公开(公告)号：US20120225233A1

公开(公告)日：2012-09-06

申请号：US13376003

申请日：2010-06-02

申请人： Laurent Guy ,  Virginie Pevere ,  Thierry Vidal

发明人： Laurent Guy ,  Virginie Pevere ,  Thierry Vidal

IPC分类号： C08L9/00 ,  C08K9/12 ,  B32B1/08 ,  C08J3/20

CPC分类号： C08K5/5425 ,  C08K3/36 ,  C08K5/544 ,  C08L9/00 ,  Y10T428/139

摘要： The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C═C or C═N, and not including any C═C—C═O bonds or N═N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C═C—C═O or N═N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.

摘要翻译： 公开了在包含异戊二烯弹性体和增强无机填料的弹性体组合物中使用官能化的有机硅化合物作为无机填料和弹性体之间的偶联剂。 所述化合物选自包括至少一个C = C或C = N的双键的官能化有机硅化合物，并且不包括任何C = C-C = O键或N = N键，并且根据电环与异戊二烯单元反应 特别是根据标准环加成反应[2 + 1]，[2 + 2]，[3 + 2]或狄尔斯 - 阿尔德反应[4 + 2]或烯 - 合成以外的烯 - 异戊二烯单元与C = C-C = O或N = N的反应。 还描述了获得的弹性体组合物和使用这些组合物制造的物品。

公开(公告)号：US08980392B2

公开(公告)日：2015-03-17

申请号：US13376003

申请日：2010-06-02

申请人： Laurent Guy ,  Virginie Pevere ,  Thierry Vidal

发明人： Laurent Guy ,  Virginie Pevere ,  Thierry Vidal

IPC分类号： C08L9/00 ,  C08K9/12 ,  C08J3/20 ,  C08K3/36 ,  C08K5/5425 ,  C08K5/544

CPC分类号： C08K5/5425 ,  C08K3/36 ,  C08K5/544 ,  C08L9/00 ,  Y10T428/139

摘要： The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C═C or C═N, and not including any C═C—C═O bonds or N═N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C═C—C═O or N═N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.

摘要翻译： 公开了在包含异戊二烯弹性体和增强无机填料的弹性体组合物中使用官能化的有机硅化合物作为无机填料和弹性体之间的偶联剂。 所述化合物选自包括至少一个C = C或C = N的双键的官能化有机硅化合物，并且不包括任何C = C-C = O键或N = N键，并且根据电环与异戊二烯单元反应 特别是根据标准环加成反应[2 + 1]，[2 + 2]，[3 + 2]或狄尔斯 - 阿尔德反应[4 + 2]或烯 - 合成以外的烯 - 异戊二烯单元与C = C-C = O或N = N的反应。 还描述了获得的弹性体组合物和使用这些组合物制造的物品。

公开(公告)号：US20110282040A1

公开(公告)日：2011-11-17

申请号：US12935056

申请日：2009-04-03

申请人： Thierry Vidal ,  Virginie Pevere

发明人： Thierry Vidal ,  Virginie Pevere

IPC分类号： C07F7/18 ,  C07F7/20 ,  C07F7/10

CPC分类号： C07F7/1804

摘要： Functionalized organosilicon compounds (I), including at least one azo-activated structural unit, are prepared by: A. reacting at least one silane precursor (IV) with at least one hydrazo-precursor compound (V) to obtain hydrazine precursors (II) of such organosilicon compounds and B. oxidizing the hydrazine group of the precursors (II) to obtain precursors of the compounds (I), employing an oxidizer (NaOCl) and a base (NaOH), the oxidation being carried out in a biphase aqueous/organic medium, with the pH of the aqueous phase ranging from 3 to 11, such oxidation B being carried out directly in the reaction medium obtained from step A and containing the precursors (II), without isolating these precursors.

摘要翻译： 包括至少一种偶氮活化的结构单元的官能化有机硅化合物（I）通过以下步骤制备：A.使至少一种硅烷前体（Ⅳ）与至少一种氢化前体化合物（Ⅴ）反应，得到肼前体（II） 的这种有机硅化合物和B.氧化前体（II）的肼基以获得化合物（I）的前体，使用氧化剂（NaOCl）和碱（NaOH），氧化在双相水/ 有机介质，其水相pH为3至11，这样的氧化B直接在步骤A获得并含有前体（II）的反应介质中进行，而不分离这些前体。

公开(公告)号：US20100185005A1

公开(公告)日：2010-07-22

申请号：US12530005

申请日：2008-03-05

申请人： Thierry Vidal

发明人： Thierry Vidal

IPC分类号： C07F7/02

CPC分类号： C07F7/1876

摘要： Organomonoalkoxy/monohydroxy silanes, particularly halogenated or aklenylated organomonoalkoxy (or monohydroxy) silanes, which are useful intermediates in organic syntheses, are prepared by reacting an alkoxysilane with an organometallic compound suited for substituting at least certain of the alkoxy functions of the alkoxysilane with a monovalent hydrocarbon radical other than alkoxy and co-preparing a metallic alkoxylate by-product capable of denaturing the substituted silanes thus obtained, including contacting the metallic alkoxylate with at least one agent (A) reactive with the alkoxy functions of the alkoxylate to generate one or more species inert relative to the alkoxysilane, such agent (A) being selected from among the electrophile and/or mineral acid groups.

摘要翻译： 有机基烷氧基/单羟基硅烷，特别是有机合成中有用的中间体的卤代或亚烷基化的有机基烷氧基（或单羟基）硅烷，是通过使烷氧基硅烷与适合于用烷基硅烷取代至少某些烷氧基官能团的有机金属化合物与一价 共同制备能够使由此获得的取代硅烷变性的金属烷氧基化物副产物，包括使金属烷氧基化物与至少一种与烷氧基化物的烷氧基官能团反应的试剂（A）接触以产生一种或多种 相对于烷氧基硅烷惰性的物质，这种试剂（A）选自亲电子和/或无机酸基团。

公开(公告)号：US20070276149A1

公开(公告)日：2007-11-29

申请号：US10580787

申请日：2004-11-29

申请人： Thierry Vidal ,  Nicolas Roques ,  Laurent Saint-Jalmes

发明人： Thierry Vidal ,  Nicolas Roques ,  Laurent Saint-Jalmes

IPC分类号： C07F7/08 ,  C07F7/10

CPC分类号： C07F7/1896 ,  Y02P20/582

摘要： The invention relates to a method for preparing a fluorinated and silylated derivative having a bond between the bearing carbon of at least one fluorine and one silicon. This method comprises at least one step during which a derivative of formula (I) Rf-CO—O-D, in which D is selected among silylated radicals, is placed in the presence of a base. The inventive method is used for synthesizing fluorinated derivatives.

摘要翻译： 本发明涉及一种制备氟化和甲硅烷基化衍生物的方法，该衍生物具有至少一个氟和一个硅的承载碳之间的键。 该方法包括至少一个步骤，其中在碱的存在下将式（I）的衍生物Rf-CO-O-D（其中D选自甲硅烷基化的基团）。 本发明的方法用于合成氟化衍生物。

公开(公告)号：US09296683B2

公开(公告)日：2016-03-29

申请号：US13702453

申请日：2011-05-31

申请人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

发明人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

IPC分类号： C07C231/02

CPC分类号： C07C231/02 ,  C07C233/05

摘要： The present invention concerns a process for preparing esteramide compounds. More particularly, the invention relates to a process for preparing esteramide compounds by reaction between a diester and an amine, in the presence of a basic compound, wherein the basic compound and the amine in gaseous form are co-added to the diester, the reaction being conducted at a temperature of 30° C. or higher.

摘要翻译： 本发明涉及一种制备酯酰胺化合物的方法。 更具体地说，本发明涉及一种在碱性化合物存在下，通过二酯和胺之间的反应制备酯酰胺化合物的方法，其中碱性化合物和气态胺与二酯共反应，反应 在30℃以上的温度下进行。

公开(公告)号：US09284262B2

公开(公告)日：2016-03-15

申请号：US13702470

申请日：2011-06-09

申请人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

发明人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

IPC分类号： C07C231/02 ,  C07C231/14

CPC分类号： C07C231/14 ,  C07C231/02 ,  C07C233/05

摘要： The present invention relates to a method for preparing esteramide compounds. More particularly, the invention relates to a method for preparing esteramide compounds by reaction between a diester and an amine, in the presence of a basic compound, wherein the amine is solubilized in an organic solvent or in the diester, when the amine is solubilized in an organic solvent, the diester is added onto the reaction mixture comprising the amine and the basic compound, when the amine is solubilized in the diester, the basic compound is added onto the reaction mixture comprising the amine and the diester (II), the reaction is conducted at a temperature greater than or equal to 30° C., the amine is present in molar excess ranging from 0.01 to 50% relatively to the diester.

摘要翻译： 本发明涉及一种制备酯酰胺化合物的方法。 更具体地说，本发明涉及一种在碱性化合物存在下，通过二酯和胺之间的反应制备酯酰胺化合物的方法，其中胺溶解在有机溶剂或二酯中时，当胺溶解在 有机溶剂，当胺溶解在二酯中时，将二酯加入到包含胺和碱性化合物的反应混合物中，将碱性化合物加入到包含胺和二酯（II）的反应混合物中，反应 在大于或等于30℃的温度下进行，胺以相对于二酯的0.01至50％的摩尔过量存在。

公开(公告)号：US07645895B2

公开(公告)日：2010-01-12

申请号：US10580787

申请日：2004-11-29

申请人： Thierry Vidal ,  Nicolas Roques ,  Laurent Saint-Jalmes

发明人： Thierry Vidal ,  Nicolas Roques ,  Laurent Saint-Jalmes

IPC分类号： C07F7/04

CPC分类号： C07F7/1896 ,  Y02P20/582

摘要： The invention relates to a method for preparing a fluorinated and silylated derivative having a bond between the bearing carbon of at least one fluorine and one silicon. This method comprises at least one step during which a derivative of formula (I) Rf—CO—O-D, in which D is selected among silylated radicals, is placed in the presence of a base. The inventive method is used for synthesizing fluorinated derivatives.

摘要翻译： 本发明涉及一种制备氟化和甲硅烷基化衍生物的方法，该衍生物具有至少一个氟和一个硅的承载碳之间的键。 该方法包括至少一个步骤，其中在碱的存在下将式（I）的衍生物Rf-CO-O-D（其中D选自甲硅烷基化的基团）。 本发明的方法用于合成氟化衍生物。

公开(公告)号：US08981148B2

公开(公告)日：2015-03-17

申请号：US13635659

申请日：2011-03-17

申请人： Massimo Guglieri ,  Thierry Vidal

发明人： Massimo Guglieri ,  Thierry Vidal

IPC分类号： C07C233/02 ,  C07C231/02 ,  C07C235/74 ,  A01N25/02

CPC分类号： C07C233/02 ,  A01N25/02 ,  C07C231/02 ,  C07C235/74

摘要： An esteramide compound of the following formula (I): R1OOC-A-CONR2R3  (I) is described, wherein: A is a covalent bond or a methylene group —CH2—; R1 is an optionally substituted, saturated or unsaturated aliphatic or cycloaliphatic hydrocarbon group including from 5 to 36 carbon atoms, R2 and R3, either identical or different, are groups selected from a hydrogen atom, and optionally substituted hydrocarbon groups, preferably including from 1 to 36 carbon atoms, and R2 and R3 not being simultaneously hydrogen atoms. Also described, are applications for using the esteramide compound, notably as a solvent.

摘要翻译： 描述下式（I）的酯酰胺化合物：R1OOC-A-CONR2R3（I），其中：A是共价键或亚甲基-CH 2 - ; R1是任选取代的饱和或不饱和的脂族或脂环族烃基，包括5至36个碳原子，R 2和R 3相同或不同，为选自氢原子和任选取代的烃基，优选包括1至 36个碳原子，R2和R3不同时为氢原子。 还描述了用于使用酯酰胺化合物，特别是作为溶剂的应用。

公开(公告)号：US20130237722A1

公开(公告)日：2013-09-12

申请号：US13702470

申请日：2011-06-09

申请人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

发明人： Thierry Vidal ,  Rabih Rached ,  Massimo Guglieri

IPC分类号： C07C231/14

CPC分类号： C07C231/14 ,  C07C231/02 ,  C07C233/05

摘要： The present invention relates to a method for preparing esteramide compounds. More particularly, the invention relates to a method for preparing esteramide compounds by reaction between a diester and an amine, in the presence of a basic compound, wherein the amine is solubilized in an organic solvent or in the diester, when the amine is solubilized in an organic solvent, the diester is added onto the reaction mixture comprising the amine and the basic compound, when the amine is solubilized in the diester, the basic compound is added onto the reaction mixture comprising the amine and the diester (II), the reaction is conducted at a temperature greater than or equal to 30° C., the amine is present in molar excess ranging from 0.01 to 50% relatively to the diester.

摘要翻译： 本发明涉及一种制备酯酰胺化合物的方法。 更具体地说，本发明涉及一种在碱性化合物存在下，通过二酯和胺之间的反应制备酯酰胺化合物的方法，其中胺溶解在有机溶剂或二酯中时，当胺溶解在 有机溶剂，当胺溶解在二酯中时，将二酯加入到包含胺和碱性化合物的反应混合物中，将碱性化合物加入到包含胺和二酯（II）的反应混合物中，反应 在大于或等于30℃的温度下进行，胺以相对于二酯的0.01至50％的摩尔过量存在。