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公开(公告)号:US09663627B2
公开(公告)日:2017-05-30
申请号:US14549108
申请日:2014-11-20
Inventor: Mohamed Eddaoudi , Vincent Guillerm , Lukasz Weselinski , Mohamed H. Alkordi , Mohamed Infas Haja Mohideen , Youssef Belmabkhout
IPC: C08J9/36
CPC classification number: C08J9/36 , B01D53/02 , B01D2253/202 , B01D2253/204 , B01D2256/10 , B01D2256/12 , B01D2256/16 , B01D2256/24 , B01D2256/245 , B01D2257/504 , B01J20/226 , B01J20/28057 , B01J20/28069 , B01J20/3085 , B01J20/3206 , B01J20/3257 , C08J2201/036 , C10L3/104 , Y02C10/08 , Y02P20/152
Abstract: Amine groups can be introduced in porous materials by a direct (one pot) or post-synthetic modification (PSM) process on aldehyde groups, and the resulting porous materials have increased gas affinity.
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公开(公告)号:US11229872B2
公开(公告)日:2022-01-25
申请号:US16903820
申请日:2020-06-17
Inventor: Mohamed Infas Haja Mohideen , Karim Adil , Youssef Belmabkhout , Mohamed Eddaoudi , Prashant M. Bhatt
Abstract: Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.
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公开(公告)号:US10759724B2
公开(公告)日:2020-09-01
申请号:US15952511
申请日:2018-04-13
Inventor: Mohamed Eddaoudi , Youssef Belmabkhout , Mohamed Infas Haja Mohideen , Karim Adil , Prashant M. Bhatt , Osama Shekhah , Valeriya Chernikova
Abstract: Embodiments of the present disclosure describe a zeolite-like metal-organic framework composition comprising a metal-organic framework composition with ana topology characterized by the formula [MIII(4, 5-imidazole dicarboxylic acid)2X(solvent)a]n wherein MIII comprises a trivalent cation of a rare earth element, X comprises an alkali metal element or alkaline earth metal element, and solvent comprises a guest molecule occupying pores. Embodiments of the present disclosure describe a method of separating paraffins comprising contacting a zeolite-like metal-organic framework with ana topology with a flow of paraffins, and separating the paraffins by size.
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公开(公告)号:US11491459B2
公开(公告)日:2022-11-08
申请号:US17008419
申请日:2020-08-31
Inventor: Mohamed Eddaoudi , Youssef Belmabkhout , Mohamed Infas Haja Mohideen , Karim Adil , Prashant M. Bhatt , Osama Shekhah , Valeriya Chernikova
IPC: B01J20/22 , B01J20/02 , B01J20/28 , C07C7/13 , C10G25/00 , C10L1/06 , C10L1/08 , F02B1/14 , F02B5/02 , F02B47/04 , F02M25/12 , C01B3/40 , B01D53/02
Abstract: Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.
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公开(公告)号:US10717036B2
公开(公告)日:2020-07-21
申请号:US15770808
申请日:2016-10-26
Inventor: Mohamed Infas Haja Mohideen , Karim Adil , Youssef Belmabkhout , Mohamed Eddaoudi , Prashant M. Bhatt
Abstract: Embodiments include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments further include a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.
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