Sodium vanadium oxide anode material for sodium ion secondary battery, preparation method thereof and sodium ion secondary battery having the same
    4.
    发明授权
    Sodium vanadium oxide anode material for sodium ion secondary battery, preparation method thereof and sodium ion secondary battery having the same 有权
    用于钠离子二次电池的钠钒氧化物阳极材料及其制备方法和具有其的钠离子二次电池

    公开(公告)号:US09166225B2

    公开(公告)日:2015-10-20

    申请号:US13966497

    申请日:2013-08-14

    Abstract: There is provided a preparation method of a sodium vanadium oxide-based (Na1+xV1−xO2) anode material for a sodium ion secondary battery synthesized by mixing particles of precursors such as sodium carbonate (Na2CO3) and vanadium oxide (V2O3) and pyrolyzing a mixture in a mixed gas atmosphere composed of 90 mol % of nitrogen gas and 10 mol % of hydrogen gas through a solid-state reaction. The sodium vanadium oxide-based anode material prepared according to the present invention shows a small change in volume caused by an initial irreversible capacity and continuous charge/discharge reactions, and thus it is useful for providing a next-generation sodium ion secondary battery having stable charge/discharge characteristics and cycle performance.

    Abstract translation: 提供了通过混合前体如碳酸钠(Na 2 CO 3)和氧化钒(V 2 O 3)的颗粒合成的钠离子二次电池的钠钒氧化物(Na1 + xV1-xO2)阳极材料的制备方法,并将 通过固相反应在由90mol%的氮气和10mol%的氢气组成的混合气体气氛中进行混合。 根据本发明制备的基于氧化钒的阳极材料显示由初始不可逆容量和连续充放电反应引起的体积变化小,因此可用于提供具有稳定的下一代钠离子二次电池 充放电特性和循环性能。

    Electrolyte for magnesium rechargeable battery and preparation method thereof
    7.
    发明授权
    Electrolyte for magnesium rechargeable battery and preparation method thereof 有权
    镁可充电电池用电解液及其制备方法

    公开(公告)号:US09543616B2

    公开(公告)日:2017-01-10

    申请号:US14633807

    申请日:2015-02-27

    Abstract: Disclosed is an electrolyte solution for a magnesium rechargeable battery with a high ionic conductivity and a wide electrochemical window compared to the conventional electrolyte solution. The electrolyte solution is prepared by dissolving magnesium metal into the ethereal solution using combinations of metal chloride catalysts. The electrolyte solution can be applied to fabricate magnesium rechargeable batteries and magnesium hybrid batteries with a markedly increased reversible capacity, rate capability, and cycle life compared to those batteries employing the conventional electrolyte solution. Also disclosed is a method for preparing the electrolyte.

    Abstract translation: 公开了与常规电解质溶液相比,具有高离子电导率和宽电化学窗口的镁可充电电池的电解液。 通过使用金属氯化物催化剂的组合将镁金属溶解在醚溶液中来制备电解质溶液。 与使用常规电解质溶液的电池相比,电解质溶液可用于制造镁可充电电池和镁混合电池,其具有显着增加的可逆容量,速率能力和循环寿命。 还公开了一种制备电解质的方法。

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