公开(公告)号：US20160130404A1

公开(公告)日：2016-05-12

申请号：US14890189

申请日：2014-05-09

Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.

Inventor： Mihirkumar Maheshbai PATEL ,  Anantharaman DHANABALAN ,  Sumi DINKAR ,  Alok SARKAR

IPC: C08G77/44

CPC classification number: C08G77/44 ,  C08G77/08 ,  C08K5/5419 ,  C08K5/544 ,  C08L43/04 ,  C08L101/10 ,  C08L83/04

Abstract: The present invention provides curable compositions that are free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst comprising curable polymers having reactive terminal silyl groups. In particular, a silylated carboxylic acid is an alternative to organotin or other metal catalysts. In addition, the catalyst may be used with an amino-containing adhesion promoter or a mixture of amine-containing adhesion promoters and an amino-containing siloxane. The combination of these materials accelerates the condensation curing of moisture curable silicones/non-silicones even in the absence of a metal-based catalyst.

Abstract translation: 本发明提供了不含金属催化剂，包括锡和非锡金属催化剂的可固化组合物。 可固化组合物使用包含具有反应性末端甲硅烷基的可固化聚合物的催化剂。 特别地，甲硅烷基化的羧酸是有机锡或其它金属催化剂的替代物。 此外，催化剂可以与含氨基的粘合促进剂或含胺粘合促进剂和含氨基的硅氧烷的混合物一起使用。 这些材料的组合即使在不存在金属基催化剂的情况下也加速了可湿固化的硅酮/非硅氧烷的缩合固化。

公开(公告)号：US20170306096A1

公开(公告)日：2017-10-26

申请号：US15528114

申请日：2015-11-20

Applicant: Momentive Performance Materials Inc.

Inventor： Ramesh MUTHUSAMY ,  Sumi DINKAR ,  Anantharaman DHANABALAN

IPC: C08G77/08 ,  C07C229/24 ,  C08G77/38 ,  C08K5/544

CPC classification number: C08G77/08 ,  C07C229/24 ,  C08G77/38 ,  C08K5/17 ,  C08K5/175 ,  C08K5/544 ,  C08L83/04

Abstract: The present invention provides moisture-curable compositions comprising an amino ester catalyst as an alternative to organotin catalysts. In particular, the present invention provides a condensation catalyst comprising a secondary amine, a tertiary amine, a substituted amine (e.g., an amino ester compound), or a combination of two or more thereof and optionally one or more aminosilanes or siloxanes. Further, the compositions employing amino esters allow for tuning or adjusting the cure characteristics of the compositions by the addition of other components such as adhesion promoters or acidic compounds, and provides good adhesion and storage stability.

公开(公告)号：US20170260335A1

公开(公告)日：2017-09-14

申请号：US15039604

申请日：2014-11-26

Applicant: Momentive Performance Materials Inc.

Inventor： Christopher Michael BYRNE ,  Anantharaman DHANABALAN ,  Sumi DINKAR ,  George SAMUELS

IPC: C08G77/08 ,  C08K5/544 ,  C08K5/56 ,  C08G77/16

CPC classification number: C08G77/08 ,  C08G77/02 ,  C08G77/16 ,  C08K5/544 ,  C08K5/56 ,  C08L83/04

Abstract: The present invention provides curable compositions comprising non-tin metal accelerators that accelerate the condensation curing of moisture-curable silicones/non-silicones. In particular, the present invention provides an accelerator comprising metal-arene complexes that are suitable as replacements for organotin in sealant and RTV formulations.

公开(公告)号：US20160060494A1

公开(公告)日：2016-03-03

申请号：US14775065

申请日：2014-02-27

Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.

Inventor： Mihirkumar PATEL ,  Anantharaman DHANABALAN ,  Sumi DINKAR ,  Vivek KARAMBELKAR

IPC: C09J183/04 ,  C09D183/04

CPC classification number: C09J183/04 ,  C08G18/289 ,  C08G18/797 ,  C08G77/08 ,  C08G77/455 ,  C08K3/01 ,  C08K5/0008 ,  C08K5/29 ,  C08K5/544 ,  C08K5/5465 ,  C08L43/04 ,  C08L101/10 ,  C08L2312/08 ,  C09D183/04 ,  C08L83/04

Abstract: The present invention provides curable compositions that are substantially free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst composition comprising the combination of a (i) carbodiimide functional compound, and (ii) an amino-containing compound such as an amino silane functional compound and/or an organic amine compound. The combination of these materials, particularly when aged, accelerates the condensation curing of moisture cur able silicones/non-silicones even in the absence of a metal-based catalyst.

Abstract translation: 本发明提供可固化组合物，其基本上不含金属催化剂，包括锡和非锡金属催化剂。 可固化组合物使用包含（i）碳二亚胺官能化合物和（ii）含氨基的化合物如氨基硅烷官能化合物和/或有机胺化合物的组合的催化剂组合物。 这些材料的组合，特别是老化时，即使在不存在金属基催化剂的情况下也加速了水分聚硅氧烷/非硅氧烷的缩合固化。

公开(公告)号：US20160369061A1

公开(公告)日：2016-12-22

申请号：US14902219

申请日：2014-07-02

Applicant: MOMENTIVE PERFORMANCE MATERIALS INC

Inventor： Sumi DINKAR

IPC: C08G77/44 ,  C08G77/08 ,  C08K5/20 ,  C08K13/02 ,  C08K3/36 ,  C08K5/544

CPC classification number: C08G77/44 ,  C08G77/08 ,  C08K3/36 ,  C08K5/20 ,  C08K5/5415 ,  C08K5/5419 ,  C08K5/5425 ,  C08K5/5435 ,  C08K5/544 ,  C08K5/5442 ,  C08K13/02

Abstract: The present invention provides curable compositions comprising non-tin metal accelerators that accelerate the condensation curing of moisture-curable silicones/non-silicones. In particular, the present invention provides an accelerator comprising amide compounds that are particularly suitable as replacements for organotin in sealant and RTV formulations. Further, the compositions employing an amide compound is comparable or superior to organotin such as DBTDL, exhibits certain behavior in the presence of components that allow for tuning or adjusting the cure characteristics of the compositions, and provides good adhesion and storage stability.

Abstract translation: 本发明提供包含非锡金属促进剂的可固化组合物，其加速湿固化性硅氧烷/非硅氧烷的缩合固化。 特别地，本发明提供了一种加速剂，其包含特别适合作为密封剂和RTV制剂中有机锡替代物的酰胺化合物。 此外，使用酰胺化合物的组合物相当于或优于有机锡如DBTDL，在存在能够调节或调节组合物的固化特性的组分的存在下表现出某些行为，并提供良好的粘附性和储存稳定性。