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    Photo-stable cosmetic and pharmaceutical formulations containing UV-filters
    5.
    发明授权
    Photo-stable cosmetic and pharmaceutical formulations containing UV-filters 失效
    光稳定的化妆品和药物配方含有紫外线过滤器

    公开(公告)号：US06407247B1

    公开(公告)日：2002-06-18

    申请号：US09494474

    申请日：2000-01-31

    申请人： Thorsten Habeck ,  Alexander Aumüller ,  Volker Schehlmann ,  Horst Westenfelder ,  Thomas Wünsch

    发明人： Thorsten Habeck ,  Alexander Aumüller ,  Volker Schehlmann ,  Horst Westenfelder ,  Thomas Wünsch

    IPC分类号： C07D22102

    CPC分类号： C07D275/03 ,  A61K8/411 ,  A61K8/42 ,  A61K8/466 ,  A61K8/49 ,  A61K8/498 ,  A61K8/4986 ,  A61Q1/04 ,  A61Q17/04 ,  C07C229/56 ,  C07C229/60 ,  C07C255/30 ,  C07C255/58 ,  C07C309/46 ,  C07D319/06 ,  C07D333/38

    摘要： A method of using compounds of formula I in which the C═C double bond is present in E and/or Z configuration and the variables have the following meanings: R1 denotes COOR5, COR5, CONR5R6, CN, O═S(—R5)═O, O═S(═OR5)═O, R7O—P(—OR8)═O; R2 denotes COOR6, COR6, CONR5R6, CN, O═S(—R6)═O, O═S(═OR6)═O, R7O—P(—OR8)═O; R3 denotes hydrogen, an optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic radical having in each case up to 18 carbon atoms; R4 denotes an optionally substituted aromatic or heteroaromatic radical containing from 5 to 12 ring atoms; R5 to R8 independently denote hydrogen, an open-chain or branched-chain aliphatic, araliphatic, cycloaliphatic or optionally substituted aromatic radical containing in each case up to 18 carbon atoms, where the variables R3 to R8 may also form, together with the carbon atoms to which they are attached, a 5-membered or 6-membered ring, which may be anellated if desired, as UV filters, particularly UV-A filters, in cosmetic and pharmaceutical formulations for the protection of the human skin or human hair from solar radiation, alone or together with compounds known per se in cosmetic and pharmaceutical formulations and capable of absorbing radiation in the UV range.

    摘要翻译： 在E和/或Z构型中使用存在C = C双键的式Iin化合物的方法，并且变量具有以下含义：R 1表示COOR 5，COR 5，CONR 5 R 6，CN，O = S（-R 5）= O = S（= OR5）= O，R7O-P（-OR8）= O; R2表示COOR6，COR6，CONR5R6，CN，O = S（-R6）= O，O = S（= OR6）= O，R7O-P（-OR8）= O; R3表示氢，任选取代的脂族，脂环族，芳脂族或芳族基团，其中每种情况下最多可达18个碳原子; R4表示任选取代的芳族或杂芳族基团， 12个环原子; R5至R8独立地表示氢，开链或支链脂族，芳脂族，脂环族或任选取代的芳族基团，其中每种情况最多可包含18个碳原子，其中变量R3至R8也可以形成， 它们所连接的碳原子，5元或6元环，如果需要，可以将其作为UV滤光器，特别是UV-A滤光器，在化妆品和药物中 用于保护人类皮肤或人类头发免受太阳辐射，单独或与化妆品和药物制剂中本身已知的化合物一起并且能够吸收UV范围内的辐射。

    Cosmetic and pharmaceutical preparations containing photostable UV filters
    6.
    发明授权
    Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
    含有光稳定紫外线过滤器的化妆品和药物制剂

    公开(公告)号：US06545174B2

    公开(公告)日：2003-04-08

    申请号：US09765624

    申请日：2001-01-22

    申请人： Thorsten Habeck ,  Sylke Haremza ,  Volker Schehlmann ,  Horst Westenfelder ,  Thomas Wünsch ,  Michael Drögemüller ,  Volker Bomm

    发明人： Thorsten Habeck ,  Sylke Haremza ,  Volker Schehlmann ,  Horst Westenfelder ,  Thomas Wünsch ,  Michael Drögemüller ,  Volker Bomm

    IPC分类号： C07C6976

    CPC分类号： C07C235/34 ,  A61K8/35 ,  A61K8/37 ,  A61K8/40 ,  A61K8/42 ,  A61K31/12 ,  A61K31/122 ,  A61K31/216 ,  A61K31/277 ,  A61K2800/52 ,  A61Q1/04 ,  A61Q17/04 ,  C07C69/618 ,  C07C233/11

    摘要： 4,4-Diarylbutadienes of the formula I, where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings: R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate, or ammonium residues; R3 is COOR5, CONR5R6; R4 is COOR6, CONR5R6; R5 and R6 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C7-C10-bicycloalkyl, C3-C10-cycloalkenyl, C7-C10-bicycloalkenyl, aryl, hetaryl, unsubstituted or substituted; n is 1 to 3; and R3 and R4 are not COOCH3 when R1 and R2 are hydrogen, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.

    摘要翻译： 式I的4,4-二芳基丁二烯，其中二烯体系具有Z，Z; Z，E; E，Z或E，E构型或其混合物，其中彼此独立的变量具有以下含义：R 1和R 2为氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基， C 3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基，杂芳基，未取代或取代的取代基，其赋予在水中的溶解性并且选自 由羧酸盐，磺酸盐或铵残基组成; R3为COOR5，CONR5R6; R4是COOR6，CONR5R6; R 5和R 6是氢，C 1 -C 20烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 7 -C 10 - 双环烷基，C 3 -C 10 - 环烯基，C 7 -C 10 - 双环烯基，芳基，杂芳基，未取代或取代的; n为1〜3; 当R 1和R 2为氢时，R 3和R 4不是COOCH 3，用作化妆品和药物制剂中的光稳定性UV过滤剂，以保护人皮肤或人类头发免受太阳光线的影响，单独或与在UV区域吸收的化合物一起， 本身就是化妆品和药物制剂。

    Cosmetic or pharmaceutical preparations which comprise enaminotriazines as light protection agents, and novel enaminotriazines
    9.
    发明授权
    Cosmetic or pharmaceutical preparations which comprise enaminotriazines as light protection agents, and novel enaminotriazines 失效
    包含氨基三嗪作为防晒剂的化妆品或药物制剂，以及新的氨基三嗪

    公开(公告)号：US07217820B2

    公开(公告)日：2007-05-15

    申请号：US10984241

    申请日：2004-11-10

    申请人： Thomas Heidenfelder ,  Kristin Tiefensee ,  Thomas Wünsch

    发明人： Thomas Heidenfelder ,  Kristin Tiefensee ,  Thomas Wünsch

    IPC分类号： C07D251/70 ,  A61K7/42

    CPC分类号： A61Q17/04 ,  A61K8/4966 ,  C07D251/70

    摘要： The invention relates to the use of enaminotriazines of the formula I in which the radicals Y, independently of one another, are hydrogen, an optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic radical having in each case up to 18 carbon atoms, the radicals X are identical or different, where at least one of the radicals X is the ethenyl radical of the formula II and X may also have the meanings of Y, and where in the formula II the radicals R are identical or different and are cyano, optionally esterified carboxyl, substituted carbonyl, optionally substituted aminocarbonyl, optionally esterified sulfo, substituted sulfonyl or optionally esterified phosphono, and where two adjacent radicals R may optionally form a ring and the radicals R′ are identical or different and are hydrogen, an optionally substituted aliphatic, cycloaliphatic or aromatic radical having in each case up to 18 carbon atoms, as UV filters in cosmetic or pharmaceutical preparations for protecting human skin or human hair against solar rays, alone or together with compounds which absorb in the UV region and which are known per se for cosmetic preparations.

    摘要翻译： 本发明涉及式I的氨基三嗪的用途，其中基团Y彼此独立地为氢，任选取代的脂族，脂环族，芳脂族或芳族基团，其中每种情况最多可达18个碳原子，基团X 相同或不同，其中基团X中的至少一个是式II的乙烯基，X也可以具有Y的含义，并且其中在式II中，基团R相同或不同并且是氰基，任选地被酯化 羧基，取代的羰基，任选取代的氨基羰基，任选酯化的磺基，取代的磺酰基或任选酯化的膦酰基，并且其中两个相邻的基团R可以任选地形成环，并且基团R'相同或不同，并且是氢，任选取代的脂族，脂环族 或在每种情况下最多18个碳原子的芳族基团，作为化妆品中的UV过滤剂或用于保护的药物制剂 人类皮肤或人类头发抵抗太阳光线，单独或与在UV区域吸收的化合物一起，并且本身已知本身用于化妆品制剂。