Method for catalytic and selective oxidation of aromatic compounds
    1.
    发明授权
    Method for catalytic and selective oxidation of aromatic compounds 失效
    芳香族化合物的催化和选择性氧化方法

    公开(公告)号:US06365762B1

    公开(公告)日:2002-04-02

    申请号:US09403461

    申请日:2000-03-14

    IPC分类号: C07C5012

    摘要: The invention relates to the use of compounds of the formula R1aRebOc.Ld  (I), in which and the total of a, b and c is such as to comply with the pentavalency or heptavalency of rhenium, with the proviso that c is not larger than 3×b, and in which R1 is absent or identical or different, and is an aliphatic hydrocarbon radical having 1 to 10 carbon atoms, an aromatic hydrocarbon radical having 6 to 10 carbon atoms or an arylalkyl radical having 7 to 9 carbon atoms, it being possible for the R1 radicals where appropriate to be substituted identically or differently, independently of one another, as catalysts for oxidizing electron-rich aromatic compounds and their derivatives, the catalysts being employed in a peroxide-containing solution in the presence of an anhydride of a carboxylic acid and/or of a dehydrating agent.

    摘要翻译: 本发明涉及甲醛化合物的用途,并且a,b和c的总量符合铼的五价态或七价态,条件是c不大于3xb,并且其中R1不存在 或相同或不同,并且是具有1至10个碳原子的脂族烃基,具有6至10个碳原子的芳族烃基或具有7至9个碳原子的芳基烷基,在适当的情况下可以使R1基团 取代相同或不同,彼此独立地,作为用于氧化富含电子的芳族化合物及其衍生物的催化剂,所述催化剂用于含羧酸酐和/或脱水剂的过氧化物溶液中 。

    Direct synthesis of organorhenium oxides from compounds containing rhenium
    2.
    发明授权
    Direct synthesis of organorhenium oxides from compounds containing rhenium 失效
    从含铼的化​​合物直接合成有机铼

    公开(公告)号:US06180807B2

    公开(公告)日:2001-01-30

    申请号:US09403439

    申请日:2000-02-10

    IPC分类号: C07F1300

    CPC分类号: C07F13/00

    摘要: The present invention relates to a process for the preparation of organorhenium oxides from rhenium-containing compounds, where the rhenium-containing compound is reacted with a silylating agent and organylating reagent, and the rhenium-containing compound originates in particular from the residue from a spent organorhenium oxide catalyst or rhenium oxide catalyst.

    摘要翻译: 本发明涉及一种从含铼化合物制备有机铼氧化物的方法,其中含铼化合物与甲硅烷基化剂和有机化试剂反应,并且含铼化合物尤其从废弃的残余物中产生 有机氧化铼催化剂或氧化铼催化剂。

    Preparation of supported cocatalysts

    公开(公告)号:US20070149387A1

    公开(公告)日:2007-06-28

    申请号:US10583064

    申请日:2004-12-22

    IPC分类号: B01J21/02

    摘要: The present invention relates to a process for preparing a supported cocatalyst for olefin polymerization, which comprises reacting A) a support bearing functional groups, B) triethylaluminum and C) a compound of the formula (I), (R1)x—A—OH)y  (I) where A is an atom of group 13 or 15 of the Periodic Table, R1 are identical or different and are each, independently of one another, hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalky, C7-C40-haloarylalkyl, C7-C40-alkylaryl, C7-C40-haloalkylaryl or an OSiR32 group, where R2 are identical or different and are each hydrogen, halogen, C1-C20-alkyl, C1-C20-haloalkyl, C1-C10-alkoxy, C6-C20-aryl, C6-C20-haloaryl, C6-C20-aryloxy, C7-C40-arylalkyl, C7-C40-haloarylalkyl, C7-C40-alkylaryl or C7-C40-haloalkylaryl, y is 1 or 2 and x is 3 minus y. In addition, the invention relates to supported cocatalysts obtainable by such a process, to the use of the supported cocatalysts for preparing a catalyst system for the polymerization of olefins, to catalyst systems for the polymerization of olefins obtainable from the supported cocatalysts and to a process for the polymerization of olefins in which these catalyst solids are used.

    Preparation of catalyst systems
    4.
    发明授权
    Preparation of catalyst systems 失效
    催化剂体系的制备

    公开(公告)号:US07285513B2

    公开(公告)日:2007-10-23

    申请号:US10521076

    申请日:2003-07-14

    IPC分类号: B01J31/12 B01J31/14

    摘要: The present invention relates to a process for preparing a catalyst for olefin polymerization which is obtainable by bringing A) at least one organic transition metal compound, B) a mixture of at least two different organo metallic compounds and C) at least one cation-forming compound into contact with one another, wherein the organic transition metal compound A) is firstly brought into contact with the mixture of the organo metallic compounds B). In addition, the invention relates to the use of the catalyst for olefin polymerization, to catalysts obtainable by this process and to a process for the polymerization of olefins in which these catalysts are used.

    摘要翻译: 本发明涉及一种制备用于烯烃聚合的催化剂的方法,其可通过使A)至少一种有机过渡金属化合物,B)至少两种不同的有机金属化合物的混合物和C)至少一种阳离子形成 化合物彼此接触,其中首先使有机过渡金属化合物A)与有机金属化合物B)的混合物接触。 此外,本发明涉及用于烯烃聚合的催化剂,通过该方法获得的催化剂的用途以及使用这些催化剂的烯烃的聚合方法。

    Preparation of supported catalyst systems

    公开(公告)号:US20060166813A1

    公开(公告)日:2006-07-27

    申请号:US10521073

    申请日:2003-07-14

    申请人: Roland Kratzer

    发明人: Roland Kratzer

    IPC分类号: B01J31/00

    摘要: The present invention relates to a process for preparing a catalyst solid for olefin polymerization which is obtainable by bringing A) at least one organic transition metal compound, B) at least one organometallic compound, C) at least one organic compound having at least one functional group containing active hydrogen, D) at least one Lewis base and E) at least one support, into contact with one another, wherein the components are combined in any order without any work-up of the mixtures present at intermediate stages being carried out. In addition, the invention relates to the use of the catalyst solid for olefin polymerization, to catalyst solids obtainable by this process, to catalyst systems in which these catalyst solids are present and to a process for the polymerization of olefins in which these catalyst solids are used.