公开(公告)号：US11326038B2

公开(公告)日：2022-05-10

申请号：US15772232

申请日：2016-12-06

Applicant: Rohm and Haas Company

Inventor： Nader N. Kamel ,  Debra A. Kline ,  Paul Nedwick

IPC: C09D201/00 ,  C08J9/36 ,  C08J9/30 ,  C08J9/28 ,  C08J9/00 ,  D06N3/00 ,  C08J7/04 ,  B05D3/12 ,  B05D3/00 ,  B05D1/00 ,  B05D3/02

Abstract: Provided is a process for producing a coating on a substrate comprising one or more steps of crushing a dried layer of a foamed aqueous coating composition, wherein the aqueous coating composition comprises a collection of multi-stage copolymer particles having a weight average diameter of 2-20 μm, wherein said multi-stage copolymer particles comprise a core having a glass transition temperature (Tg) of 20° C. or less. Also provided is a coated substrate made by that process.

公开(公告)号：US20150197659A1

公开(公告)日：2015-07-16

申请号：US14422594

申请日：2013-09-18

Applicant: Rohm and Haas Company

Inventor： Nader N. Kamel ,  Edward La Fleur ,  Partha S. Majumdar ,  Edwin Hugh Nungesser

IPC: C09D133/02

CPC classification number: C09D133/02 ,  C08F265/06 ,  C08F285/00 ,  C08L2201/10 ,  C08L2203/16 ,  C08L2205/03 ,  C08L2207/53 ,  C09D5/006 ,  C09D151/003 ,  C08L51/003 ,  C08F220/18 ,  C08F2220/1808

Abstract: Provided is an aqueous coating composition including: particular amounts of certain first solid polymeric particles having an average diameter of 0.60-0.99 μm; certain second solid polymeric particles having an average diameter of 2-20 μm, and mixtures thereof; and, third solid polymeric particles having a calculated Tg of from −60 C to 120° C. and an average particle diameter of from 50 nm to 500 nm; wherein the second solid polymeric particles have a K10 value of less than 1.9E+10 N/m2; wherein the difference between the refractive index of the outer surface of the second solid polymeric particles and the refractive index of the third solid polymeric particles is between 10E-4 to 10E-2; and wherein the aqueous coating composition comprises less than 10% by volume, inorganic extender particles. A method for providing a coating from the aqueous coating composition and a low glare coating so formed are also provided.

Abstract translation: 提供一种水性涂料组合物，其包含：特定量的某些第一固体聚合物颗粒，其平均直径为0.60-0.99μm; 某些平均直径为2-20μm的第二固体聚合物颗粒及其混合物; 以及计算出的Tg为-60℃至120℃，平均粒径为50nm至500nm的第三固体聚合物颗粒; 其中所述第二固体聚合物颗粒具有小于1.9E + 10N / m 2的K 10值; 其中所述第二固体聚合物颗粒的外表面的折射率与所述第三固体聚合物颗粒的折射率之间的差为10E-4至10E-2; 并且其中所述水性涂料组合物包含小于10体积％的无机增量剂颗粒。 还提供了一种从水性涂料组合物提供涂层和如此形成的低眩光涂层的方法。

公开(公告)号：US20180312724A1

公开(公告)日：2018-11-01

申请号：US15772232

申请日：2016-12-06

Applicant: Rohm and Haas Company

Inventor： Nader N. Kamel ,  Debra A. Kline ,  Paul Nedwick

IPC: C09D201/00 ,  C08J9/36 ,  C08J9/30 ,  C08J9/28 ,  C08J9/00 ,  D06N3/00

CPC classification number: C08J7/047 ,  C08J7/042 ,  C08J9/365 ,  C08J2433/06 ,  D06N3/0045 ,  D06N3/0063 ,  D06N2209/0853 ,  D06N2211/122

Abstract: Provided is a process for producing a coating on a substrate comprising one or more steps of crushing a dried layer of a foamed aqueous coating composition, wherein the aqueous coating composition comprises a collection of multi-stage copolymer particles having a weight average diameter of 2-20 μm, wherein said multi-stage copolymer particles comprise a core having a glass transition temperature (Tg) of 20° C. or less. Also provided is a coated substrate made by that process.

公开(公告)号：US09410053B2

公开(公告)日：2016-08-09

申请号：US14422594

申请日：2013-09-18

Applicant: Rohm and Haas Company

Inventor： Nader N. Kamel ,  Edward La Fleur ,  Partha S. Majumdar ,  Edwin Hugh Nungesser

IPC: C09D5/00 ,  C09D5/02 ,  C09D5/16 ,  C09D7/12 ,  C09D133/02 ,  C08F285/00 ,  C09D151/00 ,  C08F265/06

CPC classification number: C09D133/02 ,  C08F265/06 ,  C08F285/00 ,  C08L2201/10 ,  C08L2203/16 ,  C08L2205/03 ,  C08L2207/53 ,  C09D5/006 ,  C09D151/003 ,  C08L51/003 ,  C08F220/18 ,  C08F2220/1808

Abstract: Provided is an aqueous coating composition including: particular amounts of certain first solid polymeric particles having an average diameter of 0.60-0.99 μm; certain second solid polymeric particles having an average diameter of 2-20 μm, and mixtures thereof; and, third solid polymeric particles having a calculated Tg of from −60 C to 120° C. and an average particle diameter of from 50 nm to 500 nm; wherein the second solid polymeric particles have a K10 value of less than 1.9E+10 N/m2; wherein the difference between the refractive index of the outer surface of the second solid polymeric particles and the refractive index of the third solid polymeric particles is between 10E-4 to 10E-2; and wherein the aqueous coating composition comprises less than 10% by volume, inorganic extender particles. A method for providing a coating from the aqueous coating composition and a low glare coating so formed are also provided.

Abstract translation: 提供一种水性涂料组合物，其包含：特定量的某些第一固体聚合物颗粒，其平均直径为0.60-0.99μm; 某些平均直径为2-20μm的第二固体聚合物颗粒及其混合物; 以及计算出的Tg为-60℃至120℃，平均粒径为50nm至500nm的第三固体聚合物颗粒; 其中所述第二固体聚合物颗粒具有小于1.9E + 10N / m 2的K 10值; 其中所述第二固体聚合物颗粒的外表面的折射率与所述第三固体聚合物颗粒的折射率之间的差为10E-4至10E-2; 并且其中所述水性涂料组合物包含小于10体积％的无机增量剂颗粒。 还提供了一种从水性涂料组合物提供涂层和如此形成的低眩光涂层的方法。