公开(公告)号：US11066354B2

公开(公告)日：2021-07-20

申请号：US16621767

申请日：2018-06-11

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Prashant Sukumar Shinge ,  Jaiprakash Brijlal Sainani

IPC: C07C213/08 ,  C07C215/76

Abstract: The invention relates to a process for the preparation of a compound represented by formula (I) wherein X is selected from the group consisting of —H, -halogen, linear or branched C1-C7 alkyl group, linear or branched C1-C5 alkoxy group, —NO2 and —CN and Y is a linear or branched C1-C7 alkyl group, comprising the steps of: 10 a) reacting a compound represented by formula (II) with a compound represented by (III) to obtain an intermediate product, wherein X is as defined with respect to formula (I), wherein Z is H, CH3 or C2H5, b) reacting the intermediate product of step a) with a compound represented by Y2SO4 (IV) wherein Y is as defined with respect to formula (I) to obtain a salt and c) hydrolyzing the salt of step b) to obtain the compound of formula (I).

公开(公告)号：US09815917B2

公开(公告)日：2017-11-14

申请号：US14912631

申请日：2014-08-29

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nedumbamana Sankaran ,  Prashant Sukumar Shinge ,  Sharankumar Shetty ,  Girish Chandra ,  Haif Al-Shammari ,  Abdulaziz Hamad Al-Humydi ,  Edward Joseph Nesakumar ,  Pradeep Jeevaji Nadkarni

IPC: C07F17/00 ,  C08F4/6592 ,  C08F110/02 ,  C07F7/00 ,  C08F4/659

CPC classification number: C08F110/02 ,  C07F7/00 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

Abstract: The invention relates to a metallocene complex according to formula (1) wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, Z1, Z2, Z3 and Z4 are identical or different and can be chosen from the group consisting of hydrogen and a hydrocarbon radical with 1-20 carbon atoms, and adjacent substituents Z can form a ring system together with the carbon atoms of the Cp ring to which they are bound.

公开(公告)号：US20180273661A1

公开(公告)日：2018-09-27

申请号：US15762157

申请日：2016-09-22

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Osamah Al-Humaidan ,  Sudhakar R. Padmanabhan ,  Prashant Sukumar Shinge ,  Sharankumar G. Shetty ,  Abbas-Alli Ghudubhai Shaikh

IPC: C08F110/06 ,  C07C231/14 ,  C07C233/75

CPC classification number: C08F110/06 ,  C07C231/14 ,  C07C233/75 ,  C07C233/88 ,  C08F4/6565 ,  C08F2500/15 ,  C08F2500/18 ,  C08F4/651

Abstract: The present invention relates to a compound according to Formula (I) wherein R1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R3, R4, R5 and R6, are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R2 is a hydrogen atom or an alkyl group; wherein R3, R4, R5 and R6, are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R1—C(═O)Cl] with a compound according to Formula (III) to obtain the compound according to Formula (I) and to the use of these compounds as internal donor in Ziegler-Natta catalysis of olefins.

公开(公告)号：US09868797B2

公开(公告)日：2018-01-16

申请号：US14907923

申请日：2014-07-29

Applicant: SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Nedumbamana Sankaran ,  Prashant Sukumar Shinge ,  Sharankumar Shetty ,  Girish Chandra ,  Haif Al-Shammari ,  Abdulaziz Hamad Al-Humydi ,  Edward Joseph Nesakumar

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/76 ,  C07C211/48 ,  C07F5/02 ,  C07C211/52 ,  C08F10/02 ,  C08F4/659

CPC classification number: C08F4/76 ,  C07C211/48 ,  C07C211/52 ,  C07C2602/08 ,  C07F5/02 ,  C07F5/025 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F10/02 ,  C08F2420/02

Abstract: A metallocene complex according to formula 1 wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5, or 6, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, X is a cyclic bridging group that is bonded to a carbon atom of the cyclopentadienyl ligand and to nitrogen, Z1, and Z4 are hydrogen or a hydrocarbon radical with 1-20 carbon atoms; adjacent substituents Z2 and Z3 and are connected to form an indenyl or tetrahydroindenyl ring system and R is hydrogen or a hydrocarbon radical with 1-20 carbon atoms. Also described is a composition comprising the metallocene complex, a process for the preparation of the complex, and a process for the polymerization of olefin polymers in the presence of the metallocene complex.