公开(公告)号：US12037313B2

公开(公告)日：2024-07-16

申请号：US17292261

申请日：2019-11-20

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Guillermo Leal ,  Mohammed Bismillah Ansari

IPC: C07C41/06 ,  C07C4/02 ,  C07C5/05 ,  C07C5/32 ,  C07C5/42 ,  C07C6/04 ,  C07C7/04 ,  C07C29/04

CPC classification number: C07C41/06 ,  C07C4/02 ,  C07C5/05 ,  C07C5/32 ,  C07C5/42 ,  C07C7/04 ,  C07C29/04 ,  C07C6/04 ,  C07C7/04 ,  C07C9/10 ,  C07C7/04 ,  C07C9/12 ,  C07C5/05 ,  C07C11/08 ,  C07C41/06 ,  C07C43/046 ,  C07C29/04 ,  C07C31/12 ,  C07C7/04 ,  C07C11/08 ,  C07C5/32 ,  C07C11/04 ,  C07C5/32 ,  C07C11/09 ,  C07C5/42 ,  C07C11/09 ,  C07C4/02 ,  C07C11/04

Abstract: A process for producing ethylene and at least one of butanol and an alkyl tert-butyl ether from field butane includes separating the field butane into an n-butane stream and an isobutane stream; cracking the n-butane stream to obtain a cracked product stream comprising n-butane, 1-butene, 2-butene, butadienes, or a combination comprising at least one of the foregoing; and at least one of the following: (1) separating the cracked product stream to obtain a butane stream and a butene stream, and reacting the butene stream with water to obtain a fuel additive comprising butanol, and (2) dehydrogenating the isobutane stream in a dehydrogenation unit to form an isobutene stream and reacting the isobutene stream with an aliphatic alcohol to produce an alkyl tert-butyl ether.

公开(公告)号：US11161796B2

公开(公告)日：2021-11-02

申请号：US17264430

申请日：2019-09-16

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Mohammed A. Al-Ghamdi ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/00 ,  C07C7/00 ,  C07C29/04 ,  C07C5/05 ,  C07C7/04

Abstract: A method for the production of a fuel additive includes passing a hydrocarbon stream comprising crude mixed C4 hydrocarbons through a first hydrogenation unit to produce a first product stream; passing the first product stream from the first hydrogenation unit to a methyl tert-butyl ether synthesis unit forming methyl tert-butyl ether and a byproduct stream; passing the byproduct stream through a first distillation unit to separate the byproduct stream into a first 1-butene stream, an isobutane stream, and a 2-butene and n-butane stream; forming a second product stream by passing the 2-butene and n-butane stream to a selective conversion unit; passing the second product stream into a second distillation unit to form an n-butane stream and a second 1-butene stream; passing the second 1-butene stream to a fuel additive production unit; and passing the first 1-butene stream to the fuel additive production unit to form the fuel additive.

公开(公告)号：US20210171848A1

公开(公告)日：2021-06-10

申请号：US17052407

申请日：2019-04-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Hiren Shethna ,  Mohammed Bismillah Ansari ,  Zhonglin Zhang

IPC: C10L1/185 ,  C07C41/06 ,  C07C5/05 ,  C07C29/04 ,  C07C5/03 ,  C07C4/04 ,  C10L10/10 ,  C10L1/182

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a methyl tertiary butyl ether unit producing a first process stream; passing the first process stream through a selective butadiene hydrogenation unit transforming greater than or equal to 90% by weight of the butadiene to 1-butene and 2-butene, preferably greater than or equal to 93%, preferably, greater than or equal to 94%, more preferably, greater than or equal to 95% producing a second process stream; passing the second process stream through a hydration unit producing a third process stream and the fuel additive; passing the third process stream through a total hydrogenation unit producing a hydrogenated stream; and passing the hydrogenated stream to a cracker unit.

公开(公告)号：US10829706B2

公开(公告)日：2020-11-10

申请号：US16631100

申请日：2018-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C07C41/56 ,  C10L10/12 ,  B01J39/20

Abstract: A method of manufacturing a cetane-boosting fuel additive includes reacting formaldehyde and 2-ethylhexanol at a mole ratio of 10:1 to 1:1, or 5:1 to 1.5:1, or 4:1 to 2:1, or 3.5:1 to 2.5:1 in the presence of a heterogeneous acid catalyst at a temperature of 300 to 375° K to obtain a cetane-boosting product mixture comprising H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOH, H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOCH2CH(CH2CH3)(CH2)3CH3, or a combination thereof, wherein n has an average value of 2.8 to 3.2, preferably an average value of 3.

公开(公告)号：US20200157444A1

公开(公告)日：2020-05-21

申请号：US16631100

申请日：2018-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C10L10/12 ,  C07C41/56

Abstract: A method of manufacturing a cetane-boosting fuel additive includes reacting formaldehyde and 2-ethylhexanol at a mole ratio of 10:1 to 1:1, or 5:1 to 1.5:1, or 4:1 to 2:1, or 3.5:1 to 2.5:1 in the presence of a heterogeneous acid catalyst at a temperature of 300 to 375° K to obtain a cetane-boosting product mixture comprising H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOH, H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOCH2CH(CH2CH3)(CH2)3CH3, or a combination thereof, wherein n has an average value of 2.8 to 3.2, preferably an average value of 3.

公开(公告)号：US11427518B2

公开(公告)日：2022-08-30

申请号：US16981183

申请日：2019-03-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Mohammed Bismillah Ansari ,  Kareemuddin Mahaboob Shaik ,  Hiren Shethna ,  Zhonglin Zhang

IPC: C07C4/04 ,  C07C5/03 ,  C07C5/05 ,  C07C29/04 ,  C10L1/16 ,  C10L1/182 ,  C10L10/10

Abstract: A method of producing a fuel additive includes producing a first product stream comprising butadiene by passing a feed stream comprising C4 hydrocarbons through a steam cracker; transforming greater than or equal to 90 weight % of the butadiene in the first product stream into a second product stream by passing the first product stream through a first hydrogenation unit, wherein the second product stream comprises 1-butene, 2-butene, n-butane, isobutylene, isobutane, or a combination thereof; and converting the second product stream into the fuel additive by passing the second product stream through a fuel additive synthesis unit with an acid catalyst.

公开(公告)号：US11414611B2

公开(公告)日：2022-08-16

申请号：US17052407

申请日：2019-04-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Hiren Shethna ,  Mohammed Bismillah Ansari ,  Zhonglin Zhang

IPC: C10L1/185 ,  C07C4/04 ,  C07C5/03 ,  C07C5/05 ,  C10L1/182 ,  C10L10/10 ,  C07C29/04 ,  C07C41/06

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a methyl tertiary butyl ether unit producing a first process stream; passing the first process stream through a selective butadiene hydrogenation unit transforming greater than or equal to 90% by weight of the butadiene to 1-butene and 2-butene, preferably greater than or equal to 93%, preferably, greater than or equal to 94%, more preferably, greater than or equal to 95% producing a second process stream; passing the second process stream through a hydration unit producing a third process stream and the fuel additive; passing the third process stream through a total hydrogenation unit producing a hydrogenated stream; and passing the hydrogenated stream to a cracker unit.

公开(公告)号：US11358916B2

公开(公告)日：2022-06-14

申请号：US17047001

申请日：2019-04-23

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Al-Otaibe ,  Guillermo Leal ,  Mohammed Bismillah Ansari

IPC: C07C4/04 ,  B01D3/14 ,  C07C5/27 ,  C07C7/00 ,  C07C7/04

Abstract: Described is a process for producing field butane. The process includes increasing the n-butane concentration in field butane. The process may include a concentration process that includes distillation and a thermal cracking process.

公开(公告)号：US11124470B2

公开(公告)日：2021-09-21

申请号：US16496511

申请日：2018-03-29

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas

IPC: C07C41/06 ,  C07C5/05 ,  C07C6/00 ,  C07C6/04 ,  C07C7/04 ,  C07C7/163 ,  C07C11/06 ,  C07C43/04

Abstract: A method of producing methyl tertiary butyl ether (MTBE) and propylene is disclosed. The method involves the use of a crude C4 stream and the integration of a MTBE synthesis process and a cracking process. The method may include processing a byproduct stream from an MTBE synthesis unit to produce high purity olefin streams for an olefins conversion technology unit.

公开(公告)号：US20210155862A1

公开(公告)日：2021-05-27

申请号：US17045669

申请日：2019-04-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Kareemuddin Mahaboob Shaik ,  Hiren Shethna ,  Zhonglin Zhang

IPC: C10L1/185 ,  C10L1/182 ,  C07C29/04 ,  C07C5/05 ,  C10G65/12 ,  C10L10/10 ,  C10G69/04

Abstract: A method of producing a fuel additive includes: passing a first process stream comprising C4 hydrocarbons through a methyl tertiary butyl ether synthesis unit producing a first recycle stream; passing the first recycle stream through a hydration unit producing the fuel additive and a second recycle stream; passing the second recycle stream through a recycle hydrogenation unit and a deisobutanizer unit; and recycling the second recycle stream to the methyl tertiary butyl ether synthesis unit.