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公开(公告)号：US4107419A
公开(公告)日：1978-08-15
申请号：US774289
申请日：1977-03-04
CPC分类号： C08F4/38
摘要： Organic peroxide polymerization co-initiator compositions and their use in the initiation of the polymerization of certain monomers and comonomers such as vinyl chloride, ethylene and methyl methacrylate. The co-initiator composition contains an alpha halo substituted diacyl peroxide and a coperoxide selected from t-alkyl peresters of t-hydroperoxides, peroxydicarbonates, acyl peroxycarbonic esters, and aliphatic diacyl peroxides. Typical is acetyl 2-chlorooctanoyl peroxide with t-butyl peroxy neodecanoate.
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2.发明授权Alpha halo substituted asymmetrical diacyl peroxides in co-initiator systems 失效在共引发剂体系中的α卤代取代的不对称二酰基过氧化物
公开(公告)号：US4102815A
公开(公告)日：1978-07-25
申请号：US739416
申请日：1976-11-08
CPC分类号： C08F4/38
摘要： Organic peroxide polymerization co-initiator compositions and their use in the initiation of the polymerization of certain monomers and comonomers such as vinyl chloride, ethylene and methyl methacrylate. The co-initiator composition contains an alpha halo substituted diacyl peroxide and a coperoxide selected from t-alkyl peresters of t-hydroperoxides, peroxydicarbonates, acyl peroxycarbonic esters, and aliphatic diacyl peroxides. Typical is acetyl 2-chlorooctanoyl peroxide with t-butyl peroxy neodecanoate.
摘要翻译： 有机过氧化物聚合共引发剂组合物及其在某些单体和共聚单体例如氯乙烯，乙烯和甲基丙烯酸甲酯的引发聚合中的用途。 共引发剂组合物含有α卤素取代的二酰基过氧化物和选自叔氢过氧化物，过氧化二碳酸酯，酰基过氧碳酸酯和脂族二酰基过氧化物的叔烷基过氧化物的共过氧化物。 典型的是乙酰基2-氯辛酰基过氧化物与叔丁基过氧化新癸酸酯。
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公开(公告)号：US3932372A
公开(公告)日：1976-01-13
申请号：US415877
申请日：1973-11-15
申请人： Roger N. Lewis , Ronald L. Friedman
发明人： Roger N. Lewis , Ronald L. Friedman
IPC分类号： C08F2/00 , C08F4/34 , C08F114/02 , C08F114/16
CPC分类号： C08F4/34
摘要： A co-initiator system for polymerization of ethylenically unsaturated monomers comprising a preformed nitrile containing azo compound or symmetrical, diacyl peroxide in combination with an in situ or preformed acyl peroxy alkyl carbonate.
摘要翻译： 用于烯键式不饱和单体聚合的共引发剂体系，其包含含有偶氮化合物或对称二酰基过氧化物的预先形成的腈与原位或预制的酰基过氧基烷基碳酸酯的组合。
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4.发明授权
公开(公告)号：US4151339A
公开(公告)日：1979-04-24
申请号：US520072
申请日：1974-11-01
申请人： Ronald L. Friedman , Roger N. Lewis
发明人： Ronald L. Friedman , Roger N. Lewis
IPC分类号： C08F14/06 , C08F4/38 , C08F4/36 , C08F114/06 , C08F218/08
CPC分类号： C08F14/06
摘要： A process for polymerizing vinyl chloride and for copolymerizing vinyl chloride and up to 30 percent by weight of comonomers in aqueous suspension under heat and pressure in the presence of a mixture of an acyl sulfonyl peroxide and a perester of the formula ##STR1## wherein R.sub.3, R.sub.4, and R.sub.5 are the same or different alkyl groups of from 1 to about 10 carbon atoms provided not more than one of R.sub.3, R.sub.4, and R.sub.5 is methyl, and R is selected from 2,2-dimethyl propyl and straight chain alkyl of 1-5 carbon atoms.
摘要翻译： 在酰基磺酰基过氧化物和式IMA的混合物存在下，在加热和压力下，在水悬浮液中聚合氯乙烯和共聚氯乙烯和高达30重量％的共聚单体的方法，其中R3， R 4和R 5是相同或不同的1至约10个碳原子的烷基，不超过一个R 3，R 4和R 5是甲基，R选自2,2-二甲基丙基和直链烷基 1-5个碳原子。
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5.发明授权Polymerization method and t-alkyl peresters of t-hydroperoxides for use therein 失效聚合方法和t-hydroperoxides的叔烷基过酸酯用于其中
公开(公告)号：US4057567A
公开(公告)日：1977-11-08
申请号：US333904
申请日：1973-02-20
申请人： Ronald L. Friedman , Roger N. Lewis
发明人： Ronald L. Friedman , Roger N. Lewis
IPC分类号： C07C409/38 , C08F4/32 , C07C179/18
CPC分类号： C07C409/38 , C08F4/32
摘要： Novel tertiary alkyl peresters of tertiary hydroperoxides are used as polymerization initiators wherein the peresters are characterized by the tertiary alkyl group of the acid moiety having at least two alkyl groups of two or more carbon atoms and the tertiary alkyl group of the hydroperoxide has at least five carbon atoms. Typical is the polymerization of certain vinyl monomers such as vinyl chloride.
摘要翻译： 使用叔氢过氧化物的新型叔烷基过酸酯作为聚合引发剂，其中过酸酯的特征在于酸部分的叔烷基具有至少两个具有两个或更多个碳原子的烷基，并且氢过氧化物的叔烷基具有至少五个 碳原子。 典型的是某些乙烯基单体如氯乙烯的聚合。
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6.发明授权T-Alkyl peresters of t-hydroperoxides catalysts for polymerization of unsaturated monomers 失效用于不饱和单体聚合的叔丁基过氧化氢催化剂的T型烷基酯
公开(公告)号：US4063013A
公开(公告)日：1977-12-13
申请号：US791819
申请日：1977-04-28
申请人： Ronald L. Friedman , Roger N. Lewis
发明人： Ronald L. Friedman , Roger N. Lewis
IPC分类号： C08F2/00 , C08F4/34 , C08F4/28 , C08F14/06 , C08F110/02
CPC分类号： C08F4/34
摘要： Novel tertiary alkyl peresters of tertiary hydroperoxides are used as polymerization initiators wherein the peresters are characterized by the tertiary alkyl group of the acid moiety having at least two alkyl groups of two or more carbon atoms and the tertiary alkyl group of the hydroperoxide has at least five carbon atoms. Typical is the polymerization of certain vinyl monomers such as vinyl chloride.
摘要翻译： 使用叔氢过氧化物的新型叔烷基过酸酯作为聚合引发剂，其中过酸酯的特征在于酸部分的叔烷基具有至少两个具有两个或更多个碳原子的烷基，并且氢过氧化物的叔烷基具有至少五个 碳原子。 典型的是某些乙烯基单体如氯乙烯的聚合。
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公开(公告)号：US4271279A
公开(公告)日：1981-06-02
申请号：US688874
申请日：1976-05-21
IPC分类号： C07D323/00 , C08K5/159 , C08F8/06
CPC分类号： C07D323/00 , C08K5/159
摘要： High density polyethylene is cross-linked with certain cyclic perketals including a group of novel cyclic perketals. Typical of the novel molecules is 3,6,6,9,9-pentamethyl-3-ethylacetate-1,2,4,5-tetraoxy cyclononane.
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8.发明授权Process for crosslinking thermoplastic polymers and crosslinking system used therein 失效用于交联热塑性聚合物和交联体系的方法
公开(公告)号：US5856412A
公开(公告)日：1999-01-05
申请号：US850334
申请日：1997-05-02
申请人： Lawrence A. Bock , Roger N. Lewis
发明人： Lawrence A. Bock , Roger N. Lewis
IPC分类号： C08J3/24 , C07C409/00 , C08F8/00 , C08L23/30 , C08F8/06
CPC分类号： C08F8/00
摘要： A crosslinking system which includes a 1,2,4-trioxacycloheptane and a crosslink-promoting polyfunctional ethylenically unsaturated compound. This system is employed in a process of crosslinking a thermoplastic polymer. Preferred polymers, useful in this process, include ethylene homopolymers and copolymers.
摘要翻译： 交联体系，其包括1,2,4-三氧杂环庚烷和交联促进多官能烯属不饱和化合物。 该系统用于交联热塑性聚合物的方法。 在该方法中有用的优选聚合物包括乙烯均聚物和共聚物。
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公开(公告)号：US4279831A
公开(公告)日：1981-07-21
申请号：US65410
申请日：1979-08-10
申请人： Reidar Halle , David Peterson , Roger N. Lewis
发明人： Reidar Halle , David Peterson , Roger N. Lewis
IPC分类号： C07C409/34 , C08F4/34 , C07C179/14
CPC分类号： C08F4/34 , C07C409/34
摘要： Dialkyl diacyl peroxides in which the alpha carbon atom of one of the alkyl groups is secondary and substituted by chloro and alkyl. The compounds are useful as polymerization initiators of ethylenically unsaturated monomers such as vinyl chloride.
摘要翻译： 二烷基二酰基过氧化物，其中一个烷基的α碳原子是仲的并被氯和烷基取代。 该化合物可用作烯属不饱和单体如氯乙烯的聚合引发剂。
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公开(公告)号：US4069239A
公开(公告)日：1978-01-17
申请号：US774833
申请日：1977-03-07
IPC分类号： C08F4/00 , C07C67/00 , C07C407/00 , C07C409/32 , C07C409/34 , C08F2/00 , C08F2/50 , C08F4/28 , C08F4/34 , C08F299/04 , C08K5/14 , C07C69/96 , C07C71/00
CPC分类号： C08K5/14 , C08F299/045 , C08F4/34
摘要： Acyl peroxycarbonic esters of the formula ##STR1## in which R is methyl or ethyl, R' is alkyl, and R and R' together have 17 or more carbon atoms. The compounds have unusual thermal stability, together with improved polymerization initiating efficiency. Particularly outstanding efficiency is found in connection with the polymerization of methyl methacrylate.
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