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    Olefin polymerization catalyst system
    1.
    发明授权
    Olefin polymerization catalyst system 失效
    烯烃聚合催化剂体系

    公开(公告)号：US06232255B1

    公开(公告)日：2001-05-15

    申请号：US09397375

    申请日：1999-09-16

    申请人： Linda N. Winslow ,  Garry L. Fields ,  Kenneth W. Johnson

    发明人： Linda N. Winslow ,  Garry L. Fields ,  Kenneth W. Johnson

    IPC分类号： B01J2100

    CPC分类号： C08F10/00 ,  B01J21/08 ,  B01J31/0274 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F110/02 ,  C08F210/16 ,  C08F4/6567 ,  C08F4/6426 ,  C08F4/6565 ,  C08F4/6583 ,  C08F4/6425 ,  C08F2500/12 ,  C08F210/14

    摘要： A catalyst system for the polymerization of olefins which includes a solid catalyst component and a cocatalyst. The solid catalyst component includes the contact product of silica, an alkyl magnesium-containing species, a compound having the structural formula E(YZ)mX4-m, where E is an atom of an element of Group 14 of the Periodic Table of the Elements; Y is an atom of an element of Group 16 of the Periodic Table of the Elements; Z is hydrogen, hydrocarbyl or mixtures thereof; X is hydrogen, halogen, hydrocarbyl or mixtures thereof; and m is an integer of 1 to 4 and a tetravalent titanium compound. The cocatalyst includes a mixture of at least two compounds having the structural formula AlRxX13-x, where R is the same or different and is hydrocarbyl; X1 is halogen; and x is an integer of 1 to 3 with the proviso that at least one of the compounds is defined by x being 3 and at least one of the compounds as defined by x being 1 or 2.

    摘要翻译： 用于烯烃聚合的催化剂体系，其包括固体催化剂组分和助催化剂。 固体催化剂组分包括二氧化硅，含烷基镁的物质，具有结构式E（YZ）m X4-m的化合物的接触产物，其中E是元素周期表第14族元素的原子 ; Y是元素周期表第16族元素的原子; Z是氢，烃基或其混合物; X是氢，卤素，烃基或其混合物; m为1〜4的整数，4价的钛化合物。 助催化剂包括具有结构式AlR x X 13-x的至少两种化合物的混合物，其中R相同或不同，并且是烃基; X1是卤素; x为1至3的整数，条件是至少一个化合物由x定义为3，x中定义的至少一种化合物为1或2。

    Vanadium-containing catalyst system
    2.
    发明授权
    Vanadium-containing catalyst system 失效
    含钒催化剂体系

    公开(公告)号：US5534472A

    公开(公告)日：1996-07-09

    申请号：US412633

    申请日：1995-03-29

    申请人： Linda N. Winslow ,  Douglas D. Klendworth ,  Raghu Menon ,  Michael W. Lynch ,  Garry L. Fields ,  Kenneth W. Johnson

    发明人： Linda N. Winslow ,  Douglas D. Klendworth ,  Raghu Menon ,  Michael W. Lynch ,  Garry L. Fields ,  Kenneth W. Johnson

    IPC分类号： B01J31/12 ,  B01J31/14 ,  B01J31/16 ,  B01J31/22 ,  C08F10/00 ,  C08F210/16

    CPC分类号： B01J31/2226 ,  B01J31/128 ,  B01J31/143 ,  B01J31/1616 ,  C08F10/00 ,  B01J2531/56 ,  C08F210/16

    摘要： A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica, with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group III metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. The product of the step of contacting with compounds (1) and (2) is contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.

    摘要翻译： 一种特别适用于可吹塑烯烃聚合物聚合的含钒催化剂体系。 催化剂体系包括通过使预热的二氧化硅与（1）包含至少一个碳 - 镁共价键的化合物或络合物接触而制备的负载的第一催化剂组分和（2）包含至少一个碳至III族金属的化合物 共价键。 二氧化硅与化合物或络合物（1）和化合物（2）的接触顺序是任选的。 然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。 与化合物（1）和（2）接触的步骤的产物与包含至少一个卤素原子的钒化合物接触。 最后，将钒化合物接触步骤的产物与醇接触。 催化剂体系的第二个组分是有机铝化合物助催化剂。 催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。

    Vanadium-containing catalyst system
    9.
    发明授权
    Vanadium-containing catalyst system 失效
    含钒催化剂体系

    公开(公告)号：US5670439A

    公开(公告)日：1997-09-23

    申请号：US583371

    申请日：1996-01-05

    申请人： Linda N. Winslow ,  Raghu K. Menon

    发明人： Linda N. Winslow ,  Raghu K. Menon

    IPC分类号： B01J31/12 ,  B01J31/14 ,  B01J31/16 ,  B01J31/22 ,  C08F4/68 ,  C08F10/00 ,  C08F210/16 ,  B01J31/00 ,  B01J37/00 ,  C08F9/02 ,  C08F9/60

    CPC分类号： B01J31/2226 ,  B01J31/128 ,  B01J31/143 ,  B01J31/1616 ,  C08F10/00 ,  B01J2531/56 ,  C08F210/16

    摘要： A vanadium-containing catalyst system particularly suited to the polymerization of olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting silica with hexaalkyldisilazane and thereupon with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group 13 metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. The product of the step of contacting with compounds (1) and (2) is washed and then contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.

    摘要翻译： 一种特别适用于烯烃聚合物聚合的含钒催化剂体系。 催化剂体系包括通过使二氧化硅与六烷基二硅氮烷接触而制备的负载的第一催化剂组分，随后与（1）包含至少一个碳 - 镁共价键的化合物或络合物和（2）包含至少一个碳 - 13金属共价键。 二氧化硅与化合物或络合物（1）和化合物（2）的接触顺序是任选的。 然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。 将与化合物（1）和（2）接触的步骤的产物洗涤，然后与包含至少一个卤素原子的钒化合物接触。 最后，将钒化合物接触步骤的产物与醇接触。 催化剂体系的第二个组分是有机铝化合物助催化剂。 催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。