公开(公告)号：US10744482B2

公开(公告)日：2020-08-18

申请号：US16434472

申请日：2019-06-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US11077423B2

公开(公告)日：2021-08-03

申请号：US16943998

申请日：2020-07-30

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  C07D241/10 ,  C07F19/00 ,  B01D53/02

Abstract: Embodiments of the present disclosure describe metal-organic framework compositions comprising a pillar characterized by the formula (MbF5(O/H2O)), where Mb is selected from periodic groups IIIA, IIIB, IVB, VB, VIB, and VIII; and a square grid characterized by the formula (Ma(ligand)x), where Ma is selected from periodic groups IB, IIA, IIB, IIIA, IVA, IVB, VIB, VIIB, and VIII, ligand is a polyfunctional organic ligand, and x is 1 or more; wherein the pillaring of the square grid with the pillars forms the metal-organic framework.

公开(公告)号：US10328414B2

公开(公告)日：2019-06-25

申请号：US15564909

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Karim Adil ,  Youssef Belmabkhout ,  Osama Shekhah ,  Prashant M. Bhatt ,  Amandine Cadiau

IPC: B01J20/22 ,  B01J31/16 ,  B01D53/02 ,  B01J20/28 ,  B01J20/30 ,  C07F19/00 ,  C07D241/10

Abstract: Provided herein are metal organic frameworks having high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Metal organic frameworks can comprise metal nodes and N-donor organic ligands. Further provided are methods of making metal organic frameworks.

公开(公告)号：US11229872B2

公开(公告)日：2022-01-25

申请号：US16903820

申请日：2020-06-17

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Infas Haja Mohideen ,  Karim Adil ,  Youssef Belmabkhout ,  Mohamed Eddaoudi ,  Prashant M. Bhatt

IPC: B01D53/04 ,  B01D53/047 ,  B01J20/28 ,  B01J20/22 ,  B01J20/30 ,  C07C45/78 ,  B01D53/02

Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

公开(公告)号：US10759724B2

公开(公告)日：2020-09-01

申请号：US15952511

申请日：2018-04-13

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Mohamed Infas Haja Mohideen ,  Karim Adil ,  Prashant M. Bhatt ,  Osama Shekhah ,  Valeriya Chernikova

IPC: C07C7/13 ,  B01J20/02 ,  B01J20/04 ,  B01J20/22 ,  B01J20/28 ,  B01J31/16

Abstract: Embodiments of the present disclosure describe a zeolite-like metal-organic framework composition comprising a metal-organic framework composition with ana topology characterized by the formula [MIII(4, 5-imidazole dicarboxylic acid)2X(solvent)a]n wherein MIII comprises a trivalent cation of a rare earth element, X comprises an alkali metal element or alkaline earth metal element, and solvent comprises a guest molecule occupying pores. Embodiments of the present disclosure describe a method of separating paraffins comprising contacting a zeolite-like metal-organic framework with ana topology with a flow of paraffins, and separating the paraffins by size.

公开(公告)号：US10328380B2

公开(公告)日：2019-06-25

申请号：US15564935

申请日：2016-04-07

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/02 ,  B01D53/52 ,  B01D53/62 ,  B01D53/72 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J31/16 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  C07F5/06 ,  C07F9/00 ,  C07F15/02 ,  C07F15/04

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US11534712B2

公开(公告)日：2022-12-27

申请号：US17109844

申请日：2020-12-02

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/02 ,  B01D53/04 ,  B01D53/52 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J20/02 ,  B01J20/22 ,  B01J20/28 ,  B01J20/34 ,  B01J31/16 ,  C07F15/02 ,  C07F15/04 ,  C07F5/06 ,  C07F9/00

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.

公开(公告)号：US11491459B2

公开(公告)日：2022-11-08

申请号：US17008419

申请日：2020-08-31

Applicant: King Abdullah University of Science and Technology

Inventor： Mohamed Eddaoudi ,  Youssef Belmabkhout ,  Mohamed Infas Haja Mohideen ,  Karim Adil ,  Prashant M. Bhatt ,  Osama Shekhah ,  Valeriya Chernikova

IPC: B01J20/22 ,  B01J20/02 ,  B01J20/28 ,  C07C7/13 ,  C10G25/00 ,  C10L1/06 ,  C10L1/08 ,  F02B1/14 ,  F02B5/02 ,  F02B47/04 ,  F02M25/12 ,  C01B3/40 ,  B01D53/02

Abstract: Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.

公开(公告)号：US11285426B2

公开(公告)日：2022-03-29

申请号：US16500548

申请日：2018-04-05

Applicant: King Abdullah University of Science and Technology

Inventor： Amandine Cadiau ,  Karim Adil ,  Youssef Belmabkhout ,  Prashant M. Bhatt ,  Mohamed Eddaoudi

IPC: B01D53/02 ,  B01D53/04 ,  B01J20/22 ,  B01J20/34

Abstract: Embodiments of the present disclosure describe a method of capturing chemical species from a fluid composition comprising providing a metal-organic framework characterized by the formula MaMbF5(O/H2O)(pyrazine)2.x(solv), wherein Ma is Ni2+; Mb is Nb5+, Al3+, or Fe3+; x is from 0 to 10 and solv is one or more of H2O, CO2, DMF, EtOH, NMP, MeOH; contacting the metal-organic framework with a fluid composition including H2O, CO2, and one or more other chemical species; and capturing H2O and CO2 simultaneously from the fluid composition.

公开(公告)号：US10857500B2

公开(公告)日：2020-12-08

申请号：US16431860

申请日：2019-06-05

Applicant: King Abdullah University of Science and Technology ,  SAUDI ARABIAN OIL COMPANY

Inventor： Mohamed Eddaoudi ,  Amandine Cadiau ,  Prashant M. Bhatt ,  Karim Adil ,  Youssef Belmabkhout

IPC: B01D53/52 ,  B01D53/02 ,  B01D53/04 ,  B01D53/80 ,  B01D53/81 ,  B01D53/96 ,  B01J20/02 ,  B01J20/22 ,  B01J20/34 ,  B01J31/16 ,  C07F15/02 ,  C07F15/04 ,  C07F5/06 ,  C07F9/00 ,  B01J20/28

Abstract: Provided herein are metal organic frameworks comprising metal nodes and N-donor organic ligands which have high selectivity and stability in the present of gases and vapors including H2S, H2O, and CO2. Methods include capturing one or more of H2S, H2O, and CO2 from fluid compositions, such as natural gas.