公开(公告)号：US07468093B2

公开(公告)日：2008-12-23

申请号：US11059641

申请日：2005-02-17

申请人： Kiyoshi Aoki ,  Takeshi Matsuda ,  Kazuhiro Ishikawa

发明人： Kiyoshi Aoki ,  Takeshi Matsuda ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22 ,  B01D71/02

CPC分类号： C22C27/02 ,  B01D67/0039 ,  B01D67/0074 ,  B01D71/022 ,  B01D2323/12 ,  B01D2325/20 ,  C01B3/503 ,  C01B3/505 ,  C22C14/00 ,  H01M8/0687 ,  Y02P70/56 ,  Y10S55/05

摘要： An Ni—Ti—Nb based multiple phase alloy consists of a combined phase which comprises a phase for the hydrogen permeability and a phase for the resistance to hydrogen embrittlement. The alloy has a composition satisfying the formula: NixTiyNb(100-x-y) in which x=25˜45 mol % and y=25˜55 mol %. A metal membrane for hydrogen separation-purification is prepared using the alloy material. The alloy material is prepared by blending Ni, Ti and Nb and melting the blend. The metal membrane permits the hydrogen separation-purification and thus the resulting purified hydrogen gas can be used as a fuel and can be applied to fields of production of semiconductors.

摘要翻译： Ni-Ti-Nb基多相合金由包含氢渗透相的相组合相和耐氢脆性相组成。 该合金具有满足下式的组成：NixTiyNb（100-x-y），其中x = 25〜45摩尔％，y = 25〜55摩尔％。 使用合金材料制备用于氢分离纯化的金属膜。 通过混合Ni，Ti和Nb并熔融共混物制备合金材料。 金属膜允许氢气分离纯化，因此所得到的纯化氢气可以用作燃料，并且可以应用于半导体生产领域。

公开(公告)号：US20050217480A1

公开(公告)日：2005-10-06

申请号：US11059641

申请日：2005-02-17

申请人： Kiyoshi Aoki ,  Takeshi Matsuda ,  Kazuhiro Ishikawa

发明人： Kiyoshi Aoki ,  Takeshi Matsuda ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22 ,  B01D67/00 ,  B01D71/02 ,  C01B3/50 ,  C22C14/00 ,  C22C27/02 ,  C22C30/00 ,  H01M8/06

CPC分类号： C22C27/02 ,  B01D67/0039 ,  B01D67/0074 ,  B01D71/022 ,  B01D2323/12 ,  B01D2325/20 ,  C01B3/503 ,  C01B3/505 ,  C22C14/00 ,  H01M8/0687 ,  Y02P70/56 ,  Y10S55/05

摘要： An Ni—Ti—Nb based multiple phase alloy consists of a combined phase which comprises a phase for the hydrogen permeability and a phase for the resistance to hydrogen embrittlement. The alloy has a composition satisfying the formula: NixTiyNb(100-x-y) in which x=25˜45 mol % and y=25˜55 mol %. A metal membrane for hydrogen separation-purification is prepared using the alloy material. The alloy material is prepared by blending Ni, Ti and Nb and melting the blend. The metal membrane permits the hydrogen separation-purification and thus the resulting purified hydrogen gas can be used as a fuel and can be applied to fields of production of semiconductors.

摘要翻译： Ni-Ti-Nb基多相合金由包含氢渗透相和氢脆性相的组合相组成。 该合金具有满足下式的组成：其中x = 25〜45摩尔％的Ni×（Ti-x）Nb（100-xy） y = 25〜55mol％。 使用合金材料制备用于氢分离纯化的金属膜。 通过混合Ni，Ti和Nb并熔融共混物制备合金材料。 金属膜允许氢气分离纯化，因此所得到的纯化氢气可以用作燃料，并且可以应用于半导体生产领域。

公开(公告)号：US07597842B2

公开(公告)日：2009-10-06

申请号：US11390186

申请日：2006-03-28

申请人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

发明人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

IPC分类号： C22C27/02

CPC分类号： H01M8/0687 ,  B01D53/228 ,  B01D67/0039 ,  B01D67/0074 ,  B01D71/022 ,  B01D2256/16 ,  B01D2323/12 ,  B32B15/018 ,  C01B3/503 ,  C22C14/00 ,  C22C27/02 ,  C22C30/00 ,  Y10S420/90

摘要： An Nb—Ti—Co alloy having both good hydrogen permeability and good hydrogen embrittlement resistance comprises one of Fe, Cu or Mn as a fourth element, incorporating from 1 to 14 mol %. The content of Mn, if any, is preferably from 1 to 9 mol %. The desired hydrogen permeability can be attained by the (Nb, Ti) phase and the desired hydrogen embrittlement resistance can be attained by the CoTi phase, making is possible to obtain excellent hydrogen permeability and excellent hydrogen embrittlement resistance. None of Fe, Cu or Mn can impair these properties. Fe, Cu or Mn can replace some of the Co elements. Fe, Cu or Mn enhances the workability of the alloy.

摘要翻译： 具有良好的氢渗透性和良好的耐氢脆性的Nb-Ti-Co合金包含Fe，Cu或Mn中的一种作为第四元素，其含有1至14摩尔％。 如果有的话，Mn的含量优选为1〜9摩尔％。 通过（Nb，Ti）相可以获得所需的氢渗透性，并且可以通过CoTi相获得所需的耐氢脆性，使得可以获得优异的氢渗透性和优异的耐氢脆性。 Fe，Cu或Mn都不会损害这些性能。 Fe，Cu或Mn可以代替一些Co元素。 Fe，Cu或Mn可提高合金的加工性能。

公开(公告)号：US07514036B2

公开(公告)日：2009-04-07

申请号：US11390218

申请日：2006-03-28

申请人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

发明人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

IPC分类号： C22C27/02 ,  C22C30/00 ,  C22F1/18

CPC分类号： C22C30/00 ,  C22C14/00 ,  C22C19/07 ,  C22C27/02 ,  C22F1/10 ,  C22F1/18 ,  H01M4/383 ,  H01M8/04208 ,  H01M8/065 ,  Y10S420/90

摘要： A (Nb, Ti) phase in an Nb—Ti—Co alloy is composed of a granular structure. The Nb—Ti—Co alloy is preferably subjected to heat treatment at 800° C. or more so that the eutectic structure in the casted state can be changed to a granular structure. The Nb—Ti—Co alloy used there is preferably NbxTi(100-x-y)Coy, (x≦70, 20≦y≦50 (mol %)). By properly predetermining the heating temperature and time, the resulting alloy exhibits improved hydrogen permeability in combination with a good hydrogen embrittlement resistance characteristic in the CoTi phase, making it possible to provide a practical hydrogen permeable membrane having an advantageously high performance.

摘要翻译： Nb-Ti-Co合金中的（Nb，Ti）相由粒状结构构成。 Nb-Ti-Co合金优选在800℃以上进行热处理，使得铸态的共晶组织可以变为粒状结构。 其中使用的Nb-Ti-Co合金优选为Nb x Ti（100-x-y）Co y，（x <= 70，20 <= y <= 50（mol％））。 通过适当地预先确定加热温度和时间，所得合金在CoTi相中具有良好的耐氢脆性特性，显示出改善的氢渗透性，使得可以提供具有有利的高性能的实用的氢可渗透膜。

公开(公告)号：US07390348B2

公开(公告)日：2008-06-24

申请号：US11526829

申请日：2006-09-26

申请人： Tsuyoshi Sasaki ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

发明人： Tsuyoshi Sasaki ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22 ,  B01D71/02

CPC分类号： C01B3/503 ,  B01D53/228 ,  B01D67/0072 ,  B01D69/141 ,  B01D71/022 ,  B01D2325/021 ,  B01D2325/20 ,  C22C30/00 ,  Y10S55/05

摘要： In a multiphase hydrogen permeation alloy comprising a phase in charge of hydrogen permeation and a phase in charge of hydrogen embrittlement resistance, a structure in which the phase in charge of hydrogen permeability is continuously interconnected and in which more preferably the growth direction of the aforementioned phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane. As the hydrogen permeation alloy, an Nb—Ti—Co alloy is exemplified, wherein the phase in charge of hydrogen permeability is made of an (Nb, Ti) phase and the aforementioned phase in charge of hydrogen embrittlement resistance is made of a CoTi phase. By virtue of the fact that the growth direction of the phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane, the hydrogen permeation pass length becomes short to give further improved hydrogen permeation property.

摘要翻译： 在包含氢渗透相和负载耐氢脆性相的多相氢气渗透合金中，氢渗透性的相位相互连接并且更优选上述相的生长方向的结构 负责氢渗透的部分在渗透膜的厚度方向上排列。 作为氢渗透合金，可以举出Nb（Ti，Ti）相的合金，其中，氢渗透性的相是由（Nb，Ti）相构成的，上述的耐氢脆性相是由CoTi相 。 由于氢渗透相的生长方向在渗透膜的厚度方向上排列的事实，氢渗透通过长度变短，能够进一步提高氢渗透性。

公开(公告)号：US08075670B2

公开(公告)日：2011-12-13

申请号：US12408750

申请日：2009-03-23

申请人： Tsuyoshi Sasaki ,  Tomohiro Ueno ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

发明人： Tsuyoshi Sasaki ,  Tomohiro Ueno ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22

CPC分类号： B01D53/22 ,  B01D53/228 ,  B01D63/087 ,  B01D2256/16 ,  B01D2313/146 ,  C01B3/503 ,  C01B3/505

摘要： A hydrogen permeable module includes a hydrogen permeable membrane that permeates hydrogen, an outer peripheral part of the hydrogen permeable membrane being restricted, an inside of the outer peripheral part of the hydrogen permeable membrane being not restricted. The hydrogen permeable module permeates the hydrogen by constantly keeping a pressure of a primary side to a pressure that is equal to or more than a pressure of a secondary side. The inside of the outer peripheral part of the hydrogen permeable membrane is not restricted so as to be capable of expanding to the secondary side.

摘要翻译： 氢可渗透组件包括渗透氢的透氢膜，氢可渗透膜的外周部分被限制，氢可渗透膜的外周部分的内部不受限制。 氢可渗透模块通过将初级侧的压力恒定地保持在等于或大于次级侧的压力的压力来渗透氢。 氢可渗透膜的外周部分的内部不受限制，从而能够扩展到次级侧。

公开(公告)号：US20090056549A1

公开(公告)日：2009-03-05

申请号：US12281663

申请日：2007-03-08

申请人： Koichi Kita ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

发明人： Koichi Kita ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22

CPC分类号： C01B3/503 ,  B01D53/228 ,  B01D67/0039 ,  B01D67/0069 ,  B01D67/0074 ,  B01D67/0083 ,  B01D71/022 ,  B01D2323/12 ,  B01D2325/04 ,  B01D2325/24 ,  C01B2203/041 ,  H01M8/0687 ,  Y10S55/05

摘要： A hydrogen permeation/separation thin membrane including an Ni—Ti—Nb alloy, the Ni—Ti—Nb alloy being a cast foil material obtained by roll quenching and having a thickness of 0.07 mm or less, which has been subjected to a refining heat treatment, and the Ni—Ti—Nb alloy having the following composition (a) and alloy structure (b): (a) a composition consisting of 10 to 47 atomic % of Nb, 20 to 52 atomic % of Ti, and a remainder containing 20 to 48 atomic % of Ni and inevitable impurities; and (b) an alloy structure where fine particles of an Nb-based solid solution alloy formed of a solid solution of Ni and Ti in Nb are dispersed in a microstructure made of an Ni—Ti(Nb) intermetallic compound formed of a solid solution of an Ni—Ti intermetallic compound, in which part of Ti thereof is replaced by Nb; and a hydrogen permeation/separation thin membrane including an Nb—Ti—Ni alloy, the Nb—Ti—Ni alloy being a cast foil material obtained by roll quenching and having a thickness of 0.07 mm or less, which has been subjected to a refining heat treatment, and the Nb—Ti—Ni alloy having the following composition (a′) and alloy structure (b′): (a′) a composition consisting of 10 to 32 atomic % of Ni, 15 to 33 atomic % of Ti, and a remainder containing 48 to 70 atomic % of Nb and inevitable impurities; and (b′) an alloy structure where fine particles of an Ni—Ti(Nb) intermetallic compound formed of a solid solution of an Ni—Ti intermetallic compound, in which part of Ti thereof is replaced by Nb, are dispersed in a microstructure made of an Nb-based solid solution alloy formed of a solid solution of Ni and Ti in Nb.

摘要翻译： 包含Ni-Ti-Nb合金的氢渗透/分离薄膜，Ni-Ti-Nb合金是通过辊淬火获得并具有0.07mm或更小的厚度的铸箔材料，其经受精炼热 处理以及具有以下组成（a）和合金结构（b）的Ni-Ti-Nb合金：（a）由10〜47原子％的Nb，20〜52原子％的Ti组成的组成，其余 含有20〜48原子％的Ni和不可避免的杂质; 和（b）由在Nb中由Ni和Ti的固溶体形成的Nb系固溶体的微细粒子分散在由固溶体形成的Ni-Ti（Nb）金属间化合物构成的显微组织中的合金结构 的Ni-Ti金属间化合物，其中Ti的一部分被Nb代替; 以及包含Nb-Ti-Ni合金的氢渗透/分离薄膜，Nb-Ti-Ni合金是通过辊淬火获得并具有0.07mm以下厚度的铸造箔材料，其经过精炼 （a'）和合金结构（b'）的Nb-Ti-Ni合金：（a'）由10〜32原子％的Ni，15〜33原子％的Ti组成的组成 ，余量为48〜70原子％的Nb和不可避免的杂质; 和（b'）合金结构，其中由Ni-Ti金属间化合物的固溶体形成的Ni-Ti（Nb）金属间化合物的其中Ti的一部分被Nb替代的细小颗粒分散在微结构 由Nb中的Ni和Ti的固溶体形成的Nb基固溶体合金制成。

公开(公告)号：US20070048171A1

公开(公告)日：2007-03-01

申请号：US11390186

申请日：2006-03-28

申请人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

发明人： Kiyoshi Aoki ,  Kazuhiro Ishikawa ,  Tsuyoshi Sasaki ,  Toshiki Kabutomori

IPC分类号： H01M4/58 ,  C22C27/02

CPC分类号： H01M8/0687 ,  B01D53/228 ,  B01D67/0039 ,  B01D67/0074 ,  B01D71/022 ,  B01D2256/16 ,  B01D2323/12 ,  B32B15/018 ,  C01B3/503 ,  C22C14/00 ,  C22C27/02 ,  C22C30/00 ,  Y10S420/90

摘要： An Nb—Ti—Co alloy having both good hydrogen permeability and good hydrogen embrittlement resistance comprises one of Fe, Cu or Mn as a fourth element, incorporating from 1 to 14 mol %. The content of Mn, if any, is preferably from 1 to 9 mol %. The desired hydrogen permeability can be attained by the (Nb, Ti) phase and the desired hydrogen embrittlement resistance can be attained by the CoTi phase, making is possible to obtain excellent hydrogen permeability and excellent hydrogen embrittlement resistance. None of Fe, Cu or Mn can impair these properties. Fe, Cu or Mn can replace some of the Co elements. Fe, Cu or Mn enhances the workability of the alloy.

摘要翻译： 具有良好的氢渗透性和良好的耐氢脆性的Nb-Ti-Co合金包含Fe，Cu或Mn中的一种作为第四元素，其含有1至14摩尔％。 如果有的话，Mn的含量优选为1〜9摩尔％。 可以通过（Nb，Ti）相获得所需的氢渗透性，并且可以通过CoTi相获得所需的耐氢脆性，使得可以获得优异的氢渗透性和优异的耐氢脆性。 Fe，Cu或Mn都不会损害这些性能。 Fe，Cu或Mn可以代替一些Co元素。 Fe，Cu或Mn可提高合金的加工性能。

公开(公告)号：US08105424B2

公开(公告)日：2012-01-31

申请号：US12281663

申请日：2007-03-08

申请人： Koichi Kita ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

发明人： Koichi Kita ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22

CPC分类号： C01B3/503 ,  B01D53/228 ,  B01D67/0039 ,  B01D67/0069 ,  B01D67/0074 ,  B01D67/0083 ,  B01D71/022 ,  B01D2323/12 ,  B01D2325/04 ,  B01D2325/24 ,  C01B2203/041 ,  H01M8/0687 ,  Y10S55/05

摘要： A hydrogen permeation/separation thin membrane including a Ni—Ti—Nb alloy. The Ni—Ti—Nb alloy is a cast foil material obtained by roll quenching and a refining heat treatment. The membrane has a thickness of 0.07 mm or less. The Ni—Ti—Nb alloy has the following: (a) a composition consisting of 10 to 47 atomic % of Nb, 20 to 52 atomic % of Ti, and a remainder containing 20 to 48 atomic % of Ni and inevitable impurities; and (b) an alloy structure where fine particles of a Nb-based solid solution alloy, in which Nb forms a solid solution with Ni and Ti in Nb, are dispersed in a basic structure made of a Ni—Ti(Nb) intermetallic compound formed of a solid solution of a Ni—Ti intermetallic compound, in which part of Ti thereof is replaced by Nb.

摘要翻译： 包含Ni-Ti-Nb合金的氢透过/分离薄膜。 Ni-Ti-Nb合金是通过辊淬和精炼热处理得到的铸箔材料。 膜的厚度为0.07mm以下。 Ni-Ti-Nb合金具有以下成分：（a）Nb为10〜47原子％，Ti为20〜52原子％，余量为20〜48原子％的Ni和不可避免的杂质; 和（b）其中Nb与Nb中形成具有Ni和Ti的固溶体的Nb基固溶体合金的细颗粒分散在由Ni-Ti（Nb）金属间化合物制成的基本结构中的合金结构 由Ni-Ti金属间化合物的固溶体形成，其中Ti的一部分被Nb代替。

公开(公告)号：US20070068383A1

公开(公告)日：2007-03-29

申请号：US11526829

申请日：2006-09-26

申请人： Tsuyoshi Sasaki ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

发明人： Tsuyoshi Sasaki ,  Toshiki Kabutomori ,  Kiyoshi Aoki ,  Kazuhiro Ishikawa

IPC分类号： B01D53/22

CPC分类号： C01B3/503 ,  B01D53/228 ,  B01D67/0072 ,  B01D69/141 ,  B01D71/022 ,  B01D2325/021 ,  B01D2325/20 ,  C22C30/00 ,  Y10S55/05

摘要： In a multiphase hydrogen permeation alloy comprising a phase in charge of hydrogen permeation and a phase in charge of hydrogen embrittlement resistance, a structure in which the phase in charge of hydrogen permeability is continuously interconnected and in which more preferably the growth direction of the aforementioned phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane. As the hydrogen permeation alloy, an Nb—Ti—Co alloy is exemplified, wherein the phase in charge of hydrogen permeability is made of an (Nb, Ti) phase and the aforementioned phase in charge of hydrogen embrittlement resistance is made of a CoTi phase. By virtue of the fact that the growth direction of the phase in charge of hydrogen permeation lies aligned in the thickness direction of the permeation membrane, the hydrogen permeation pass length becomes short to give further improved hydrogen permeation property.

摘要翻译： 在包含氢渗透相和负载耐氢脆性相的多相氢气渗透合金中，氢渗透性的相位相互连接并且更优选上述相的生长方向的结构 负责氢渗透的部分在渗透膜的厚度方向上排列。 作为氢渗透合金，可以举出Nb（Ti，Ti）相的合金，其中，氢渗透性的相是由（Nb，Ti）相构成的，上述的耐氢脆性相是由CoTi相 。 由于氢渗透相的生长方向在渗透膜的厚度方向上排列的事实，氢渗透通过长度变短，能够进一步提高氢渗透性。