Abstract:
A hydrogenation method and distillate two-phase hydrogenation reactor in which the size of an upper space of the reactor is greater than that of a lower catalyst bed part. The reactor comprises 2 to 4 catalyst beds. An inner component for gas replenishment and for stripping a liquid-phase stream containing impurities is arranged between at least one adjacent catalyst bed and comprises a separator plate and exhaust pipes. The separator plate is provided with multiple downcomer through holes. The separator plate is connected with a plurality of exhaust pipes. The exhaust pipes are vertically arranged above the separator plate. The top parts of the exhaust pipes are in contact with the lower part of the upper catalyst bed.
Abstract:
A gas-phase aldehyde hydrogenation catalyst, a preparation method thereof and an application thereof, where the preparation method includes: mixing an aluminum salt, a first zinc salt, silica sol, a first precipitant and water, and performing a first aging treatment to obtain a first mixed solution; mixing a copper salt, a second zinc salt, a zinc powder and water, and performing an ultrasonic treatment to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and a second precipitant, and performing a second aging treatment to obtain a third mixed solution; adding boric acid into the third mixed solution, and performing a third aging treatment to obtain a fourth mixed solution; filtering the fourth mixed solution, and sequentially drying and roasting the obtained solid product to obtain a catalyst precursor; mixing and molding the catalyst precursor with a graphite to obtain a gas-phase aldehyde hydrogenation catalyst.