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公开(公告)号：US08153544B2
公开(公告)日：2012-04-10
申请号：US12460640
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
CPC分类号： C08F10/00 , C08F4/64144 , C08F4/64151 , C08F4/64158 , C08F4/64155 , C08F4/64148
摘要： A method of preparing supported catalysts useful for olefin polymerization is described. The catalysts comprise a Group 4 metal complex that incorporates a tridentate dianionic ligand. An activator mixture is first made from a boron compound having Lewis acidity and an excess of an alumoxane. The activator mixture is then combined with a support and the Group 4 metal complex to give a supported catalyst. The method provides an active, supported catalyst capable of making high-molecular-weight polyolefins.
摘要翻译： 描述了制备用于烯烃聚合的负载型催化剂的方法。 催化剂包含掺入三齿二离子配体的第4族金属络合物。 活化剂混合物首先由具有路易斯酸度和过量的铝氧烷的硼化合物制成。 然后将活化剂混合物与载体和第4族金属络合物结合，得到负载型催化剂。 该方法提供了能够制备高分子量聚烯烃的活性的负载型催化剂。
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公开(公告)号：US20110213107A1
公开(公告)日：2011-09-01
申请号：US12660555
申请日：2010-03-01
CPC分类号： C08F10/02 , C08F4/63912 , C08F4/6392 , C08F110/02 , C08F210/16 , C08F2420/01 , C08F4/63916 , C08F4/63908 , C08F2500/04 , C08F210/08 , C08F2500/03 , C08F2500/07
摘要： A method for preparing a supported catalyst suitable for use in slurry and gas-phase olefin polymerizations is disclosed. An alumoxane-treated silica is combined with a monocyclopentadienyl Group 6 metal complex that comprises a chelating Cp moiety to give the supported catalyst. The method is simple to practice and provides catalysts having high activity. Polyolefins made using the catalysts have high molecular weight that is readily controlled by adding hydrogen.
摘要翻译： 公开了一种制备适用于淤浆和气相烯烃聚合反应的负载型催化剂的方法。 将铝氧烷处理的二氧化硅与包含螯合Cp部分的单环戊二烯基6金属络合物组合以得到负载型催化剂。 该方法操作简单，提供具有高活性的催化剂。 使用该催化剂制备的聚烯烃具有通过加入氢容易控制的高分子量。
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公开(公告)号：US20110021344A1
公开(公告)日：2011-01-27
申请号：US12460640
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Karen L. Neal-Hawkins
IPC分类号： B01J31/22
CPC分类号： C08F10/00 , C08F4/64144 , C08F4/64151 , C08F4/64158 , C08F4/64155 , C08F4/64148
摘要： A method of preparing supported catalysts useful for olefin polymerization is described. The catalysts comprise a Group 4 metal complex that incorporates a tridentate dianionic ligand. An activator mixture is first made from a boron compound having Lewis acidity and an excess of an alumoxane. The activator mixture is then combined with a support and the Group 4 metal complex to give a supported catalyst. The method provides an active, supported catalyst capable of making high-molecular-weight polyolefins.
摘要翻译： 描述了制备用于烯烃聚合的负载型催化剂的方法。 催化剂包含掺入三齿二离子配体的第4族金属络合物。 活化剂混合物首先由具有路易斯酸度和过量的铝氧烷的硼化合物制成。 然后将活化剂混合物与载体和第4族金属络合物结合，得到负载型催化剂。 该方法提供了能够制备高分子量聚烯烃的活性的负载型催化剂。
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4.发明授权Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands 失效基于2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的催化剂公开(公告)号：US08158733B2
公开(公告)日：2012-04-17
申请号：US12460628
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , C08F210/08 , C08F4/64155 , C08F4/64158 , C08F4/64151
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二偶氮三齿2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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公开(公告)号：US20120016092A1
公开(公告)日：2012-01-19
申请号：US12804122
申请日：2010-07-14
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir V. Bagrov
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Vladimir V. Bagrov
CPC分类号： C08F10/00 , C07F7/00 , C08F4/659 , C08F110/02 , C08F2500/10 , C08F2500/04 , C08F2500/17 , C08F2500/20 , C08F4/64148 , C08F4/64113 , C08F4/64134
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise a transition metal complex, an optional activator, and an optional support. The complex is the reaction product of a Group 3-6 transition metal source, an optional alkylating agent, and a ligand precursor comprising a 2-imino-8-anilinoquinoline or a 2-aminoalkyl-8-anilinoquinoline. The catalysts, which are easy to synthesize by in-situ metallation of the ligand precursor, offer polyolefin manufacturers good activity and the ability to make high-molecular-weight ethylene copolymers that have little or no long-chain branching.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包括过渡金属络合物，任选的活化剂和任选的载体。 络合物是3-6族过渡金属源，任选的烷基化剂和包含2-亚氨基-8-苯胺基喹啉或2-氨基烷基-8-苯胺基喹啉的配体前体的反应产物。 易于通过配体前体的原位金属化合成的催化剂为聚烯烃制造商提供了良好的活性和制备具有很少或不具有长链支化的高分子量乙烯共聚物的能力。
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公开(公告)号：US07858718B1
公开(公告)日：2010-12-28
申请号：US12460621
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko , Michael W. Lynch
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , Y10S526/901 , Y10S526/941 , C08F2/06 , C08F210/08 , C08F2500/17 , C08F210/14 , C08F4/64144
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-aryl-8-anilinoquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二阴离子，三齿2-芳基-8-苯胺基喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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7.发明申请Catalysts based on 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligands 失效基于2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的催化剂公开(公告)号：US20110021727A1
公开(公告)日：2011-01-27
申请号：US12460628
申请日：2009-07-22
申请人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
发明人： Sandor Nagy , Linda N. Winslow , Shahram Mihan , Reynald Chevalier , Lenka Lukesova , Ilya E. Nifant'ev , Pavel V. Ivchenko
CPC分类号： C07F7/00 , C08F10/00 , C08F210/16 , C08F210/08 , C08F4/64155 , C08F4/64158 , C08F4/64151
摘要： Catalysts useful for polymerizing olefins are disclosed. The catalysts comprise an activator and a Group 4 metal complex that incorporates a dianionic, tridentate 2-(2-aryloxy)quinoline or 2-(2-aryloxy)dihydroquinoline ligand. In one aspect, supported catalysts are prepared by first combining a boron compound having Lewis acidity with excess alumoxane to produce an activator mixture, followed by combining the activator mixture with a support and the tridentate, dianionic Group 4 metal complex. The catalysts are easy to synthesize, support, and activate, and they enable facile production of high-molecular-weight polyolefins.
摘要翻译： 公开了可用于聚合烯烃的催化剂。 催化剂包含活化剂和含有二偶氮三齿2-（2-芳氧基）喹啉或2-（2-芳氧基）二氢喹啉配体的第4族金属络合物。 在一个方面，通过首先将具有路易斯酸性的硼化合物与过量的铝氧烷组合以产生活化剂混合物，然后将活化剂混合物与载体和三齿的二阴离子第4族金属络合物组合来制备负载型催化剂。 催化剂易于合成，支持和活化，并且能够容易地生产高分子量聚烯烃。
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公开(公告)号：US06908972B2
公开(公告)日：2005-06-21
申请号：US10123774
申请日：2002-04-16
申请人： Barbara M. Tsuie , Karen L. Neal-Hawkins , Sandor Nagy , Michael W. Lynch , Mark P. Mack , Shaotian Wang , Jean A Merrick-Mack , Clifford C. Lee , Joel A. Mutchler , Kenneth W. Johnson
发明人： Barbara M. Tsuie , Karen L. Neal-Hawkins , Sandor Nagy , Michael W. Lynch , Mark P. Mack , Shaotian Wang , Jean A Merrick-Mack , Clifford C. Lee , Joel A. Mutchler , Kenneth W. Johnson
IPC分类号： C08F4/642 , C08F4/659 , C08F110/02 , C08F210/02 , C08F210/16 , C08F4/52
CPC分类号： C08F210/02 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/09 , C08F210/08 , C08F2500/12 , C08F2500/08 , C08F210/14
摘要： A method for making ethylene polymers and copolymers is disclosed. The method uses a catalyst system comprising a low level of an aluminum-containing activator, a bridged indenoindolyl transition metal complex, and a treated silica support. The method enables economical preparation of ethylene copolymers having very low density. The silica-supported, bridged complexes incorporate comonomers efficiently and are valuable for a commercial slurry loop process. Use of a bridged indeno[2,1-b]indolyl complex provides exceptionally efficient comonomer incorporation, and gives polymers with a substantial and controlled level of long-chain branching. The method facilitates the production of a wide variety of polyolefins, from HDPE to plastomers.
摘要翻译： 公开了制备乙烯聚合物和共聚物的方法。 该方法使用包含低含量的含铝活化剂，桥连茚并吲哚基过渡金属络合物和经处理的二氧化硅载体的催化剂体系。 该方法能够经济地制备具有非常低密度的乙烯共聚物。 二氧化硅负载的桥接配合物有效地引入共聚单体，并且对于商业淤浆循环方法是有价值的。 桥联茚并[2,1-b]吲哚基复合物的使用提供了非常有效的共聚单体掺入，并且得到具有实质和受控水平的长链支化的聚合物。 该方法有助于生产从HDPE到塑性体的各种各样的聚烯烃。
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9.发明授权公开(公告)号：US06544918B1
公开(公告)日：2003-04-08
申请号：US09907180
申请日：2001-07-17
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/659
摘要： A catalyst system useful for polymerizing olefins is disclosed. The catalyst system comprises an activator and a complex that incorporates a Group 3 to 10 transition metal and at least one chelating dianionic bis(allyl) or bis(benzyl) ligand. The ligands are often easy to make, and they are readily incorporated into transition metal complexes. By modifying the structure of the dianionic ligand, polyolefin makers can control comonomer incorporation, catalyst activity, and polymer properties.
摘要翻译： 公开了一种可用于烯烃聚合的催化剂体系。 该催化剂体系包括活化剂和掺入第3至10族过渡金属和至少一种螯合的二 - 阴离子双（烯丙基）或双（苄基）配体的络合物。 配体通常易于制备，并且它们容易并入过渡金属络合物中。 通过改变二阴离子配体的结构，聚烯烃制造商可以控制共聚单体掺入，催化剂活性和聚合物性质。
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10.发明授权公开(公告)号：US06933354B2
公开(公告)日：2005-08-23
申请号：US10806503
申请日：2004-03-23
IPC分类号： C08F4/606 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08F4/52 , C08F4/54
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F210/16 , C08F4/65925 , C08F210/08 , C08F2500/12 , C08F2500/02
摘要： Single-site catalyst systems useful for polymerizing olefins are disclosed. The catalyst systems comprise an organometallic complex and an activator. The complex includes a Group 3-10 transition metal, M, and at least one indenoindolyl ligand that is pi-bonded to M. The activator is a reaction product of an alkylaluminum compound and an organoboronic acid. Catalyst systems of the invention significantly outperform known catalyst systems that employ a metallocene complex and similar aluminoboronate activators.
摘要翻译： 公开了可用于聚合烯烃的单中心催化剂体系。 催化剂体系包括有机金属络合物和活化剂。 络合物包括3-10过渡金属M和至少一个与M键合的茚并吲哚基配体。活化剂是烷基铝化合物和有机硼酸的反应产物。 本发明的催化剂体系显着优于使用茂金属络合物和类似的铝硼酸盐活化剂的已知催化剂体系。
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