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公开(公告)号：US5517356A
公开(公告)日：1996-05-14
申请号：US270052
申请日：1994-07-01
IPC分类号： C03B23/025 , C03B23/03 , C03C3/091 , C03C3/093 , C03C3/11 , C03C4/00 , C03C4/06 , C03C4/08 , C03C14/00 , C03C23/00 , G02B5/23 , G02B5/30 , C03C10/16 , G02B27/28
CPC分类号： C03B23/0256 , C03B23/03 , C03C14/006 , C03C23/007 , C03C3/091 , C03C3/11 , C03C4/065 , C03C4/085 , G02B5/23 , G02B5/3025
摘要： A glass article that is effective in polarizing radiation in the range of 400-700 nm and method of making, the glass having an R.sub.2 O--Al.sub.2 O.sub.3 --B.sub.2 O.sub.3 --SiO.sub.2 base glass composition, a precipitated crystal phase consisting of a halide selected from the group composed of cuprous, cadmium and mixed cuprous-cadmium halides, the crystals in the crystal phase being elongated, and a portion of the crystals near the surface of the article being at least partially reduced to colloidal copper, whereby the article exhibits permanent dichroic behavior and has a polarization efficiency across the entire wavelength range of 400-700 nm of at least 0.80.
摘要翻译： 对400-700nm范围内的偏振光有效的玻璃制品及其制造方法，具有R2O-Al2O3-B2O3-SiO2基玻璃组合物的玻璃，由选自组成的组中的卤化物组成的沉淀结晶相 的亚铜，镉和混合的锍 - 卤化镉，结晶相中的晶体是细长的，并且制品表面附近的晶体的一部分至少部分地还原成胶体铜，由此该制品具有永久的二色性，并具有 在400-700nm的整个波长范围内的极化效率至少为0.80。
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公开(公告)号：US5430573A
公开(公告)日：1995-07-04
申请号：US166833
申请日：1993-12-15
IPC分类号： C03B23/025 , C03B23/03 , C03C3/091 , C03C3/11 , C03C4/06 , C03C4/08 , C03C14/00 , C03C23/00 , G02B5/23 , G02B5/30 , G02B1/08 , C03B37/00
CPC分类号： C03B23/03 , C03B23/0256 , C03C14/006 , C03C23/007 , C03C3/091 , C03C3/11 , C03C4/065 , C03C4/085 , G02B5/23 , G02B5/3025 , Y10S501/905
摘要： A UV-absorbing, polarizing glass article and method of making, the glass having an R.sub.2 O-B.sub.2 O.sub.3 -SiO.sub.2 base glass composition, a sharp spectral cut-off at about 400 nm, a precipitated crystal phase consisting of a halide selected from the group composed of cuprous, cadmium and mixed cuprous-cadmium halides, the crystallites in the crystal phase being elongated, and a portion of the crystallites near the surface of the article being at least partially reduced to colloidal copper, whereby the article exhibits permanent dichroic behavior.
摘要翻译： UV吸收偏光玻璃制品及其制造方法，具有R2O-B2O3-SiO2基玻璃组合物的玻璃，约400nm处的尖锐光谱截止值，由选自组成的组中的卤化物组成的沉淀结晶相 的亚铜，镉和混合的铯 - 镉卤化物，结晶相中的微晶是细长的，并且制品表面附近的微晶的一部分至少部分地还原成胶体铜，由此该制品呈现永久的二色性。
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公开(公告)号：US5625427A
公开(公告)日：1997-04-29
申请号：US294636
申请日：1994-08-23
IPC分类号： G02C7/10 , C03B23/025 , C03B23/03 , C03C3/091 , C03C3/11 , C03C4/06 , C03C4/08 , C03C14/00 , C03C23/00 , G02B1/02 , G02B5/23 , G02B5/30 , G02C7/12 , G02C7/02 , C03C15/00
CPC分类号： C03B23/0307 , C03B23/0256 , C03B23/0302 , C03C14/006 , C03C23/007 , C03C3/091 , C03C3/11 , C03C4/065 , C03C4/085 , G02B5/23 , G02B5/3025
摘要： An ophthalmic lens of photochromic glass having an R.sub.2 O-Al.sub.2 O.sub.3 -B.sub.2 O.sub.3 -SiO.sub.2 base glass composition and a method of producing the lens. The lens contains precipitated cuprous halide crystals that are elongated and oriented, whereby the lens is capable of polarizing light when the lens is in the darkened state. If at least a portion of the crystals in at least a surface layer on the lens are reduced to copper metal, the lens exhibits a permanent dichroic behavior. The lens provides effective polarization of radiation across the entire visible wavelength region of the spectrum, has a sharp spectral cutoff for radiation below the 400 nm wavelength, thereby eliminating UV transmission, and has a transmittance not over about 40% in the darkened state.
摘要翻译： 具有R2O-Al2O3-B2O3-SiO2基玻璃组合物的光致变色玻璃的眼用透镜及其制造方法。 该透镜含有沉淀的卤化亚铜晶体，其被细长定向，从而当透镜处于黑暗状态时透镜能够使光线偏振。 如果透镜中的至少一个表面层中的至少一部分晶体被还原为铜金属，则该透镜具有永久的二色性。 透镜在光谱的整个可见光波长区域提供有效的辐射极化，对于400nm以下的辐射具有尖锐的光谱截止，从而消除紫外线透射，并且在变暗状态下透射率不超过约40％。
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公开(公告)号：US06403508B1
公开(公告)日：2002-06-11
申请号：US09583631
申请日：2000-05-31
申请人： Roger J. Araujo , Nicholas F. Borrelli , Robert E. McLay , Daniel R. Sempolinski , Charlene M. Smith
发明人： Roger J. Araujo , Nicholas F. Borrelli , Robert E. McLay , Daniel R. Sempolinski , Charlene M. Smith
IPC分类号： C03C306
CPC分类号： G03F7/70958 , C03B19/1407 , C03B19/1423 , C03B2201/21 , C03B2207/06 , C03B2207/20 , C03B2207/22 , C03B2207/32 , C03B2207/36 , C03B2207/50 , C03C3/06 , C03C2201/21 , C03C2203/40
摘要： An optical member includes a fused silica glass having a concentration of ≡SiH moiety below detection limit as measured by Raman spectroscopy and a concentration of molecular hydrogen of at least 1×1017 molecules/cm3. The fused silica glass exhibits an induced absorption level which quickly attains an initial peak upon exposure to irradiation and rapidly decays to a low value. The induced absorption level after decaying to the low value remains substantially unchanged by further irradiation.
摘要翻译： 光学构件包括通过拉曼光谱测量的浓度= SiH部分低于检测限的熔融石英玻璃，并且分子氢浓度至少为1×10 17分子/ cm 3。 熔融石英玻璃表现出诱导吸收水平，其在暴露于照射时快速达到初始峰值并迅速衰变至低值。 通过进一步照射，衰减至低值后的诱导吸收水平基本上保持不变。
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5.发明授权Method of forming high purity fused silica having high resistance to optical damage 失效形成高耐光损伤的高纯度熔融石英的方法
公开(公告)号：US5616159A
公开(公告)日：1997-04-01
申请号：US422104
申请日：1995-04-14
CPC分类号： C03C3/06 , C03B19/1453 , C03B2201/075 , C03B2201/21 , C03B2201/23 , C03B2207/32 , C03C2201/21 , C03C2201/23 , C03C2203/40 , C03C2203/54 , Y10S501/90 , Y10S501/905
摘要： High purity fused silica glass which is highly resistant to optical damage by ultraviolet radiation in the laser wavelength of about 300 nm or shorter is produced. In particular, a fused silica optical member or blank exhibits substantially no optical damage up to 10.sup.7 pulses (350 mJ/cm.sup.2) at the KrF laser wavelength region of about 248 nm, and at the ArF laser wavelength region of about 193 nm.
摘要翻译： 产生高纯度熔融石英玻璃，其在约300nm或更短的激光波长下通过紫外线辐射高度抵抗光学损伤。 特别地，熔融石英光学构件或坯料在约248nm的KrF激光波长区域和约193nm的ArF激光波长区域基本上不表现出至多107个脉冲（350mJ / cm 2）的光学损伤。
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公开(公告)号：US3981707A
公开(公告)日：1976-09-21
申请号：US570713
申请日：1975-04-23
IPC分类号： B29D11/00 , C03B37/012 , C03B37/027 , C03C3/089 , C03C3/091 , C03C23/00 , G02B6/028 , C03C25/02 , C03C15/00 , G02B5/14 , G02B21/34
CPC分类号： G02B6/0288 , B29D11/00682 , C03B37/01225 , C03B37/02754 , C03C23/00 , C03C3/089 , C03C3/091 , C03B2201/12 , C03B2201/14 , C03B2201/30 , C03B2201/32 , C03B2201/50 , C03B2203/22 , C03B2205/16 , Y10S65/16
摘要： A fluorine containing silicate glass substrate is heated to a temperature sufficiently high to permit fluorine to out-diffuse from the surface thereof. A surface region is formed having a gradient fluorine concentration in a direction perpendicular to the substrate surface, the region of lowest fluorine concentration having the highest refractive index. The resultant device is capable of functioning as an optical waveguide.
摘要翻译： 将含氟硅酸盐玻璃基板加热到足够高的温度以使氟从其表面扩散。 在垂直于衬底表面的方向，具有最高折射率的最低氟浓度的区域中形成具有梯度氟浓度的表面区域。 所得到的器件能够用作光波导。
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公开(公告)号：US5668067A
公开(公告)日：1997-09-16
申请号：US697094
申请日：1996-08-19
CPC分类号： C03C3/06 , C03B19/1453 , C03B2201/075 , C03B2201/21 , C03B2201/23 , C03B2207/32 , C03C2201/21 , C03C2201/23 , C03C2203/40 , C03C2203/54 , Y10S501/90 , Y10S501/905
摘要： The invention relates to the production of high purity fused silica glass which is highly resistant to optical damage by ultraviolet radiation in the laser wavelength of about 300 nm or shorter. In particular, this invention relates to a fused silica optical member or blank which exhibits substantially no optical damage up to 10.sup.7 pulses (350 mJ/cm.sup.2) at the KrF laser wavelength region of about 248 nm, and at the ArF laser wavelength region of about 193 nm.
摘要翻译： 本发明涉及高纯度熔融石英玻璃的生产，该玻璃在激光波长为约300nm或更短的范围内通过紫外线辐射具有很高的抗光损伤性。 特别地，本发明涉及一种在大约248nm的KrF激光波长区域和在大约248nm的ArF激光波长区域基本上不表现出高达107个脉冲（350mJ / cm 2）的光损伤的熔融石英光学部件或坯料 193nm。
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公开(公告)号：US4405672A
公开(公告)日：1983-09-20
申请号：US358351
申请日：1982-03-15
CPC分类号： C03C4/06 , C03C3/091 , Y10S428/913 , Y10T428/23 , Y10T428/24926 , Y10T428/26 , Y10T428/315
摘要： There is disclosed a composite photochromic glass article composed of a glass core and a thin surface layer substantially encasing that core, the core preferably containing a copper-cadmium halide photochromic crystal system and the substantially encasing glass layer preferably containing a copper-cadmium-silver halide photochromic crystal system. The article may be made by fusion laminating two separately formed glasses, or by introducing silver into a surface layer on a glass article by ion exchange.
摘要翻译： 公开了一种复合光致变色玻璃制品，其由玻璃芯和基本上包围该芯的薄表面层组成，该芯优选含有卤化镉 - 卤化物光致变色晶体系统，并且基本上包含玻璃层优选含有镉 - 卤化银 光致变色晶体系统。 制品可以通过熔融层压两个单独形成的玻璃，或者通过离子交换将银引入到玻璃制品上的表面层中。
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公开(公告)号：US5735921A
公开(公告)日：1998-04-07
申请号：US762513
申请日：1996-12-10
CPC分类号： C03B19/1453 , C03B19/1415 , C03C3/06 , C03B2201/02 , C03B2201/20 , C03B2207/32 , Y10S65/90
摘要： The invention relates to the production of high purity fused silica glass which is highly resistant to 248 nm excimer laser-induced optical damage. In particular, this invention relates to a fused silica optical member or blank.
摘要翻译： 本发明涉及高纯度熔融石英玻璃的生产，其高度抗248nm准分子激光诱导的光学损伤。 特别地，本发明涉及熔融硅石光学构件或坯料。
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公开(公告)号：US5212120A
公开(公告)日：1993-05-18
申请号：US900667
申请日：1992-06-19
摘要： A photosensitive borosilicate glass which consists essentially in calculated weight percent on an oxide basis of 20-80% SiO.sub.2, 8-40% B.sub.2 O.sub.3, 0-6% Li.sub.2, 0-28% Na.sub.2, 0-25% K.sub.2 O, the total Na.sub.2 O+K.sub.2 O being 10-28%, 0-18% Al.sub.2 O.sub.3 and minor amounts of photosensitizing agents silver, cerium oxide, antimony oxide and bromine and/or chlorine, the cation ratio of R.sub.2 O--Al.sub.2 O.sub.3 to B.sub.2 O.sub.3 being at least 0.6.
摘要翻译： 感光硼硅酸盐玻璃，其基本上以基于20-80％SiO 2，8-40％B 2 O 3，0-6％Li 2，0-28％Na 2，0-25％K 2 O的氧化物计算的重量百分比组成，总Na 2 O + K2O为10-28％，0-18％Al2O3和少量光敏剂银，氧化铈，氧化锑和溴和/或氯，R2O-Al2O3与B2O3的阳离子比至少为0.6。
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