公开(公告)号：US20110071318A1

公开(公告)日：2011-03-24

申请号：US12994599

申请日：2008-10-24

申请人： Tatsuya Tsujiuchi ,  Shinya Tachibana ,  Tsuyoshi Oishi ,  Tomio Mimura ,  Yasuyuki Yagi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

发明人： Tatsuya Tsujiuchi ,  Shinya Tachibana ,  Tsuyoshi Oishi ,  Tomio Mimura ,  Yasuyuki Yagi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

IPC分类号： C07C213/04 ,  B01J19/00

CPC分类号： C07C213/10 ,  C07C213/04 ,  C07C215/08

摘要： A reaction column (12) to which a raw material mixture (11) containing a mono-lower-alkylamine (AA: raw material I) and an alkylene oxide (AO: raw material II) is supplied, an unreacted raw material distillation column (14) that separates an unreacted raw material (15) from a reaction product (13a) (containing the unreacted raw material (15), a target reaction product (monomer) (17), and a by-product (dimer) (18)), and a flash drum (16) to which a reaction product (13b) (containing the target reaction product (monomer) (17) and the by-product (dimer) (18)) is supplied, the flash drum (16) separating a mono-lower-alkyl monoalkanolamine (monomer, the target reaction product 17) in a gas state, are provided.

摘要翻译： 将供给含有单低级烷基胺（AA：原料I）和环氧烷（AO：原料II））的原料混合物（11）的反应塔（12），未反应原料蒸馏塔 14），将未反应的原料（15）与反应产物（13a）（含有未反应的原料（15）），目标反应产物（单体）（17）和副产物（二聚体）（18）分离， ）和提供有反应产物（13b）（含有目标反应产物（单体）（17）和副产物（二聚体）（18））的闪蒸筒），闪蒸鼓（16） 分离出气态下的单低级烷基单烷醇胺（单体，目标反应产物17）。

公开(公告)号：US08415502B2

公开(公告)日：2013-04-09

申请号：US12994599

申请日：2008-10-24

申请人： Tatsuya Tsujiuchi ,  Shinya Tachibana ,  Tsuyoshi Oishi ,  Tomio Mimura ,  Yasuyuki Yagi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

发明人： Tatsuya Tsujiuchi ,  Shinya Tachibana ,  Tsuyoshi Oishi ,  Tomio Mimura ,  Yasuyuki Yagi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

IPC分类号： C07C213/04

CPC分类号： C07C213/10 ,  C07C213/04 ,  C07C215/08

摘要： A reaction column (12) to which a raw material mixture (11) containing a mono-lower-alkylamine (AA: raw material I) and an alkylene oxide (AO: raw material II) is supplied, an unreacted raw material distillation column (14) that separates an unreacted raw material (15) from a reaction product (13a) (containing the unreacted raw material (15), a target reaction product (monomer) (17), and a by-product (dimer) (18)), and a flash drum (16) to which a reaction product (13b) (containing the target reaction product (monomer) (17) and the by-product (dimer) (18)) is supplied, the flash drum (16) separating a mono-lower-alkyl monoalkanolamine (monomer, the target reaction product 17) in a gas state, are provided.

摘要翻译： 将供给含有单低级烷基胺（AA：原料I）和环氧烷（AO：原料II））的原料混合物（11）的反应塔（12），未反应原料蒸馏塔 14），将未反应的原料（15）与反应产物（13a）（含有未反应的原料（15）），目标反应产物（单体）（17）和副产物（二聚体）（18）分离， ）和提供有反应产物（13b）（含有目标反应产物（单体）（17）和副产物（二聚体）（18））的闪蒸筒），闪蒸鼓（16） 分离出气态下的单低级烷基单烷醇胺（单体，目标反应产物17）。

公开(公告)号：US07977513B2

公开(公告)日：2011-07-12

申请号：US12438025

申请日：2007-08-06

申请人： Shinya Tachibana ,  Ryuji Yoshiyama ,  Tsuyoshi Oishi ,  Mikiya Sakurai ,  Kazuo Ishida ,  Tatsuya Tsujiuchi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

发明人： Shinya Tachibana ,  Ryuji Yoshiyama ,  Tsuyoshi Oishi ,  Mikiya Sakurai ,  Kazuo Ishida ,  Tatsuya Tsujiuchi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

IPC分类号： C07C213/00 ,  C07C213/04

CPC分类号： C07C213/04 ,  C07C213/10 ,  C07C215/08

摘要： An amine producing apparatus includes a reactor that reacts a mono-lower-alkylamine and an alkylene oxide, an unreacted-raw-material-recovery distillation column that separates unreacted raw materials by distillation from a product including unreacted raw materials obtained in the reactor, a non-aqueous distillation column that removes water and a light component by a distillation method from a reactive product from which unreacted raw material have been separated, and a purification and distillation column that separates by distillation a desired reactive product (mono-lower-alkylmonoalkanolamine) and residue (mono-lower-alkyldialkanolamine which is a dimer) from a reactive product from which the water and the light component have been removed.

摘要翻译： 胺生产装置包括使单低级烷基胺和环氧烷反应的反应器，通过蒸馏将未反应原料与包含反应器中得到的未反应原料的产物分离的未反应原料回收蒸馏塔， 通过蒸馏法从未反应的原料分离出的反应性产物中除去水和轻质成分的非水蒸馏塔和通过蒸馏分离所需的反应性产物（单低级烷基单链烷醇胺）的纯化和蒸馏塔， 和去除水和轻组分的反应产物的残基（单 - 低级 - 烷基二烷醇胺，其是二聚体）。

公开(公告)号：US20100249463A1

公开(公告)日：2010-09-30

申请号：US12438025

申请日：2007-08-06

申请人： Shinya Tachibana ,  Ryuji Yoshiyama ,  Tsuyoshi Oishi ,  Mikiya Sakurai ,  Kazuo Ishida ,  Tatsuya Tsujiuchi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

发明人： Shinya Tachibana ,  Ryuji Yoshiyama ,  Tsuyoshi Oishi ,  Mikiya Sakurai ,  Kazuo Ishida ,  Tatsuya Tsujiuchi ,  Hidehisa Mita ,  Ryosuke Araki ,  Kenji Saito

IPC分类号： C07C215/08 ,  B01J8/00

CPC分类号： C07C213/04 ,  C07C213/10 ,  C07C215/08

摘要： An amine producing apparatus includes a reactor that reacts a mono-lower-alkylamine and an alkylene oxide, an unreacted-raw-material-recovery distillation column that separates unreacted raw materials by distillation from a product including unreacted raw materials obtained in the reactor, a non-aqueous distillation column that removes water and a light component by a distillation method from a reactive product from which unreacted raw material have been separated, and a purification and distillation column that separates by distillation a desired reactive product (mono-lower-alkylmonoalkanolamine) and residue (mono-lower-alkyldialkanolamine which is a dimer) from a reactive product from which the water and the light component have been removed.

摘要翻译： 胺生产装置包括使单低级烷基胺和环氧烷反应的反应器，通过蒸馏将未反应原料与包含反应器中得到的未反应原料的产物分离的未反应原料回收蒸馏塔， 通过蒸馏法从未反应的原料分离出的反应性产物中除去水和轻质成分的非水蒸馏塔和通过蒸馏分离所需的反应性产物（单低级烷基单链烷醇胺）的纯化和蒸馏塔， 和去除水和轻组分的反应产物的残基（单 - 低级 - 烷基二烷醇胺，其是二聚体）。

公开(公告)号：US20140150653A1

公开(公告)日：2014-06-05

申请号：US14235636

申请日：2012-09-10

申请人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： B01D53/14

CPC分类号： B01D53/1418 ,  B01D53/1425 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/204 ,  B01D2252/20478 ,  B01D2258/0283 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

摘要： The CO2 recovery apparatus is provided with a CO2 absorption portion for absorbing CO2 in a CO2-containing exhaust gas by a CO2 absorbing liquid, a water washing portion provided on the upper portion side of the CO2 absorption portion so as to cool a CO2-removed exhaust gas and also recover the accompanying CO2 absorbing liquid, a washing liquid circulation line for directly circulating a washing liquid containing the CO2 absorbing liquid recovered in the water washing portion, an extraction line for extracting part of the washing liquid containing the CO2 absorbing liquid as an extracted liquid from the washing liquid circulation line, a concentration portion for separating a gas component (water vapor) from the extracted liquid while concentrating the CO2 absorbing liquid, and a concentrated liquid feed line for feeding a concentrated liquid concentrated in the concentration portion to the side of an absorbing liquid regeneration tower.

摘要翻译： 二氧化碳回收装置设置有CO 2吸收部分，用于通过CO 2吸收液体吸收含CO 2排气中的CO 2，设置在CO 2吸收部分的上部侧的水洗部分，以冷却CO 2去除 废气，还回收伴随的CO 2吸收液体，用于使含有在水洗部中回收的CO 2吸收液的洗涤液直接循环的洗涤液循环管线，将含有CO 2吸收液的洗涤液的一部分提取的提取线作为 来自洗涤液循环管线的提取液，浓缩CO 2吸收液的浓缩部分，用于从浓缩CO 2吸收液中分离出气体成分（水蒸汽）与浓缩液的浓缩液;以及浓缩液体供给管线， 吸收液体再生塔的一侧。

公开(公告)号：US09383101B2

公开(公告)日：2016-07-05

申请号：US13580469

申请日：2011-01-11

申请人： Tatsuya Tsujiuchi ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Keiji Fujikawa ,  Tetsuya Imai ,  Hiroshi Tanaka ,  Tsuyoshi Oishi ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Tatsuya Tsujiuchi ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Keiji Fujikawa ,  Tetsuya Imai ,  Hiroshi Tanaka ,  Tsuyoshi Oishi ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： F23J15/04 ,  F23J15/00 ,  F23L15/04 ,  B01D53/14 ,  F23L7/00 ,  F23J15/06

CPC分类号： B01D53/1425 ,  B01D53/1475 ,  B01D2252/204 ,  B01D2257/302 ,  B01D2258/0283 ,  F23G2207/104 ,  F23J15/006 ,  F23J15/04 ,  F23J15/06 ,  F23J2215/20 ,  F23J2219/40 ,  F23L7/002 ,  F23L15/04 ,  Y02A50/2342 ,  Y02C10/06 ,  Y02E20/326 ,  Y02E20/348

摘要： A CO2 recovery unit includes an absorber that reduces CO2 in flue gas (101) discharged from a combustion facility (50) by absorbing CO2 by an absorbent, a regenerator that heats the absorbent having absorbed CO2 to emit CO2, and regenerates and supplies the absorbent to the absorber, and a regenerating heater that uses steam (106) supplied from the combustion facility (50) for heating the absorbent in the regenerator and returns heated condensed water (106a) to the combustion facility (50). The CO2 recovery unit further includes a condensed water/flue gas heat exchanger (57) that heats the condensed water (106a) to be returned from the regenerating heater to the combustion facility (50) by heat-exchanging the condensed water (106a) with the flue gas (101) in a flue gas duct (51) in the combustion facility (50).

摘要翻译： CO 2回收单元包括吸收器，其通过吸收剂吸收CO 2而减少从燃烧设备（50）排出的烟道气（101）中的CO 2;再生器，其加热吸收了CO 2的吸收剂以排放CO 2，并再生并供应吸收剂 以及再生加热器，其使用从燃烧设备（50）供应的蒸汽（106）来加热再生器中的吸收剂并将加热的冷凝水（106a）返回到燃烧设备（50）。 CO 2回收单元还包括冷凝水/烟道气热交换器（57），其通过将冷凝水（106a）与所述冷凝水（106a）进行热交换来加热从再生加热器返回到燃烧设备（50）的冷凝水（106a） 燃烧设备（50）中烟道气（51）中的烟气（101）。

公开(公告)号：US09421491B2

公开(公告)日：2016-08-23

申请号：US14235636

申请日：2012-09-10

申请人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： B01D53/14 ,  B01D53/62

CPC分类号： B01D53/1418 ,  B01D53/1425 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/204 ,  B01D2252/20478 ,  B01D2258/0283 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

摘要： The CO2 recovery apparatus is provided with a CO2 absorption portion for absorbing CO2 in a CO2-containing exhaust gas by a CO2 absorbing liquid, a water washing portion provided on the upper portion side of the CO2 absorption portion so as to cool a CO2-removed exhaust gas and also recover the accompanying CO2 absorbing liquid, a washing liquid circulation line for directly circulating a washing liquid containing the CO2 absorbing liquid recovered in the water washing portion, an extraction line for extracting part of the washing liquid containing the CO2 absorbing liquid as an extracted liquid from the washing liquid circulation line, a concentration portion for separating a gas component (water vapor) from the extracted liquid while concentrating the CO2 absorbing liquid, and a concentrated liquid feed line for feeding a concentrated liquid concentrated in the concentration portion to the side of an absorbing liquid regeneration tower.

摘要翻译： 二氧化碳回收装置设置有CO 2吸收部分，用于通过CO 2吸收液体吸收含CO 2排气中的CO 2，设置在CO 2吸收部分的上部侧的水洗部分，以冷却CO 2去除 废气，还回收伴随的CO 2吸收液体，用于使含有在水洗部中回收的CO 2吸收液的洗涤液直接循环的洗涤液循环管线，将含有CO 2吸收液的洗涤液的一部分提取的提取线作为 来自洗涤液循环管线的提取液，浓缩CO 2吸收液的浓缩部分，用于从浓缩CO 2吸收液中分离出气体成分（水蒸汽）与浓缩液的浓缩液;以及浓缩液体供给管线， 吸收液体再生塔的一侧。

公开(公告)号：US20140245888A1

公开(公告)日：2014-09-04

申请号：US14236294

申请日：2012-09-10

申请人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Tatsuya Tsujiuchi ,  Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： B01D53/14

CPC分类号： B01D53/1425 ,  B01D53/1412 ,  B01D53/1418 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/204 ,  B01D2258/0283 ,  Y02C10/04 ,  Y02C10/06

摘要： A CO2 recovery apparatus provided with a CO2 absorption tower for making a purified exhaust gas and an absorbing liquid regeneration tower for regenerating a CO2 absorbing liquid by separating CO2 from the CO2 absorbing liquid, in which a lean solution removed of CO2 in the absorbing liquid regeneration tower is reused in the CO2 absorption tower, a cooling tower for cooling the CO2-containing exhaust gas containing CO2 is provided on the upstream flow side of the CO2 absorption tower so as to set a temperature (T2) of the purified exhaust gas exhausted from the CO2 absorption tower lower than a temperature (T1) of the CO2-containing exhaust gas containing CO2 cooled in the cooling tower (T1>T2), and a condensed water made by condensing water vapor discharged from the absorbing liquid regeneration tower is evaporated in an evaporation portion.

摘要翻译： 一种二氧化碳回收装置，其具有用于制造净化废气的二氧化碳吸收塔和用于通过从吸收液体再生中分离出二氧化碳的二氧化碳吸收液分离二氧化碳来再生二氧化碳吸收液体的吸收液体再生塔 在二氧化碳吸收塔中重新使用塔，在CO 2吸收塔的上游侧设置用于冷却含CO 2废气的冷却塔，以设定从CO 2吸收塔排出的净化废气的温度（T2） CO 2吸收塔低于在冷却塔（T1> T2）中冷却的含有CO 2的废气的温度（T1），并且通过冷凝从吸收液体再生塔排出的水蒸气而制成的冷凝水蒸发 蒸发部。

公开(公告)号：US20140013945A1

公开(公告)日：2014-01-16

申请号：US14005970

申请日：2012-05-10

申请人： Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tatsuya Tsujiuchi ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Hiroshi Tanaka ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Tatsuya Tsujiuchi ,  Tsuyoshi Oishi ,  Takashi Kamijo ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： C01B31/20

CPC分类号： C01B32/50 ,  B01D53/1418 ,  B01D53/1475 ,  B01D2258/0283 ,  Y02C10/04 ,  Y02C10/06 ,  Y02P20/152

摘要： A CO2 recovery device includes: a CO2 absorption unit for absorbing CO2 in a CO2-containing flue gas, by a CO2 absorbent; a washing unit for cooling a CO2-removed flue gas and recovering the accompanying CO2 absorbent; a circulation line for directly circulating wash water; an extraction line for extracting a part of the wash water containing the CO2 absorbent as an extracted fluid; a first gas-liquid separation unit for separating a gas component from the extracted fluid; a concentration unit for concentrating the CO2 absorbent contained in the extracted fluid and separating the gas component; a concentrated fluid return line through which a concentrated fluid returns to the CO2 absorption unit provided below the washing unit; and a gas inlet line through which the separated gas component is introduced into an absorber.

摘要翻译： CO 2回收装置包括：CO 2吸收单元，用于通过CO 2吸收剂吸收含CO 2的烟道气中的CO 2; 洗涤单元，用于冷却除去CO 2的烟气并回收伴随的CO 2吸收剂; 用于直接循环洗涤水的循环管线; 提取管线，用于提取含有CO 2吸收剂的洗涤水的一部分作为提取液; 第一气液分离单元，用于从提取的流体中分离出气体成分; 用于浓缩包含在所提取的流体中的CO 2吸收剂并分离气体组分的浓缩单元; 浓缩流体返回管线，浓缩流体通过该浓缩流体返回到设置在洗涤单元下方的CO 2吸收单元; 以及气体入口管线，通过该气体入口管线将分离的气体成分引入吸收器。

公开(公告)号：US20120318141A1

公开(公告)日：2012-12-20

申请号：US13580469

申请日：2011-01-11

申请人： Tatsuya Tsujiuchi ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Keiji Fujikawa ,  Tetsuya Imai ,  Hiroshi Tanaka ,  Tsuyoshi Oishi ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

发明人： Tatsuya Tsujiuchi ,  Hiromitsu Nagayasu ,  Takuya Hirata ,  Keiji Fujikawa ,  Tetsuya Imai ,  Hiroshi Tanaka ,  Tsuyoshi Oishi ,  Masahiko Tatsumi ,  Yasuyuki Yagi ,  Kazuhiko Kaibara

IPC分类号： B01D53/14 ,  B01D19/00

CPC分类号： B01D53/1425 ,  B01D53/1475 ,  B01D2252/204 ,  B01D2257/302 ,  B01D2258/0283 ,  F23G2207/104 ,  F23J15/006 ,  F23J15/04 ,  F23J15/06 ,  F23J2215/20 ,  F23J2219/40 ,  F23L7/002 ,  F23L15/04 ,  Y02A50/2342 ,  Y02C10/06 ,  Y02E20/326 ,  Y02E20/348

摘要： A CO2 recovery unit includes an absorber that reduces CO2 in flue gas (101) discharged from a combustion facility (50) by absorbing CO2 by an absorbent, a regenerator that heats the absorbent having absorbed CO2 to emit CO2, and regenerates and supplies the absorbent to the absorber, and a regenerating heater that uses steam (106) supplied from the combustion facility (50) for heating the absorbent in the regenerator and returns heated condensed water (106a) to the combustion facility (50). The CO2 recovery unit further includes a condensed water/flue gas heat exchanger (57) that heats the condensed water (106a) to be returned from the regenerating heater to the combustion facility (50) by heat-exchanging the condensed water (106a) with the flue gas (101) in a flue gas duct (51) in the combustion facility (50).

摘要翻译： CO 2回收单元包括吸收器，其通过吸收剂吸收CO 2而减少从燃烧设备（50）排出的烟道气（101）中的CO 2;再生器，其加热吸收了CO 2的吸收剂以排放CO 2，并再生并供应吸收剂 以及再生加热器，其使用从燃烧设备（50）供应的蒸汽（106）来加热再生器中的吸收剂并将加热的冷凝水（106a）返回到燃烧设备（50）。 CO 2回收单元还包括冷凝水/烟道气热交换器（57），其通过将冷凝水（106a）与所述冷凝水（106a）进行热交换来加热从再生加热器返回到燃烧设备（50）的冷凝水（106a） 燃烧设备（50）中烟道气（51）中的烟气（101）。