公开(公告)号：US07619803B2

公开(公告)日：2009-11-17

申请号：US11915729

申请日：2006-04-11

申请人： Noriyuki Kokeguchi ,  Osamu Ishige ,  Rie Sakuragi

发明人： Noriyuki Kokeguchi ,  Osamu Ishige ,  Rie Sakuragi

IPC分类号： G02F1/15 ,  G02B5/23

CPC分类号： G02F1/155 ,  C09K9/02 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  G02F1/15 ,  G02F2001/1555

摘要： An electrochromic display element includes a pair of counter electrodes having therebetween an electrochromic compound represented by Formula (1), wherein the electrochromic compound becomes colored when being oxidized and becomes colorless when being reduced by a driving operation of the electrodes: wherein R1 represents a substituted or unsubstituted aryl group; and R2 and R3 each represent a hydrogen atom or a substituent; X represents >N—R4, an oxygen atom or a sulfur atom; and R4 represents a hydrogen atom or a substituent.

摘要翻译： 电致变色显示元件包括一对相对电极，其间具有由式（1）表示的电致变色化合物，其中电致变色化合物在氧化时变色，并且当通过电极的驱动操作而变得无色时：其中R1表示取代的 或未取代的芳基; R2和R3各自表示氢原子或取代基; X表示> N-R4，氧原子或硫原子; R4表示氢原子或取代基。

公开(公告)号：US20090027757A1

公开(公告)日：2009-01-29

申请号：US11915729

申请日：2006-04-11

申请人： Noriyuki Kokeguchi ,  Osamu Ishige ,  Rie Sakuragi

发明人： Noriyuki Kokeguchi ,  Osamu Ishige ,  Rie Sakuragi

IPC分类号： G02F1/153

CPC分类号： G02F1/155 ,  C09K9/02 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  G02F1/15 ,  G02F2001/1555

摘要： An electrochromic display element includes a pair of counter electrodes having therebetween an electrochromic compound represented by Formula (1), wherein the electrochromic compound becomes colored when being oxidized and becomes colorless when being reduced by a driving operation of the electrodes: wherein R1 represents a substituted or unsubstituted aryl group; and R2 and R3 each represent a hydrogen atom or a substituent; X represents >N—R4, an oxygen atom or a sulfur atom; and R4 represents a hydrogen atom or a substituent.

摘要翻译： 电致变色显示元件包括一对相对电极，其间具有由式（1）表示的电致变色化合物，其中电致变色化合物在氧化时变色，并且当通过电极的驱动操作而变得无色时：其中R1表示取代的 或未取代的芳基; R2和R3各自表示氢原子或取代基; X表示> N-R4，氧原子或硫原子; R4表示氢原子或取代基。

公开(公告)号：US08064119B2

公开(公告)日：2011-11-22

申请号：US12448884

申请日：2007-11-14

申请人： Noriyuki Kokeguchi ,  Takeshi Hakii ,  Osamu Ishige

发明人： Noriyuki Kokeguchi ,  Takeshi Hakii ,  Osamu Ishige

IPC分类号： G02F1/153 ,  G02F1/15 ,  G09G3/19

CPC分类号： G02F1/1521 ,  G02F1/1506 ,  G02F1/155

摘要： This invention provides a novel electrochemical display element, which can realize bright white display, high-contrast black and white display, and full-color display by a simple member construction, and a method for driving the display element. The display element is characterized in that it comprises opposed electrodes, and an electrolyte, an electrochromic compound, a metal salt compound, and a white scattering material between the opposed electrodes, and multicolor display of three or more colors is carried out by black display, white display, and display of color other than black by driving the opposed electrodes by taking advantage of 1) a color change as a result of oxidation and reduction reactions of the electrochromic compound, and 2) a color change as a result of reduction precipitation and oxidation dissolution of a metallic element contained in the metal salt compound in at least one of the opposed electrodes.

摘要翻译： 本发明提供一种新颖的电化学显示元件，其可以通过简单的构件构造实现亮白显示，高对比度黑白显示和全色显示，以及用于驱动显示元件的方法。 显示元件的特征在于它包括相对电极，在相对电极之间的电解质，电致变色化合物，金属盐化合物和白色散射材料，并且通过黑色显示来执行三种或更多种颜色的多色显示， 通过利用1）作为电致变色化合物的氧化还原反应的结果的颜色变化，以及2）作为还原析出的结果的颜色变化，通过驱动相对的电极而显示除了黑色以外的颜色，以及 包含在金属盐化合物中的金属元素在至少一个相对电极中的氧化溶解。

公开(公告)号：US20100091352A1

公开(公告)日：2010-04-15

申请号：US12448884

申请日：2007-11-14

申请人： Noriyuki Kokeguchi ,  Takeshi Hakii ,  Osamu Ishige

发明人： Noriyuki Kokeguchi ,  Takeshi Hakii ,  Osamu Ishige

IPC分类号： G02F1/153 ,  G02F1/155

CPC分类号： G02F1/1521 ,  G02F1/1506 ,  G02F1/155

摘要： This invention provides a novel electrochemical display element, which can realize bright white display, high-contrast black and white display, and full-color display by a simple member construction, and a method for driving the display element. The display element is characterized in that it comprises opposed electrodes, and an electrolyte, an electrochromic compound, a metal salt compound, and a white scattering material between the opposed electrodes, and multicolor display of three or more colors is carried out by black display, white display, and display of color other than black by driving the opposed electrodes by taking advantage of 1) a color change as a result of oxidation and reduction reactions of the electrochromic compound, and 2) a color change as a result of reduction precipitation and oxidation dissolution of a metallic element contained in the metal salt compound in at least one of the opposed electrodes.

摘要翻译： 本发明提供一种新颖的电化学显示元件，其可以通过简单的构件构造实现亮白显示，高对比度黑白显示和全色显示，以及用于驱动显示元件的方法。 显示元件的特征在于它包括相对电极，在相对电极之间的电解质，电致变色化合物，金属盐化合物和白色散射材料，并且通过黑色显示来执行三种或更多种颜色的多色显示， 通过利用1）作为电致变色化合物的氧化还原反应的结果的颜色变化，以及2）作为还原析出的结果的颜色变化，通过驱动相对的电极而显示除了黑色以外的颜色，以及 包含在金属盐化合物中的金属元素在至少一个相对电极中的氧化溶解。

公开(公告)号：US08999430B2

公开(公告)日：2015-04-07

申请号：US12600928

申请日：2008-05-01

申请人： Noriyuki Kokeguchi

发明人： Noriyuki Kokeguchi

IPC分类号： B05D5/12 ,  B05D5/06 ,  C09D11/36 ,  G02F1/161 ,  G02F1/155 ,  G02F1/15

CPC分类号： C09D11/36 ,  G02F1/1521 ,  G02F1/155 ,  G02F1/161 ,  G02F2001/151

摘要： Disclosed is a method of manufacturing an electrochromic display element having improved durability. Specifically disclosed is a method of manufacturing a display element containing opposed electrodes and a porous layer which is arranged between the opposed electrodes and containing a metal oxide and an electrochromic dye supported on the metal oxide. The method contains the step of applying plural kinds of inks to the porous layer by an inkjet apparatus, wherein the inks are capable of uniformizing the amount of the electrochromic dye supported on the porous layer containing the metal oxide in one pixel of the display element.

摘要翻译： 公开了一种具有改善的耐久性的电致变色显示元件的制造方法。 具体公开了一种制造显示元件的方法，该显示元件包含相对的电极和多孔层，该多孔层布置在相对的电极之间并且包含负载在金属氧化物上的金属氧化物和电致变色染料。 该方法包括通过喷墨设备将多种油墨应用于多孔层的步骤，其中油墨能够使显示元件的一个像素中含有金属氧化物的多孔层上的电致变色染料的量均匀化。

公开(公告)号：US08264423B2

公开(公告)日：2012-09-11

申请号：US12449411

申请日：2008-01-28

申请人： Noriyuki Kokeguchi

发明人： Noriyuki Kokeguchi

IPC分类号： G09G3/18

CPC分类号： G02F1/1506 ,  G09G3/38 ,  G09G2300/0809 ,  G09G2300/0842 ,  G09G2310/061 ,  G09G2320/0666

摘要： Provided is a method of driving a display element in which color tone variation of white during repeated drive has been reduced. Also disclosed is a method of driving a display element in which an electrolyte comprising silver or a compound containing silver in a chemical structure thereof is contained between facing electrodes, comprising the step of applying a driving operation to the facing electrodes so as to induce dissolution and deposition of silver, wherein an impression necessary for displaying black color is the impression of a pulse applied to the facing electrodes, satisfying the following Expression (1). Expression (1) 1/100 ≦TBP/TW≦1/5, where TBP represents time width (ms) of one pulse applied in an applied direction necessary for black display, and TW represents the sum of applied time (ms) in an applied direction necessary for white display after conducting the black display employing the applied pulse.

摘要翻译： 提供了一种驱动重复驱动期间白色的色调变化已经降低的显示元件的方法。 还公开了一种驱动显示元件的方法，其中包含银或其化学结构中含有银的化合物的电解质包含在相对电极之间的显示元件，包括向对置电极施加驱动操作以引起溶解的步骤，以及 银的沉积，其中显示黑色所需的印象是施加到面对电极的脉冲的印象，满足以下表达式（1）。 表达式（1）1/100＆nlE; TBP / TW＆nlE; 1/5，其中TBP表示在黑色显示所需的施加方向上施加的一个脉冲的时间宽度（ms），TW表示施加的时间（ms） 在使用所施加的脉冲进行黑色显示之后白色显示所需的施加方向。

公开(公告)号：US07751111B2

公开(公告)日：2010-07-06

申请号：US11915842

申请日：2006-04-20

申请人： Noriyuki Kokeguchi

发明人： Noriyuki Kokeguchi

IPC分类号： G02B1/153

CPC分类号： G02F1/1508 ,  G02F1/163 ,  G02F2001/136245 ,  G09G3/38 ,  G09G2300/0852 ,  G09G2310/0262

摘要： Provided is a display element which is drivable with simple components and at a relatively low voltage and exhibits high display contrast, enhanced white display reflectance, superior response speed and reduced image unevenness. The display element includes opposing electrodes having therebetween an electrolyte containing silver or a compound having silver in the chemical structure, wherein the opposing electrodes are driven by a drive circuit disposed for each of pixels so that the silver is dissolved and deposited and the opposing electrodes are provided on a plane separate from the drive circuit.

摘要翻译： 提供一种显示元件，其以简单的组件驱动并且处于相对低的电压并且显示出高显示对比度，增强的白色显示反射率，优异的响应速度和减少的图像不均匀性。 显示元件包括在其间具有包含银的电解质或在化学结构中具有银的化合物的电极，其中相对电极由为每个像素设置的驱动电路驱动，使得银溶解并沉积，并且相对电极为 设置在与驱动电路分开的平面上。

公开(公告)号：US20100091353A1

公开(公告)日：2010-04-15

申请号：US12519663

申请日：2007-12-06

申请人： Noriyuki Kokeguchi ,  Kaori Ono

发明人： Noriyuki Kokeguchi ,  Kaori Ono

IPC分类号： G02F1/153

CPC分类号： C07D233/64 ,  C07D263/32 ,  C07D491/048 ,  C09B1/00 ,  C09B5/14 ,  C09B11/02 ,  C09B11/24 ,  C09B17/00 ,  C09B19/00 ,  C09B21/00 ,  C09B23/0091 ,  C09B23/14 ,  C09B57/00 ,  C09K9/02 ,  C09K2211/1007 ,  C09K2211/1033 ,  C09K2211/1037 ,  C09K2211/1044 ,  G02F1/1506 ,  G02F1/163

摘要： Provided is a novel electrochemical display element which performs bright white display, high contrast black/white display and full-color display with a simple member configuration. A method for driving such display element is also provided. The display element contains an electrochromic compound, which is colored or has its color disappear due to oxidation or reduction, a metallic salt compound, an electrolyte and a white scattered material, between opposing electrodes. The display element substantially performs multiple color display of three colors or more, i.e., black display, white display and colored display other than black, by driving operation of the opposing electrodes.

摘要翻译： 提供了一种新颖的电化学显示元件，其执行明亮的白色显示，高对比度黑/白显示和具有简单构件配置的全色显示。 还提供了一种用于驱动这种显示元件的方法。 显示元件含有在对置电极之间着色或由于氧化或还原的颜色消失的电致变色化合物，金属盐化合物，电解质和白色散射材料。 通过驱动相对电极的操作，显示元件基本上进行三色以上的多色显示，即黑色显示，白色显示，黑色以外的彩色显示。

公开(公告)号：US20090201239A1

公开(公告)日：2009-08-13

申请号：US12304361

申请日：2007-06-05

申请人： Noriyuki Kokeguchi

发明人： Noriyuki Kokeguchi

IPC分类号： G09G3/36

CPC分类号： G02F1/1506

摘要： A display element in which a tone variation in halftone color is reduced at the time of repetitive driving. The display element contains electrolyte which contains silver between counter electrodes or contains a compound including silver in the chemical structure, and performs drive operation of the counter electrodes to cause dissolution deposition of silver. The display element is characterized by satisfying a relation A1/A2>4, where A1 (mA/cm2) is the maximum absolute value of a current flowing between the counter electrodes when they are driven in the direction for depositing silver from a state where silver is not deposited on the display electrode side, and A2 (mA/cm2) is the maximum absolute value of a current flowing between the counter electrodes when they are driven in the direction for dissolving silver from a state where silver is not deposited on the display electrode side.

摘要翻译： 在重复驱动时，半色调色调的色调变小的显示元件。 显示元件含有在对置电极之间含有银或在化学结构中含有包含银的化合物的电解质，并且进行对电极的驱动操作以引起银的溶解沉积。 显示元件的特征在于满足A1 / A2> 4的关系，其中A1（mA / cm2）是当银从银的方向驱动时在对电极之间流动的电流的最大绝对值 不会沉积在显示电极侧，A2（mA / cm 2）是从银不会沉积在显示器上的银的溶解方向被驱动时的对置电极之间流动的电流的最大绝对值 电极侧。

公开(公告)号：US07344763B2

公开(公告)日：2008-03-18

申请号：US11209114

申请日：2005-08-22

申请人： Noriyuki Kokeguchi ,  Satoru Ikesu

发明人： Noriyuki Kokeguchi ,  Satoru Ikesu

IPC分类号： C09K19/52 ,  C09K19/54 ,  C09K19/60

CPC分类号： G02F1/13718 ,  C09K19/52 ,  C09K19/544 ,  C09K19/60 ,  C09K2019/546 ,  G02F1/13476 ,  Y10T428/10 ,  Y10T428/1036 ,  Y10T428/1041

摘要： A rewritable display containing a substrate having thereon one or more constitution layers, one of the constitution layers being a liquid crystal layer containing a liquid crystal composition which is dispersed in a binder, and one of the constitution layers containing a compound selected from the group constituted of: (a) alumina particles; (b) a layer structured inorganic compound; (c) a specific azomethine dye compound represented by Formula (D) whose structure is described in the specification; (d) a fluorescent brightening agent; and (e) a ultraviolet absorber.

摘要翻译： 一种包含其上具有一个或多个构成层的基板的可重写显示器，其中一个构成层是包含分散在粘合剂中的液晶组合物的液晶层，以及包含选自构成的组中的化合物的构成层之一 ：（a）氧化铝颗粒; （b）层状结构的无机化合物; （c）结构在说明书中描述的由式（D）表示的特定的偶氮甲碱染料化合物; （d）荧光增白剂; 和（e）紫外线吸收剂。