, R14, R15, R16, R17, R18, and R19 are independently monovalent hydrocarbon radicals; wherein a, b, c, d, e, f, h, and i are stoichiometric subscripts that are zero or positive subject to the following limitations: b has a value of 2; d is greater than or equal to 1; when (a+c+e+f) is equal to zero, (b+d) is greater than or equal to 3; and when i=0, h is at least 1.

    摘要翻译: 本文公开了包含结构(M1)a(ME)b(D1)c(D2)d(T)e(Q)f的组合物,其中M1 = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D1 = R6R7SiO2 / 2; D2 = R8R9SiO2 / 2; T = R10SiO3 / 2; 和Q = SiO4 / 2; 其中每个RE独立地为含有环氧基的单价烃基; R9包括结构-L1-Si(R11)g(OR12)3-g或L2(D3)h(M2)i-L3-Si(R13)g'(OR14)3-g',其中L1,L2, 和L3独立地是二价连接基团; g和g'独立地具有0至2的值; M2 = R15R16R17SiO1 / 2; D3 = R18R19SiO2 / 2; 其中R1,R2,R3,R4,R5,R6,R7,R8,R10,R11,R12,R13,R14,R15,R16,R17,R18和R19独立地是一价烃基; 其中a,b,c,d,e,f,h和i是化学计量下标,其为零或正,受制于以下限制:b具有值2; d大于或等于1; 当(a + c + e + f)等于零时,(b + d)大于或等于3; 当i = 0时,h至少为1。

    Organosilicone Compositions and Methods for Preparing Them
    3.
    发明申请
    Organosilicone Compositions and Methods for Preparing Them 有权
    有机硅组合物及其制备方法

    公开(公告)号:US20100249358A1

    公开(公告)日:2010-09-30

    申请号:US12718552

    申请日:2010-03-05

    IPC分类号: C08G77/06

    摘要: Disclosed herein is a composition comprising a structure (M1)a(ME)b(D1)c(D2)d(T)e(Q)f, wherein M1=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D1=R6R7SiO2/2; D2=R8R9SiO2/2; T=R10SiO3/2; and Q=SiO4/2; wherein each RE is independently a monovalent hydrocarbon radical containing an epoxy group; R9 comprises a structure -L1-Si(R11)g(OR12)3-g or L2(D3)h(M2)i-L3-Si(R13)g′(OR14)3-g′, wherein L1, L2, and L3 are independently divalent linking groups; g and g′ independently have a value from 0 to 2; M2=R15R16R17SiO1/2; D3=R18R19SiO2/2; wherein R1, R2, R3, R4, R5, R6, R7, R8, R10, R11, R12, R13, R14, R15, R16, R17, R18, and R19 are independently monovalent hydrocarbon radicals; wherein a, b, c, d, e, f, h, and i are stoichiometric subscripts that are zero or positive subject to the following limitations: b has a value of 2; d is greater than or equal to 1; when (a+c+e+f) is equal to zero, (b+d) is greater than or equal to 3; and when i=0, h is at least 1.

    摘要翻译: 本文公开了包含结构(M1)a(ME)b(D1)c(D2)d(T)e(Q)f的组合物,其中M1 = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D1 = R6R7SiO2 / 2; D2 = R8R9SiO2 / 2; T = R10SiO3 / 2; 和Q = SiO4 / 2; 其中每个RE独立地为含有环氧基的单价烃基; R9包括结构-L1-Si(R11)g(OR12)3-g或L2(D3)h(M2)i-L3-Si(R13)g'(OR14)3-g',其中L1,L2, 和L3独立地是二价连接基团; g和g'独立地具有0至2的值; M2 = R15R16R17SiO1 / 2; D3 = R18R19SiO2 / 2; 其中R1,R2,R3,R4,R5,R6,R7,R8,R10,R11,R12,R13,R14,R15,R16,R17,R18和R19独立地是一价烃基; 其中a,b,c,d,e,f,h和i是化学计量下标,其为零或正,受制于以下限制:b具有值2; d大于或等于1; 当(a + c + e + f)等于零时,(b + d)大于或等于3; 当i = 0时,h至少为1。

    Copolyetheresters derived from polyethylene terephthalate
    8.
    发明授权
    Copolyetheresters derived from polyethylene terephthalate 有权
    衍生自聚对苯二甲酸乙二醇酯的共聚醚酯

    公开(公告)号:US08110609B2

    公开(公告)日:2012-02-07

    申请号:US12852668

    申请日:2010-08-09

    IPC分类号: C08J11/04

    摘要: The invention relates to a composition comprising a modified, random copolyetherester containing a modified, random polytrimethylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers and combinations thereof; and contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component. The composition has a modulus of elasticity that is at least 80%, as compared to the modulus of elasticity of a copolyetherester derived from (1) polytrimethylene terephthalate derived from a monomer component selected from the group consisting of terephthalic acid, isophthalic acid, alkyl esters of terephthalic acid, hydroxyalkyl esters of terephthalic acid, alkyl esters of isophthalic acid, 1,3-propane diol, (2) polyalkylene oxide glycol, and (3) combinations thereof.

    摘要翻译: 本发明涉及一种组合物,其包含改性的无规共聚醚酯,其含有由聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物及其组合组成的组中的聚对苯二甲酸乙二醇酯组分衍生的改性的无规聚对苯二甲酸丙二醇酯共聚物嵌段; 并含有至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基; 和含有聚环氧烷和至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基的聚环氧烷共聚物嵌段。 该组合物的弹性模量与源自(1)选自对苯二甲酸,间苯二甲酸,烷基酯的单体组分的(1)聚对苯二甲酸丙二醇酯的共聚醚酯的弹性模量相比,至少为80% 的对苯二甲酸,对苯二甲酸的羟烷基酯,间苯二甲酸的烷基酯,1,3-丙二醇,(2)聚环氧烷二醇,和(3)它们的组合。

    Articles derived from compositions containing modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET)
    9.
    发明授权
    Articles derived from compositions containing modified polybutylene terephthalate (PBT) random copolymers derived from polyethylene terephthalate (PET) 有权
    衍生自衍生自聚对苯二甲酸乙二醇酯(PET)的改性聚对苯二甲酸丁二醇酯(PBT)无规共聚物的组合物的制品

    公开(公告)号:US07935737B2

    公开(公告)日:2011-05-03

    申请号:US11668189

    申请日:2007-01-29

    IPC分类号: C08J11/04

    摘要: Compositions of matter including articles derived from (a) from 5 to 99.99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate and (2) contains a at least one residue derived from polyethylene terephthalate selected from the group consisting of antimony, germanium, diethylene glycol groups, isophthalic acid groups, cis isomer of cyclohexane dimethanol, trans isomer of cyclohexane dimethanol, sodium benzoate, alkali salts, napthalane dicarboxylic acids, 1,3-propane diols, cobalt, cobalt-containing compounds, and combinations thereof, and (b) from 0.01 to 95 wt. % of a member selected from the group consisting of (1) fillers, (2) a carboxy reactive component, (3) polyethyelene terephthalate, (4) a component including a polycarbonate and an impact modifier. The articles may be derived from various conversion processes, e.g., injection molding processes, extrusion processes, thermoforming processes, melt-blown process.

    摘要翻译: 包括衍生自(a)5至99.99重量%的改性聚对苯二甲酸丁二醇酯无规共聚物的物质组合物,(1)衍生自聚对苯二甲酸乙二醇酯和(2)含有至少一种衍生自聚对苯二甲酸乙二醇酯的残基, 由锑,锗,二甘醇基,间苯二甲酸基,环己烷二甲醇的顺式异构体,环己烷二甲醇的反式异构体,苯甲酸钠,碱金属盐,萘二甲酸,1,3-丙二醇,钴,含钴化合物, 及其组合,和(b)0.01至95wt。 选自(1)填料,(2)羧基反应性组分,(3)聚对苯二甲酸乙二醇酯,(4)包含聚碳酸酯和抗冲改性剂的组分的组分的%。 制品可以衍生自各种转化方法,例如注射成型工艺,挤出工艺,热成型工艺,熔喷工艺。

    Process for the manufacture of lonomeric polybutylene terephthalate from polyethylene terephthalate, and compositions and articles thereof
    10.
    发明授权
    Process for the manufacture of lonomeric polybutylene terephthalate from polyethylene terephthalate, and compositions and articles thereof 有权
    用于从聚对苯二甲酸乙二醇酯制造单体聚对苯二甲酸丁二醇酯的方法及其组合物和制品

    公开(公告)号:US07928150B2

    公开(公告)日:2011-04-19

    申请号:US12115753

    申请日:2008-05-06

    IPC分类号: C08J9/00

    摘要: An ionomeric, modified poly(1,4-butylene terephthalate) copolymer comprising: polyester units comprising non-ionomeric ester units and ionomeric ester units substituted with an inorganic ionic group; and polyester units having at least one residue that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate and polyethylene terephthalate copolymers is described.

    摘要翻译: 共聚物,包括:由非离子聚酯酯单元和被无机离子基团取代的离聚单体酯单元的聚酯单元; 并且描述了具有至少一种衍生自选自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分的残余物的聚酯单元。