公开(公告)号：US5331063A

公开(公告)日：1994-07-19

申请号：US968082

申请日：1992-10-27

申请人： Ruth H. Pater ,  Norman J. Johnston

发明人： Ruth H. Pater ,  Norman J. Johnston

IPC分类号： C08G73/10 ,  C08L79/08 ,  C08J5/08 ,  C08K3/04

CPC分类号： C08G73/1082 ,  C08G73/101 ,  C08G73/1064 ,  C08L79/08 ,  Y10S525/903

摘要： This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit. ##STR1## wherein Z=C or SO.sub.2. Provided is an improved high temperature matrix resin which is capable of performing in the 200.degree. to 300.degree. C. range. This resin has significantly improved toughness and microcracking resistance, excellent processability, mechanical performance and moisture and solvent resistances.

摘要翻译： 本发明是一种半互穿聚合物网络，其包括具有作为交联部位的纳蒂端基的高性能热固性聚酰亚胺和具有以下重复单元的高性能线性热塑性聚酰亚胺。 其中Z = C或SO2。 提供一种改进的高温基质树脂，其能够在200℃至300℃的范围内进行。 该树脂具有显着提高的韧性和抗微裂纹性，优异的加工性能，机械性能和耐湿性和耐溶剂性。

公开(公告)号：US5159029A

公开(公告)日：1992-10-27

申请号：US429514

申请日：1989-10-31

申请人： Ruth H. Pater ,  Norman J. Johnston

发明人： Ruth H. Pater ,  Norman J. Johnston

IPC分类号： C08G73/10 ,  C08L79/08

CPC分类号： C08G73/1082 ,  C08G73/101 ,  C08G73/1064 ,  C08L79/08 ,  Y10S525/903

摘要： This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit. ##STR1## wherein Z=C or SO.sub.2. Provided is an improved high temperature matrix resin which is capable of performing in the 200.degree. to 300.degree. C. range. This resin has significantly improved toughness and microcracking resistance, excellent processability, mechanical performance and moisture and solvent resistances.

摘要翻译： 本发明是一种半互穿聚合物网络，其包括具有作为交联部位的纳蒂端基的高性能热固性聚酰亚胺和具有以下重复单元的高性能线性热塑性聚酰亚胺。 ＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;其中Z = C或SO 2。 提供一种改进的高温基质树脂，其能够在200℃至300℃的范围内进行。 该树脂具有显着提高的韧性和抗微裂纹性，优异的加工性能，机械性能和耐湿性和耐溶剂性。

公开(公告)号：US08545986B2

公开(公告)日：2013-10-01

申请号：US12043276

申请日：2008-03-06

申请人： Ruth H. Pater

发明人： Ruth H. Pater

IPC分类号： B32B17/10 ,  B32B15/08 ,  H01B17/32 ,  H05K9/00

CPC分类号： H01B3/306 ,  Y10T428/31623 ,  Y10T428/31663 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A composite conductor includes a conductor that has a high temperature polyimide insulation formed around it. This polyimide layer may include reinforcing fibers such as, for instance, glass fibers. The insulation layer may further include grading layers. The conductor is placed inside an earth layer. The composite conductor may be protected with a stainless steel enclosure.

摘要翻译： 复合导体包括在其周围形成有高温聚酰亚胺绝缘体的导体。 该聚酰亚胺层可以包括增强纤维，例如玻璃纤维。 绝缘层还可以包括分级层。 导体放置在地层内。 复合导体可以用不锈钢外壳保护。

公开(公告)号：US4624727A

公开(公告)日：1986-11-25

申请号：US766628

申请日：1985-08-19

申请人： Daniel A. Scola ,  Ruth H. Pater

发明人： Daniel A. Scola ,  Ruth H. Pater

IPC分类号： C08G73/10 ,  C09J3/14 ,  C09J3/16

CPC分类号： C08G73/1039

摘要： A low temperature processable, thermoplastic polyimide and methods for making and using the same. The polyimide has repeating polymer units of the formula ##STR1## wherein n is 2 to about 20 and the molecular weight of the polymer chain is about 5,000 to about 50,000. The polymer is made by reacting 4,4'-(hexafluoroisopropylidene)bis(o-phthalic anhydride) with a diamine having the formula H.sub.2 N(CH.sub.2).sub.n NH.sub.2 wherein n is 2 to about 20 to form a polyamic acid. The polyamic acid is imidized to form the polyimide described above. The polyimide is particularly adapted to use as a hot melt adhesive by placing it between two articles and applying heat and pressure.

摘要翻译： 低温可加工的热塑性聚酰亚胺及其制造和使用方法。 聚酰亚胺具有下式的重复聚合物单元，其中n为2至约20，聚合物链的分子量为约5,000至约50,000。 该聚合物通过使4,4' - （六氟异亚丙基）双（邻苯二甲酸酐）与具有式H2N（CH2）nNH2的二胺反应制得，其中n为2至约20以形成聚酰胺酸。 将聚酰胺酸酰亚胺化以形成上述聚酰亚胺。 聚酰亚胺特别适用于将其置于两个制品之间并施加热和压力作为热熔粘合剂。

公开(公告)号：US5648432A

公开(公告)日：1997-07-15

申请号：US473605

申请日：1995-06-07

申请人： Ruth H. Pater ,  Marion G. Hansen

发明人： Ruth H. Pater ,  Marion G. Hansen

IPC分类号： C08G73/10 ,  C08G73/12 ,  C08L79/08 ,  C09J179/08 ,  C08F283/04

CPC分类号： C08L79/08 ,  C08G73/101 ,  C08G73/1064 ,  C08G73/12 ,  C08G73/126 ,  C08J5/24 ,  C08L79/085 ,  C09J179/08 ,  C09J179/085 ,  C08J2379/08 ,  Y10S525/903 ,  Y10S526/935 ,  Y10T428/31504

摘要： In the process of the present invention, a non-polar, aprotic solvent is removed from an oligomer/polymer solution by freeze-drying in order to produce IPNs and semi-IPNs. By thermally quenching the solution to a solid in a short length of time, the size of the minor constituent-rich regions is greatly reduced as they are excluded along with the major constituent from the regions of crystallizing solvent. The use of this process sequence of controlling phase morphology provides IPNs and semi-IPNs with improved fracture toughness, microcracking resistance, and other physical-mechanical properties as compared to IPNs and semi-IPNs formed when the solvent is evaporated rather than sublimed.

摘要翻译： 在本发明的方法中，通过冷冻干燥从低聚物/聚合物溶液中除去非极性的非质子溶剂，以便产生IPN和半IPN。 通过在短时间内将溶液热淬火成固体，随着与结晶溶剂区域的主要成分一起排除，少量组分富集区域的尺寸大大降低。 与溶剂蒸发而不是升华时形成的IPN和半IPN相比，使用这种控制相形态的工艺顺序提供了具有改进的断裂韧性，显微裂纹性和其它物理机械性能的IPN和半IPN。

公开(公告)号：US5306784A

公开(公告)日：1994-04-26

申请号：US831763

申请日：1992-01-31

申请人： Ruth H. Pater

发明人： Ruth H. Pater

IPC分类号： C08G73/10 ,  C08J5/08 ,  C08G73/00

CPC分类号： C08G73/101 ,  C08G73/1039 ,  C08G73/1067 ,  Y10S525/903 ,  Y10T428/31721

摘要： A high temperature semi-interpenetrating polymer network (semi-IPN) was developed which had significantly improved processability, damage tolerance and mechanical performance, when compared to the commercial Thermid.RTM. materials. This simultaneous semi-IPN was prepared by mixing the monomer precursors of Thermid.RTM. AL-600 (a thermoset) and NR-150B2 (a thermoplastic) and allowing the monomers to react randomly upon heating. This reaction occurs at a rate which decreases the flow and broadens the processing window. Upon heating at a higher temperature, there is an increase in flow. Because of the improved flow properties, broadened processing window and enhanced toughness, high strength polymer matrix composites, adhesives and molded articles can now be prepared from the acetylene end-capped polyimides which were previously inherently brittle and difficult to process.

摘要翻译： 与商业Thermid（商标）材料相比，开发了高温半互穿聚合物网络（semi-IPN），其具有显着改善的加工性能，耐损伤性和机械性能。 通过混合Thermid（商标）AL-600（热固性）的单体前体和NR-150B2（热塑性））并使单体在加热时随机反应来制备该同时半IPN。 该反应以降低流动并扩大加工窗口的速率发生。 在较高温度下加热时，流量增加。 由于改进的流动性能，现在可以由以前固有地脆性且难以加工的乙炔封端的聚酰亚胺来制备加宽窗口和增强的韧性，高强度聚合物基质复合材料，粘合剂和模塑制品。

公开(公告)号：US5149746A

公开(公告)日：1992-09-22

申请号：US665371

申请日：1991-03-06

申请人： Ruth H. Pater

发明人： Ruth H. Pater

IPC分类号： C08G73/10 ,  C08L79/08

CPC分类号： C08G73/1007 ,  C08G73/1039 ,  C08L79/08 ,  Y10S525/903

摘要： This invention is a process for making a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit: ##STR1## Provided is an improved high temperature matrix resin which is capable of performing at 316.degree. C. in air for several hundreds of hours. This resin has significantly improved toughness and microcracking resistance, excellent processability and mechanical performance, and cost effectiveness.

摘要翻译： 本发明是一种制备半互穿聚合物网络的方法，其包括具有作为交联部位的纳米端基的高性能热固性聚酰亚胺和具有以下重复单元的高性能线性热塑性聚酰亚胺：提供了一种改进的 能在316℃下在空气中进行数百小时的高温基体树脂。 该树脂具有显着提高的韧性和抗微裂纹性，优异的加工性能和机械性能，以及成本效益。

公开(公告)号：US5589182A

公开(公告)日：1996-12-31

申请号：US161350

申请日：1993-12-06

申请人： Renki Tashiro ,  Ruth H. Pater

发明人： Renki Tashiro ,  Ruth H. Pater

IPC分类号： A61K9/08 ,  A61K9/14 ,  A61K9/20 ,  A61K9/48 ,  A61K36/074 ,  A61K36/076 ,  A61K36/14 ,  A61K36/232 ,  A61K36/258 ,  A61K36/287 ,  A61K36/344 ,  A61K36/346 ,  A61K36/484 ,  A61K36/488 ,  A61K36/537 ,  A61K36/69 ,  A61K36/718 ,  A61K36/725 ,  A61K36/756 ,  A61K36/79 ,  A61K36/804 ,  A61K36/808 ,  A61K36/8965 ,  A61K36/8968 ,  A61K35/78

CPC分类号： A61K36/484 ,  A61K36/074 ,  A61K36/076 ,  A61K36/14 ,  A61K36/232 ,  A61K36/258 ,  A61K36/287 ,  A61K36/344 ,  A61K36/346 ,  A61K36/488 ,  A61K36/537 ,  A61K36/69 ,  A61K36/718 ,  A61K36/725 ,  A61K36/756 ,  A61K36/79 ,  A61K36/804 ,  A61K36/808 ,  A61K36/8965 ,  A61K36/8968 ,  Y10S514/824 ,  Y10S514/879

摘要： A pharmaceutical composition suitable for the treatment of a condition selected from the group consisting of cardiovascular disease, cerebrovascular disease, Alzheimer's disease, depression or combinations thereof comprising various mixtures of the aqueous extracts of tissue of specific Chinese plants and herbs. A method of preparing the pharmaceutical compositions of the invention and a method for treating a patient therewith are also disclosed.

摘要翻译： 一种适用于治疗选自心血管疾病，脑血管疾病，阿尔茨海默氏病，抑郁症或其组合的病症的药物组合物，其包含特定中国植物和草药组织的水性提取物的各种混合物。 还公开了制备本发明的药物组合物的方法和用于治疗患者的方法。

公开(公告)号：US5338806A

公开(公告)日：1994-08-16

申请号：US829792

申请日：1992-01-31

申请人： Ruth H. Pater

发明人： Ruth H. Pater

IPC分类号： C08G73/10 ,  C08J5/08 ,  C08K3/04

CPC分类号： C08G73/1067 ,  C08G73/101 ,  C08G73/1039 ,  Y10S525/903

摘要： A high temperature semi-interpenetrating polymer network (semi-IPN) was developed which had significantly improved processability, damage tolerance and mechanical performance, when compared to the commercial Thermid.RTM. materials. This simultaneous semi-IPN was prepared by mixing a thermosetting polyimide with a thermoplastic monomer precursor solution (NR-150B2) and allowing them to react upon heating. This reaction occurs at a rate which decreases the flow and broadens the processing window. Upon heating at a higher temperature, there is an increase in flow. Because of the improved flow properties, broadened processing window and enhanced toughness, high strength polymer matrix composites, adhesives and molded articles can now be prepared from the acetylene endcapped polyimides which were previously inherently brittle and difficult to process.

摘要翻译： 与商业Thermid TM材料相比，开发了高温半互穿聚合物网络（semi-IPN），其具有显着改善的加工性，耐损伤性和机械性能。 通过将热固性聚酰亚胺与热塑性单体前体溶液（NR-150B2）混合并使其在加热下反应来制备该同时半IPN。 该反应以降低流动并扩大加工窗口的速率发生。 在较高温度下加热时，流量增加。 由于改进的流动性能，现在可以由之前固有地易于脆化并难以加工的乙炔封端的聚酰亚胺来制备加工窗口和增强的韧性，高强度聚合物基质复合材料，粘合剂和模塑制品。

公开(公告)号：US5098961A

公开(公告)日：1992-03-24

申请号：US301925

申请日：1989-01-26

申请人： Ruth H. Pater

发明人： Ruth H. Pater

IPC分类号： C08G73/10 ,  C08L79/08

CPC分类号： C08G73/1007 ,  C08G73/1039 ,  C08L79/08 ,  Y10S525/903

摘要： This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit: ##STR1## Provided is an improved high temperature matrix resin which is capable of performing at 316.degree. C. in air for several hundreds of hours. This resin has significantly improved toughness and microcracking resistance, excellent processability and mechanical performance, and cost effectiveness.

摘要翻译： 本发明是一种半互穿聚合物网络，其包括具有作为交联部位的纳米端基的高性能热固性聚酰亚胺和具有以下重复单元的高性能线性热塑性聚酰亚胺：提供改进的高温基质树脂 其能够在316℃下在空气中进行几百小时。 该树脂具有显着提高的韧性和抗微裂纹性，优异的加工性能和机械性能，以及成本效益。