公开(公告)号：US09096781B2

公开(公告)日：2015-08-04

申请号：US13891592

申请日：2013-05-10

Applicant: Nitto Denko Corporation

Inventor： Yu Morimoto ,  Kousuke Yonezaki ,  Tatsumi Amano ,  Kazuma Mitsui ,  Kyoko Takashima

IPC: C09J133/02 ,  C08L101/04 ,  C09J133/04 ,  C09J133/16

CPC classification number: C09J133/02 ,  C08L101/04 ,  C08L2201/54 ,  C09J133/04 ,  C09J133/16

Abstract: An aim of the prevention invention is to provide a water dispersion type acryl-based pressure-sensitive adhesive composition for re-peeling, which can prevent electrification of an adherend at the time of peeling (peeling antistatic properties) and which can form a pressure-sensitive adhesive layer excellent in adherability and re-peelable properties, and also to provide a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer formed of the pressure-sensitive adhesive composition. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition of the present invention contains an acrylic emulsion-based polymer composed of a (meth)acrylic acid alkyl ester and a carboxyl-containing unsaturated monomer as raw material monomers, a perfluoroalkyl-containing oligomer, and an ionic compound.

Abstract translation: 本发明的目的在于提供一种用于再剥离的水分散型丙烯酸类压敏粘合剂组合物，其可以防止剥离时的被粘物带电（剥离抗静电性），并且可以形成压敏粘合剂， 粘合性和再剥离性优异的粘合剂层，以及提供具有由压敏粘合剂组合物形成的粘合剂层的压敏粘合片。 本发明的可再剥离型水分散型丙烯酸系粘合剂组合物含有由（甲基）丙烯酸烷基酯和含羧基的不饱和单体作为原料单体构成的丙烯酸乳液系聚合物，全氟烷基 的低聚物和离子化合物。

公开(公告)号：US20140308516A1

公开(公告)日：2014-10-16

申请号：US14352502

申请日：2012-10-12

Applicant: NITTO DENKO CORPORATION

Inventor： Kousuke Yonezaki ,  Tatsumi Amano ,  Yu Morimoto ,  Kazuma Mitsui ,  Kyoko Takashima

IPC: C09J7/02

CPC classification number: C09J7/38 ,  C08F220/18 ,  C08G77/46 ,  C09J7/22 ,  C09J133/02 ,  C09J133/08 ,  C09J2203/318 ,  C09J2205/114 ,  C09J2433/00 ,  C09J2483/00 ,  G02F2202/28 ,  Y10T428/2891 ,  Y10T428/31663 ,  C08F2220/1858 ,  C08F220/06 ,  C08F220/14

Abstract: Provided is a removable water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that is superior in antistatic properties (resistance to peeling-induced static build-up), removability, adhesion (adhesive properties), and the ability to prevent an increase in peel strength (adhesive strength) over time and also superior in less-staining properties on adherends, particularly, the ability to prevent white staining on adherends in a high-humidity environment. Also provided is a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer made from such a pressure-sensitive adhesive composition. The removable water-dispersible acrylic pressure-sensitive adhesive composition contains an acrylic emulsion polymer including units derived from raw material monomers including at least (A) an alkyl (meth)acrylate and (B) 0.5 to 10% by weight of a carboxyl group-containing unsaturated monomer; and an alkylene oxide group-containing polysiloxane.

Abstract translation: 本发明提供能够形成抗静电性（耐剥离性静电累积性），可除去性，粘合性（粘合性）优异的压敏粘合剂层的可除去的水分散性丙烯酸系压敏粘合剂组合物， 防止随着时间的推移剥离强度（粘合强度）增加的能力，并且在被粘物上的染色性能也优异，特别是在高湿度环境下防止被粘附物白色染色的能力。 还提供了具有由这种压敏粘合剂组合物制成的压敏粘合剂层的压敏粘合片。 可拆卸的水分散性丙烯酸类压敏粘合剂组合物包含丙烯酸乳液聚合物，其包含衍生自至少包含（A）（甲基）丙烯酸烷基酯的原料单体的单元和（B）0.5至10重量％的羧基 - 含不饱和单体; 和含环氧烷基团的聚硅氧烷。

公开(公告)号：US20140342152A1

公开(公告)日：2014-11-20

申请号：US14352533

申请日：2012-10-12

Applicant: NITTO DENKO CORPORATION

Inventor： Tatsumi Amano ,  Yu Morimoto ,  Kazuma Mitsui ,  Kousuke Yonezaki ,  Kyoko Takashima

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08F220/18 ,  C09J7/385 ,  C09J11/04 ,  C09J11/06 ,  C09J133/02 ,  Y10T428/2891 ,  Y10T428/31935 ,  C08F2220/1858 ,  C08F220/06

Abstract: An object of the invention to provide a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that can prevent static build-up on adherends when peeled off (antistatic properties) and is superior not only in removability and the ability to prevent an increase in peel strength (adhesive strength) over time but also in less-staining properties on adherends and, especially, the ability to prevent white staining on adherends in a high-humidity environment (the ability to prevent white staining). The invention is directed to a removable water-dispersible acrylic pressure-sensitive adhesive composition, including: an acrylic emulsion polymer including units derived from raw material monomers including (i) 70 to 99.5% by weight of an alkyl(meth)acrylate and (ii) 0.5 to 10% by weight of a carboxyl group-containing unsaturated monomer; a non-water-soluble crosslinking agent; and an ionic compound.

Abstract translation: 本发明的目的是提供一种能够形成压敏粘合剂层的水分散性丙烯酸类压敏粘合剂组合物，其可以防止被剥离时的被粘附物的静电积聚（抗静电性），并且不仅在可除去性方面和 防止随着时间的推移剥离强度（粘合强度）增加而且在被粘物上的染色性能降低的能力，特别是在高湿度环境下防止被粘附物白色染色的能力（防止白色染色的能力） 。 本发明涉及可拆卸的水分散性丙烯酸类压敏粘合剂组合物，其包括：丙烯酸乳液聚合物，其包含衍生自原料单体的单元，所述单体包括（i）70-99.5重量％的（甲基）丙烯酸烷基酯和（ii ）0.5〜10重量％的含羧基的不饱和单体; 非水溶性交联剂; 和离子化合物。

公开(公告)号：US20140248490A1

公开(公告)日：2014-09-04

申请号：US14352245

申请日：2012-10-12

Applicant: NITTO DENKO CORPORATION

Inventor： Yu Morimoto ,  Tatsumi Amano ,  Kazuma Mitsui ,  Kousuke Yonezaki ,  Kyoko Takashima

IPC: C09J11/08 ,  C09J133/08 ,  C09J133/12 ,  C09J7/02

CPC classification number: C09J11/08 ,  C08G2650/58 ,  C08K3/017 ,  C08K3/16 ,  C08K5/0075 ,  C08K5/17 ,  C08L71/02 ,  C09J7/385 ,  C09J133/00 ,  C09J133/06 ,  C09J133/08 ,  C09J133/12 ,  C09J2203/318 ,  C09J2205/102 ,  C09J2433/00 ,  C09J2471/00 ,  Y10T428/2891 ,  Y10T428/31938

Abstract: Provided is a removable water-dispersible acrylic pressure-sensitive adhesive composition with which it is possible to form a pressure-sensitive adhesive layer that has excellent antistatic properties, adhesive properties, removability, removal stability, and the ability to prevent an increase in adhesive strength over time, less-staining properties on adherends, especially, the ability to prevent white staining on adherends in a high-humidity environment (the ability to prevent white staining), and appearance properties. The present invention is directed to a removable water-dispersible acrylic pressure-sensitive adhesive composition, including: an acrylic emulsion polymer including 70 to 99.5% by weight of a monomer unit derived from an alkyl(meth)acrylate and 0.5 to 10% by weight of a monomer unit derived from a carboxyl group-containing unsaturated monomer; an ionic compound; and a polyether antifoamer represented by formula (I) below. HO—(PO)n1-(EO)m1—H  (I) In formula (I), PO represents an oxypropylene group, EO represents an oxyethylene group, m1 represents an integer of 0 to 40, n1 represents an integer of 1 or more, and EO and PO are added in a random form or a block form.

Abstract translation: 提供一种可拆卸的水分散性丙烯酸类压敏粘合剂组合物，其可以形成具有优异的抗静电性，粘合性，可除去性，去除稳定性以及防止粘合强度增加的能力的压敏粘合剂层 随着时间的推移，被粘物的染色性能降低，特别是在高湿度环境（防止白色染色的能力）上防止白色染色的能力和外观性能。 本发明涉及一种可去除的水分散性丙烯酸类压敏粘合剂组合物，其包括：丙烯酸乳液聚合物，其包含70-99.5重量％的衍生自（甲基）丙烯酸烷基酯的单体单元和0.5至10重量％ 的衍生自含羧基的不饱和单体的单体单元; 离子化合物; 和由下式（I）表示的聚醚消泡剂。 HO-（PO）n1-（EO）m1-H（I）在式（I）中，PO表示氧化亚丙基，EO表示氧化乙烯基，m1表示0〜40的整数，n1表示1或1的整数， 更多，EO和PO以随机形式或嵌段形式加入。

公开(公告)号：US20140302314A1

公开(公告)日：2014-10-09

申请号：US14247704

申请日：2014-04-08

Applicant: NITTO DENKO CORPORATION

Inventor： Kyoko Takashima ,  Yu Morimoto ,  Kazuma Mitsui ,  Kousuke Yonezaki ,  Tsunaki Kitahara

IPC: C09J133/08 ,  C09J7/02

CPC classification number: C09J133/08 ,  C08F220/18 ,  C08L2201/54 ,  C08L2312/00 ,  C09J7/385 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/06 ,  C08F220/14

Abstract: Provided is a water-dispersible acrylic pressure-sensitive adhesive composition which can form a pressure-sensitive adhesive layer excellent in antistatic property, repeeling property (light peeling property), and appearance property. The repeelable water-dispersible acrylic pressure-sensitive adhesive composition of the present invention contains an acrylic emulsion-based polymer composed of 70 to 99.5% by weight of a (meth)acrylic acid alkyl ester and 0.5 to 10% by weight of a carboxyl group-containing unsaturated monomer as monomer components, a crosslinking agent, an ionic compound, and a nonionic surfactant with an HLB value of 6 or more.

Abstract translation: 本发明提供一种能够形成抗静电性，重复性（光剥离性）和外观性优异的压敏粘合剂层的水分散性丙烯酸类粘合剂组合物。 本发明的可重复使用的水分散性丙烯酸类粘合剂组合物含有由70〜99.5重量％的（甲基）丙烯酸烷基酯和0.5〜10重量％的羧基组成的丙烯酸系乳液系聚合物 作为单体成分的不饱和单体，HLB值为6以上的交联剂，离子性化合物和非离子表面活性剂。

公开(公告)号：US20140255690A1

公开(公告)日：2014-09-11

申请号：US14352435

申请日：2012-10-12

Applicant: NITTO DENKO CORPORATION

Inventor： Tatsumi Amano ,  Yu Morimoto ,  Kazuma Mitsui ,  Kousuke Yonezaki ,  Kyoko Takashima

IPC: C09J7/02

CPC classification number: C09J7/22 ,  C08F220/08 ,  C08K5/0075 ,  C08K5/19 ,  C08K5/34 ,  C09J7/38 ,  C09J9/02 ,  C09J133/08 ,  C09J2203/318 ,  C09J2205/102 ,  C09J2433/00 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/06

Abstract: Provided is a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that is superior in adhesive properties, antistatic properties, removability, the ability to prevent an increase in peel strength (adhesive strength) over time, and superior in less-staining properties on adherends, particularly, in the ability to prevent white staining on adherends in a high-humidity environment (the ability to prevent white staining), and also superior in appearance properties. The invention is directed to a water-dispersible acrylic pressure-sensitive adhesive composition, including: an acrylic emulsion polymer including 70 to 99.5% by weight of a monomer unit derived from an alkyl (meth)acrylate and 0.5 to 10% by weight of a monomer unit derived from a carboxyl group-containing unsaturated monomer; a non-water-soluble (hydrophobic) ionic liquid; and an acetylene diol compound with an HLB value of less than 13 and/or a derivative thereof with an HLB value of less than 13.

Abstract translation: 提供一种能够形成粘合性，抗静电性，可除去性，防止随时间推移的剥离强度（粘合强度）增加的能力的粘合剂层的水分散性丙烯酸类压敏粘合剂组合物，以及 特别是在高湿度环境下（特别是防止白色染色的能力）防止白色染色的能力，以及外观性能也优异。 本发明涉及一种水分散性丙烯酸类压敏粘合剂组合物，其包括：丙烯酸乳液聚合物，其包含70-99.5重量％的衍生自（甲基）丙烯酸烷基酯的单体单元和0.5至10重量％的 衍生自含羧基的不饱和单体的单体单元; 非水溶性（疏水）离子液体; 和HLB值小于13的乙炔二醇化合物和/或其HLB值小于13的衍生物。

公开(公告)号：US20140272408A1

公开(公告)日：2014-09-18

申请号：US14352896

申请日：2012-10-12

Applicant: NITTO DENKO CORPORATION

Inventor： Tatsumi Amano ,  Yu Morimoto ,  Kazuma Mitsui ,  Kousuke Yonezaki ,  Kyoko Takashima

IPC: C09J7/02

CPC classification number: C08L33/02 ,  C08G77/46 ,  C08G2650/58 ,  C08K5/0075 ,  C08L2201/50 ,  C08L2201/54 ,  C09J7/22 ,  C09J7/38 ,  C09J133/02 ,  C09J133/08 ,  C09J133/26 ,  C09J171/02 ,  C09J2203/318 ,  C09J2205/102 ,  C09J2433/00 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/06 ,  C08F220/14 ,  C08F218/08 ,  C08F220/54

Abstract: Provided is a water-dispersible acrylic pressure-sensitive adhesive composition capable of forming a pressure-sensitive adhesive layer that can prevent static build-up at the time of peeling (antistatic properties), is superior in removability, in the ability to prevent an increase in peel strength (adhesive strength) over time among the adhesive properties, as well as in appearance properties (decrease of appearance defects due to dents or the like), and also in less-staining properties on adherends, particularly, in the ability to prevent white staining on adherends in high-humidity environments (the ability to prevent white staining). The water-dispersible acrylic pressure-sensitive adhesive composition according to the invention contains an acrylic emulsion polymer containing, as monomer components, (i) an alkyl (meth)acrylate, (ii) a carboxyl group-containing unsaturated monomer, and (iii) at least one monomer selected from the group consisting of methyl methacrylate, vinyl acetate, and diethylacrylamide, and an ionic compound, and is characterized in that 70 to 99.5% by weight of the alkyl (meth)acrylate (i) is contained in the total amount of the monomer components.

Abstract translation: 本发明提供一种能够形成能够防止剥离时的静电积聚（抗静电性）的粘合剂层的防水性分散性丙烯酸系压敏粘合剂组合物，其除去性优异，防止增加的能力 在粘合性能以及外观性能（由凹痕等引起的外观缺陷减少）时的剥离强度（粘合强度）随着时间的推移，以及在被粘物上的污染性较差，特别是在防止 在高湿环境下的被粘物上白色染色（防止白色染色的能力）。 本发明的水分散性丙烯酸类粘合剂组合物含有（i）（甲基）丙烯酸烷基酯，（ii）含羧基的不饱和单体作为单体组分的丙烯酸乳液聚合物，和（iii） 至少一种选自甲基丙烯酸甲酯，乙酸乙烯酯和二乙基丙烯酰胺的单体和离子性化合物，其特征在于，总共含有70〜99.5重量％的（甲基）丙烯酸烷基酯（i） 单体组分的量。

公开(公告)号：US20140242384A1

公开(公告)日：2014-08-28

申请号：US14352455

申请日：2012-10-15

Applicant: NITTO DENKO CORPORATION

Inventor： Kyoko Takashima ,  Kazuma Mitsui ,  Yu Morimoto ,  Tatsumi Amano ,  Kousuke Yonezaki

IPC: C09J7/02

CPC classification number: C09J7/385 ,  C08L2201/54 ,  C08L2312/00 ,  C09J133/02 ,  C09J133/08 ,  Y10T428/2848 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/14 ,  C08F220/06

Abstract: The present invention provides an acrylic water-dispersible pressure-sensitive adhesive composition that can prepare a removable adhesive layer having low contamination of an adherent. The acrylic water-dispersible pressure-sensitive removable adhesive composition according to the present invention comprises an acrylic emulsion polymer (A) comprising an alkyl (meth)acrylate ester and a carboxyl group-containing unsaturated monomer as essential raw material constitutive monomers and prepared by polymerization with a reactive surfactant containing no oxyalkylene group.

Abstract translation: 本发明提供一种丙烯酸水分散性压敏粘合剂组合物，其可以制备具有低粘附剂污染的可除去粘合剂层。 根据本发明的丙烯酸水分散性压敏可去除粘合剂组合物包含包含（甲基）丙烯酸烷基酯和含羧基的不饱和单体作为主要原料组成单体并通过聚合制备的丙烯酸乳液聚合物（A） 与不含氧化烯基的反应性表面活性剂。

公开(公告)号：US20130303669A1

公开(公告)日：2013-11-14

申请号：US13891592

申请日：2013-05-10

Applicant: NITTO DENKO CORPORATION

Inventor： Yu Morimoto ,  Kousuke Yonezaki ,  Tatsumi Amano ,  Kazuma Mitsui ,  Kyoko Takashima

IPC: C09J133/02

CPC classification number: C09J133/02 ,  C08L101/04 ,  C08L2201/54 ,  C09J133/04 ,  C09J133/16

Abstract: An aim of the prevention invention is to provide a water dispersion type acryl-based pressure-sensitive adhesive composition for re-peeling, which can prevent electrification of an adherend at the time of peeling (peeling antistatic properties) and which can form a pressure-sensitive adhesive layer excellent in adherability and re-peelable properties, and also to provide a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer formed of the pressure-sensitive adhesive composition. The re-peelable water dispersion type acryl-based pressure-sensitive adhesive composition of the present invention contains an acrylic emulsion-based polymer composed of a (meth)acrylic acid alkyl ester and a carboxyl-containing unsaturated monomer as raw material monomers, a perfluoroalkyl-containing oligomer, and an ionic compound.

Abstract translation: 本发明的目的在于提供一种用于再剥离的水分散型丙烯酸类压敏粘合剂组合物，其可以防止剥离时的被粘物带电（剥离抗静电性），并且可以形成压敏粘合剂， 粘合性和再剥离性优异的粘合剂层，以及提供具有由压敏粘合剂组合物形成的粘合剂层的压敏粘合片。 本发明的可再剥离型水分散型丙烯酸系粘合剂组合物含有由（甲基）丙烯酸烷基酯和含羧基的不饱和单体作为原料单体构成的丙烯酸乳液系聚合物，全氟烷基 的低聚物和离子化合物。