公开(公告)号：US20050279255A1

公开(公告)日：2005-12-22

申请号：US10533428

申请日：2003-10-21

申请人： Tadashi Suzuki ,  Osamu Funayama ,  Andreas Dierdorf ,  Hubert Liebe

发明人： Tadashi Suzuki ,  Osamu Funayama ,  Andreas Dierdorf ,  Hubert Liebe

IPC分类号： A61K6/087 ,  A61K6/093 ,  C04B41/49 ,  C04B41/50 ,  C04B41/87 ,  C08K3/00 ,  C08K5/00 ,  C09D183/16

CPC分类号： C04B41/009 ,  C04B41/5035 ,  C04B41/87 ,  C08G77/62 ,  C09D183/16 ,  C04B41/4554 ,  C04B33/00 ,  C04B14/308 ,  C08K5/098 ,  C08K5/3445

摘要： A coating solution comprising 0.1 to 35% by weight of an inorganic or organic polysilazane having repeating units represented by the general formula below and soluble in a solvent and 0.1 to 10% by weight of catalyst such as 4,4′-trimethylenebis(1-methylpiperidine) based on a pure polysilazane content. By applying the coating solution onto the surface of base materials such as metals, plastics, glass, ceramic, wood, cement, mortar, bricks, etc., a silica coating strongly adhered to the base materials can be formed excellent in corrosion resistance and anti-scratch properties and simultaneously excellent in characteristics such as abrasion resistant, long-lasting anti-fouling properties, wetting properties to water, sealing properties, chemical resistance, oxidation resistance, physical barrier effect, heat resistance, fire resistance and antistatic properties.

摘要翻译： 包含0.1至35重量％的具有由以下通式表示的并且可溶于溶剂的重复单元的无机或有机聚硅氮烷和0.1至10重量％的催化剂如4,4'-三亚甲基双（1- 基于纯聚硅氮烷含量的甲基哌啶）。 通过将涂布溶液涂布在诸如金属，塑料，玻璃，陶瓷，木材，水泥，砂浆，砖等基材的表面上，可以形成强烈粘合到基材上的二氧化硅涂层，其耐腐蚀性和抗反射性优异 同时优异的耐磨性，持久的防污性能，对水的润湿性能，密封性能，耐化学性，抗氧化性，物理屏障效应，耐热性，耐火性和抗静电性等特性。

公开(公告)号：US08309228B2

公开(公告)日：2012-11-13

申请号：US11991718

申请日：2006-08-25

申请人： Andreas Dierdorf ,  Stefan Brand ,  Andreas Wacker ,  Hubert Liebe

发明人： Andreas Dierdorf ,  Stefan Brand ,  Andreas Wacker ,  Hubert Liebe

IPC分类号： B32B15/04 ,  B05D3/02 ,  C08L83/04

CPC分类号： C09D183/16 ,  C08G77/62 ,  Y10T428/25 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31667 ,  C08K5/17 ,  C08K5/09 ,  C08K5/098

摘要： The invention relates to the use of polysilazanes as a permanent coating on metal and polymer surfaces for preventing corrosion, increasing scratch resistance and to facilitate easier cleaning. The invention comprises a solution of a polysilazane or a blend of polysilazanes of the general formula 1 —(SiR′R″—NR′″)n—  (1) where R′, R″ and R′″ are identical or different and independently of one another represent hydrogen or an optionally substituted alkyl, aryl, vinyl or (trialkoxysilyl)alkyl group and n represents a whole number and is calculated in such a way that the polysilazane has a numerical average molecular weight of 150 to 150 000 g/mol, in a solvent. The invention also relates to a method for producing the coating.

摘要翻译： 本发明涉及聚硅氮烷作为永久性涂层在金属和聚合物表面上的用途，以防止腐蚀，增加耐刮擦性和便于清洗。 本发明包括聚硅氮烷或通式1-（SiR'R“-NR”“）n - （1）的聚硅氮烷的共混物，其中R'，R”和R“”相同或不同且独立地 彼此表示氢或任选取代的烷基，芳基，乙烯基或（三烷氧基甲硅烷基）烷基，n表示整数，并且以这样的方式计算，即聚硅氮烷的数均分子量为150至150000g / mol ，在溶剂中。 本发明还涉及一种生产该涂层的方法。

公开(公告)号：US20080014461A1

公开(公告)日：2008-01-17

申请号：US11667654

申请日：2005-10-25

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

IPC分类号： C09D183/16 ,  C04B35/589 ,  C23C18/12 ,  C08G77/62

CPC分类号： C23C18/1241 ,  C08G77/62 ,  C09D183/16 ,  C23C18/122 ,  C23C18/14 ,  Y10T428/12569 ,  Y10T428/12681 ,  Y10T428/12736

摘要： A coating for metals containing a polysilazane solution or a mixture of polysilazanes of general formula (1) —(SiR′R″—NR″)n— (1) wherein R′, R″, R″′ are identical or different and independently represent hydrogen or an optionally substituted alkyl-, aryl-, vinyl or (trialkoxysilyl)alkyl radical, wherein n is a whole number and n is dimensioned in such a way that polysilazane has an average molecular weight of 150-150,000 g/mol, in a solvent and at least one catalyst. The invention also relates to a method for the production of the coating.

摘要翻译： 含有聚硅氮烷溶液或通式（1） - （SiR'R“-NR”'） - （1）的聚硅氮烷的混合物的金属涂层，其中R'，R“ R“'相同或不同，并且独立地表示氢或任选取代的烷基 - ，芳基 - ，乙烯基或（三烷氧基甲硅烷基）烷基，其中n是整数，并且n的尺寸设计使聚硅氮烷具有平均值 分子量为150-150,000g / mol，在溶剂和至少一种催化剂中。 本发明还涉及一种生产该涂层的方法。

公开(公告)号：US08247037B2

公开(公告)日：2012-08-21

申请号：US11667654

申请日：2005-10-25

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

IPC分类号： B05D3/02

CPC分类号： C23C18/1241 ,  C08G77/62 ,  C09D183/16 ,  C23C18/122 ,  C23C18/14 ,  Y10T428/12569 ,  Y10T428/12681 ,  Y10T428/12736

摘要： A coating for metals containing a polysilazane solution or a mixture of polysilazanes of the general formula (I) —(SiR′R″-NR′″)n—  (1) wherein R′, R″ and R′″ are identical or different and independently represent hydrogen or an optionally substituted alkyl, aryl, vinyl or (trialkoxysilyl)alkyl radical, wherein n is a whole number and n is dimensioned in such a way that the polysilazane has a number-average molecular weight of 150 to 150 000 g/mol, in a solvent and at least one catalyst. The invention also relates to a method for the production of the coating.

摘要翻译： 含有聚硅氮烷溶液或通式（I） - （SiR'R“-NR”“）n - （1）的聚硅氮烷的混合物的金属涂层，其中R'，R”和R“”相同或不同 并且独立地表示氢或任选取代的烷基，芳基，乙烯基或（三烷氧基甲硅烷基）烷基，其中n是整数，n的尺寸使得聚硅氮烷的数均分子量为150〜150000g / mol，在溶剂和至少一种催化剂中。 本发明还涉及一种生产该涂层的方法。

公开(公告)号：US20080118651A1

公开(公告)日：2008-05-22

申请号：US11883153

申请日：2006-01-12

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

IPC分类号： B05D1/36

CPC分类号： C09D183/16

摘要： A method used to produce a permanent support layer on precious metal surfaces by coating solutions which are based on polysilazane. Said method is used to coat surfaces made of precious metal or precious metal alloys with a solution containing a polysilazane of formula (I), wherein n is measured in such a manner that the polysilazane has an average molecular weight from 150-150,000 g/mol, in addition to a solvent and a catalyst. The invention is characterized in that a silane based primer which contains sulphur and which is used to improve adherence, is applied to the object which is to be coated prior to the coating with the polysilazane solution. The invention also relates to coatings which are produced according to the inventive method.

摘要翻译： 一种用于通过涂覆基于聚硅氮烷的溶液在贵金属表面上产生永久性支撑层的方法。 所述方法用于用含有式（I）聚硅氮烷的溶液涂覆由贵金属或贵金属合金制成的表面，其中n以聚硅氮烷的平均分子量为150-150,000g / mol ，除了溶剂和催化剂。 本发明的特征在于，在用聚硅氮烷溶液涂布之前，将含有硫并用于改善粘附性的硅烷基底漆施加到待涂布的物体上。 本发明还涉及根据本发明方法生产的涂层。

公开(公告)号：US20080131706A1

公开(公告)日：2008-06-05

申请号：US11884856

申请日：2006-02-10

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

IPC分类号： B32B15/04 ,  C08G77/62

CPC分类号： C09D183/16 ,  C08L83/16 ,  C09D7/65

摘要： The invention relates to the use of polysilazanes as permanent coatings on metal surfaces for the prevention of the susceptibility to fingerprints, characterized in that the polysilazane is in the form of a solution of a polysilazane or a mixture of polysilazanes of the general formula 1 —(SiR′R″—NR′″)n—   (1) where R′, R″, R′″ independently=H, optionally-substituted alkyl-, aryl, vinyl- or (trialkoxysilyl)alkyl, n=a whole number such that the polysilazane has a number-average molecular weight of from 150 to 150,000 g/mol in a solvent. The invention further relates to a method for production of the coating.

摘要翻译： 本发明涉及聚硅氮烷作为金属表面上的永久涂层用于防止指纹敏感性的用途，其特征在于聚硅氮烷为聚硅氮烷或通式1的聚硅氮烷混合物的形式， in-line-formula description =“In-line Formulas”end =“lead”？> - （SiR'R“ - NR”'） - （1） 其中R'，R“，R”独立地为H，任选取代的烷基 - ，芳基，乙烯基 - 或（三烷氧基甲硅烷基）烷基，n为整数 =整数，使得聚硅氮烷在溶剂中的数均分子量为150〜150,000g / mol。 本发明还涉及一种生产该涂层的方法。

公开(公告)号：US20070196672A1

公开(公告)日：2007-08-23

申请号：US10591573

申请日：2005-02-22

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Andreas Wacker

IPC分类号： B32B27/00 ,  B05D3/02 ,  C08L83/00 ,  C08G77/00

CPC分类号： C09D183/16 ,  Y10T428/31663

摘要： The invention relates to a surface coating comprising at least one type of perhydropolysilazane of the formula I wherein n is an integer of a value such that the perhydropolysilazane number-average molecular weight of from 150 to 150 000 g/mol, a solvent and a catalyst and, possibly one or more cobinding agents. The hardened coating has thickness of at least 1 micrometer, preferably ranging from 2 to 20 micrometers. The inventive coating containing at least one type of perhydropolysilazane is suitable for protecting rims, in particular, aluminum rims.

摘要翻译： 本发明涉及包含至少一种式I的全氢聚硅氮烷的表面涂层，其中n是一个整数，使得全氢聚硅氮烷的数均分子量为150-150,000g / mol，溶剂和催化剂 以及可能的一种或多种助磨剂。 硬化涂层的厚度至少为1微米，优选为2至20微米。 含有至少一种类型的全氢聚硅氮烷的本发明的涂层适用于保护边缘，特别是铝边缘。

公开(公告)号：US08470924B2

公开(公告)日：2013-06-25

申请号：US12600050

申请日：2008-05-15

申请人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Frank Osterod ,  Markus Mahn ,  Ken Ryan

发明人： Stefan Brand ,  Andreas Dierdorf ,  Hubert Liebe ,  Frank Osterod ,  Markus Mahn ,  Ken Ryan

IPC分类号： C08L83/16

CPC分类号： C09D183/16 ,  C08L83/16

摘要： The present invention is directed to a color-pigmented paint composition with high hiding power, comprising a solvent or a solvent mixture and a.) based on the total formulation, 1% to 80% by weight of a polysilazane of the formula (1) —(SiR′R″—NR′″)n−  (1) and b.) based on the total formulation 1% to 15% by weight, particularly 2% to 8% by weight, of one or more pigments wherein R′, R″, and R″′ are alike or different and independently of one another are hydrogen or an unsubstituted or substituted alkyl, aryl, vinyl or (trialkoxysilyl)alkyl radical, n being an integer and n having a magnitude such that the polysilazane has a number average molecular weight of 150 to 150 000 g/mol.

摘要翻译： 本发明涉及一种具有高遮盖力的着色颜料漆组合物，其包含溶剂或溶剂混合物，和a。基于总配方，1重量％至80重量％的式（1）聚硅氮烷， - （SiR'R“ - NR”'）n-（1）和b。），基于总配方1％至15％重量，特别是2％至8％重量的一种或多种颜料，其中 R'，R“和R”'是相同或不同的，彼此独立地是氢或未取代或取代的烷基，芳基，乙烯基或（三烷氧基甲硅烷基）烷基，n是整数，n的大小等于 聚硅氮烷的数均分子量为150〜150000g / mol。

公开(公告)号：US08057858B2

公开(公告)日：2011-11-15

申请号：US12084191

申请日：2006-10-13

申请人： Andreas Dierdorf ,  Stefan Brand ,  Hubert Liebe ,  Frank Osterod ,  Oliver Eich ,  Mark Jozefowicz

发明人： Andreas Dierdorf ,  Stefan Brand ,  Hubert Liebe ,  Frank Osterod ,  Oliver Eich ,  Mark Jozefowicz

IPC分类号： B05D3/02

CPC分类号： C25D11/24 ,  C09D183/16

摘要： A method for producing corrosion-resistant, painted oxide layers on aluminum or aluminum alloys. According to the method, a polysilazane solution is applied to a dry oxide layer that is painted with a water-soluble, anionic color, and the coating is then hardened at a temperature ranging from 40 to 150° C.

摘要翻译： 一种在铝或铝合金上生产耐腐蚀，涂漆的氧化物层的方法。 根据该方法，将聚硅氮烷溶液施加到涂有水溶性阴离子颜色的干燥氧化物层上，然后将涂层在40-150℃的温度下硬化。

公开(公告)号：US20090286086A1

公开(公告)日：2009-11-19

申请号：US11991718

申请日：2006-08-25

申请人： Andreas Dierdorf ,  Stefan Brand ,  Andreas Wacker ,  Hubert Liebe

发明人： Andreas Dierdorf ,  Stefan Brand ,  Andreas Wacker ,  Hubert Liebe

IPC分类号： B32B9/04 ,  C08L83/04 ,  B05D3/02 ,  B32B15/04 ,  B32B27/36 ,  B32B27/38

CPC分类号： C09D183/16 ,  C08G77/62 ,  Y10T428/25 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31667 ,  C08K5/17 ,  C08K5/09 ,  C08K5/098

摘要： The invention relates to the use of polysilazanes as a permanent coating on metal and polymer surfaces for preventing corrosion, increasing scratch resistance and to facilitate easier cleaning. The invention comprises a solution of a polysilazane or a blend of polysilazanes of the general formula 1 —(SiR′R″—NR′″)n—  (1) where R′, R″ and R′″ are identical or different and independently of one another represent hydrogen or an optionally substituted alkyl, aryl, vinyl or (trialkoxysilyl)alkyl group and n represents a whole number and is calculated in such a way that the polysilazane has a numerical average molecular weight of 150 to 150 000 g/mol, in a solvent. The invention also relates to a method for producing the coating.

摘要翻译： 本发明涉及聚硅氮烷作为永久性涂层在金属和聚合物表面上的用途，以防止腐蚀，增加耐刮擦性和便于清洗。 本发明包括聚硅氮烷或通式1-（SiR'R“-NR”'）n - （1）的聚硅氮烷的混合物，其中R'，R“和R”'相同 或不同且彼此独立地表示氢或任选取代的烷基，芳基，乙烯基或（三烷氧基甲硅烷基）烷基，n表示整数，并且以这样的方式计算，使得聚硅氮烷的数均分子量为150至150 000g / mol。 本发明还涉及一种生产该涂层的方法。